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MSDS  
:
 Carbowax PEG 600
CAS  
:
 25322-68-3
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Carbowax PEG 600
Catalog Numbers: NC9442223, P142-1
Synonyms:
Poly(oxy-1,2-ethanediyl), .alpha.-hydro-.omega.-hydroxy-; Polyethylene glycol; Poly(ethylene oxide); Poly(oxyethylene) glycol; Ethylene oxide, homopolymer.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
25322-68-3 Polyethylene glycol 100 unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless viscous liquid.
Good laboratory procedures are recommended when handling this compound. This is expected to be a low hazard for usual industrial handling.
Target Organs: None.


Potential Health Effects
Eye: May cause mild eye irritation.
Skin: Low hazard for usual industrial handling.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Low hazard for usual industrial handling.
Inhalation: Low hazard for usual industrial handling.
Chronic: Prolonged exposure may cause eye irritation.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medi cal aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Flash Point: 279 deg C ( 534.20 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 0; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Forms smooth, slippery surfaces on floors, posing an accident risk.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Storage: No special precautions indicated. Store at room temperature.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Good general ventilation should be sufficient to control airborne levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Polyethylene glycol none listed none listed none listed

OSHA Vacated PELs: Polyethylene glycol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Glove protection is not normally required.
Clothing: Protective garments not normally required.
Respirators: Respirator protection is not normally required.

Section 9 - Physical and Chemical Properties


Physical State: Viscous liquid
Appearance: colorless
Odor: faint odor
pH: Not available.
Vapor Pressure: .000013 atm
Vapor Density: >10.0
Evaporation Rate:0.01 (Butyl acetate=1)
Viscosity: 9.9-11.1 cS@99C
Boiling Point: 200 deg C
Freezing/Melting Point:20-25 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.126 @ 25C
Molecular Formula:HO-[CH2CH2O]n-H
Molecular Weight:570 - 630

Section 10 - Stability and Reactivity


Chemical Stability: Stable.
Conditions to Avoid: No specific conditions to avoid noted.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 25322-68-3: TQ3500000; TQ3520000; TQ3560000; TQ3580000; TQ3600000; TQ3610000; TQ3620000; TQ3630000; TQ3650000; TQ3675000; TQ3700000; TQ3800000; TQ3850000; TQ4025000; TQ4026000; TQ4027000; TQ4028000; TQ4030000; TQ4040000; TQ4041000; TQ4050000; TQ4070000; TQ4100000; TQ4105000; TQ4110000; TQ4950000; TQ5090000; TR1579850; ZD2465300
LD50/LC50:
CAS# 25322-68-3:
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, eye: 100 uL Mild;
     Draize test, rabbit, eye: 500 mg Mild;
     Draize test, rabbit, eye: 500 mg Mild;
     Draize test, rabbit, eye: 500 mg Mild;
     Draize test, rabbit, eye: 500 mg Mild;
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, eye: 500 mg Mild;
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Draize test, rabbit, skin: 500 mg/24H
Carcinogenicity:
CAS# 25322-68-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Goldfish: LC50 = >5000 mg/L; 24 Hr.; Unspecified
Bacteria: Phytobacterium phosphoreum: EC50 =100,000 mg/L; 15 minutes; Microtox test

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated as a hazardous material No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 25322-68-3 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 25322-68-3: Not controlled.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 25322-68-3 can be found on the following state right to know lists: Minnesota.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:


WGK (Water Danger/Protection)

     CAS# 25322-68-3: 1
Canada - DSL/NDSL
     CAS# 25322-68-3 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of Not controlled..
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 7/01/1999
Revision #8 Date: 3/16/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Carbowax PEG 400 25322-68-3
Carbowax PEG 600 25322-68-3
Carbowax PEG 3350 25322-68-3
Carbowax PEG 7000-8000 25322-68-3
Carbowax PEG 20M 37225-26-6
1-Bromopentane, 98% 110-53-2
Hydrindantin dihydrate, 96% 5950-69-6
Benzylacetone, 98% 2550-26-7Benzylacetone<-td>
2-Amino-5-Chlorobenzophenone Oxime, Mixture of Syn and Anti Isomers 18097-52-4
Trimethylacetaldehyde 630-18-2
Polyvinyl alcohol, 75 - 100% hydrolyzed, M.W. 2000 - 95000 9002-89-5
POPOP, Scintanalyzed 1806-34-4
Tetraphenyltin, 97% 595-90-4
Potassium Metal 7440-09-7
1-Chloro-2-Fluorobenzene, 99% 348-51-6
Acetic acid, potassium salt, anhydrous 127-08-2
5-Fluorocytosine, 99+% 2022-85-7
Trichloroisocyanuric Acid, 99% (Titr.) 87-90-1
Potassium Bitartrate 868-14-4
Solketal, 97+%(GC) 100-79-8
Aluminum potassium sulfate dodecahydrate 7784-24-9
1,4-Naphthoquinone-2-Sulfonic Acid, Potassium Salt 34169-62-5
1,2,3,4-Tetrahydro-1-naphthylamine 2217-40-5
12-Crown-4, 97+% 294-93-9
Dimethyl Nitroterephthalate, 99% 5292-45-5
3-Nitrobenzamide, 98% 645-09-0
3-Pyridinesulfonic acid 636-73-7
2-Methyltetrahydrofuran 128-37-0
Potassium Bicarbonate 298-14-6
Potassium Biiodate 13455-24-8Iodic acid (HIO3), potassium salt (2:1)<-td>
Potassium Bisulfate 7646-93-7Sulfuric acid, monopotassium salt<-td>
Cyclobutyl-4-fluorophenyl ketone, 98% 31431-13-7
1-Triphenylphosphoranylidene-2-Propanone, 99% 1439-36-7
Methyl 3,5-dimethoxy-4-hydroxybenzoate, 98% 884-35-5
2-Amino-5-Iodobenzoic Acid, 99% 5326-47-6
5-Bromo-2-chlorobenzoic acid, 98% 21739-92-4
Potassium bromide 7758-02-3
2-Acetylbenzoic acid 577-56-0
Potassium carbonate anhydrous 584-08-7
Potassium Carbonate Sesquihydrate 6381-79-9Potassium carbonate, sesquihydrate<-td>
Potassium chlorate 3811-04-9
2-Bromohexadecanoic acid, 98%. 18263-25-7
Diphenylmercury 587-85-9
Potassium chloride 7447-40-7
2-(Tert-Butylamino)ethanol, 99+% 4620-70-6
Potassium chromate 7789-00-6
Potassium citrate monohydrate 6100-05-6
2-Methoxybenzyl alcohol 612-16-8
(S)-(+)-2,2-Dimethyl-4-(Hydroxymethyl)-1,3-Dioxolane-P-Toluenesulfonate, 97% 23735-43-5
Chromium (III) Potassium Sulfate Dodecahydrate 7788-99-0



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