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MSDS  
:
 Potassium citrate monohydrate
CAS  
:
 6100-05-6
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Potassium citrate monohydrate
Catalog Numbers: AC611755000, S75185, AL2760-10, AL2760-100, P218-12, P218-200LB, P218-212, P218-500, P222-500
Synonyms:
Citric acid, tripotassium salt, monohydrate.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
6100-05-6 Tripotassium citrate, monohydrate 99 unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless or white solid.
Caution! May cause eye, skin, and respiratory tract irritation.
Target Organs: No data found.


Potential Health Effects
Eye: Dust may cause mechanical irritation.
Skin: May cause mild skin irritation.
Ingestion: Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation: Inhalation of dust may cause respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dust from this material can form explosive organic dust cloud.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid breathing dust.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Tripotassium citrate, monohydrate none listed none listed none listed
1,2,3-propanetricarboxylic acid, 2-hydroxy-, tripotassium sa none listed none listed none listed

OSHA Vacated PELs: Tripotassium citrate, monohydrate: No OSHA Vacated PELs are listed for this chemical. 1,2,3-propanetricarboxylic acid, 2-hydroxy-, tripotassium sa: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: colorless or white
Odor: odorless
pH: 8.5 (10% solution)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:230 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.98
Molecular Formula:C6H7K3O8
Molecular Weight:324.41

Section 10 - Stability and Reactivity


Chemical Stability: Stable.
Conditions to Avoid: Dust generation.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 6100-05-6 unlisted.      
CAS# 866-84-2 unlisted.
LD50/LC50:
Not available.
Not available.

Carcinogenicity:
CAS# 6100-05-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 866-84-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated Not Regulated
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 6100-05-6 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
     CAS# 866-84-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 6100-05-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 866-84-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

     CAS# 6100-05-6: No information available.
     CAS# 866-84-2: 0
Canada - DSL/NDSL
     CAS# 866-84-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of Not controlled..
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #5 Date: 3/15/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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3-Pyridinesulfonic acid 636-73-7
2-Methyltetrahydrofuran 128-37-0
Potassium Bicarbonate 298-14-6
Potassium Biiodate 13455-24-8Iodic acid (HIO3), potassium salt (2:1)<-td>
Potassium Bisulfate 7646-93-7Sulfuric acid, monopotassium salt<-td>
Cyclobutyl-4-fluorophenyl ketone, 98% 31431-13-7
1-Triphenylphosphoranylidene-2-Propanone, 99% 1439-36-7
Methyl 3,5-dimethoxy-4-hydroxybenzoate, 98% 884-35-5
2-Amino-5-Iodobenzoic Acid, 99% 5326-47-6
5-Bromo-2-chlorobenzoic acid, 98% 21739-92-4
Potassium bromide 7758-02-3
2-Acetylbenzoic acid 577-56-0
Potassium carbonate anhydrous 584-08-7
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Potassium chlorate 3811-04-9
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Diphenylmercury 587-85-9
Potassium chloride 7447-40-7
2-(Tert-Butylamino)ethanol, 99+% 4620-70-6
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Potassium citrate monohydrate 6100-05-6
2-Methoxybenzyl alcohol 612-16-8
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