Section 1 - Chemical Product and Company Identification |
MSDS Name: Carbowax PEG 600
Catalog Numbers:
NC9442223, P142-1
Synonyms:
Poly(oxy-1,2-ethanediyl), .alpha.-hydro-.omega.-hydroxy-;
Polyethylene glycol; Poly(ethylene oxide); Poly(oxyethylene) glycol;
Ethylene oxide, homopolymer.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
25322-68-3 |
Polyethylene glycol |
100 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colorless viscous liquid.
Good laboratory procedures are recommended when handling this
compound. This is expected to be a low hazard for usual industrial
handling.
Target Organs: None.
Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
Low hazard for usual industrial handling.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling.
Chronic:
Prolonged exposure may cause eye irritation.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. If irritation develops, get medi
cal aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water. Wash mouth out with water. Get medical aid if
irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
Flash Point: 279 deg C ( 534.20 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 0; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Forms smooth, slippery surfaces on
floors, posing an accident risk.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed.
Storage:
No special precautions indicated. Store at room temperature.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Polyethylene glycol
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Polyethylene glycol:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Glove protection is not normally required.
Clothing:
Protective garments not normally required.
Respirators:
Respirator protection is not normally required.
Section 9 - Physical and Chemical Properties
|
Physical State: Viscous liquid
Appearance: colorless
Odor: faint odor
pH: Not available.
Vapor Pressure: .000013 atm
Vapor Density: >10.0
Evaporation Rate:0.01 (Butyl acetate=1)
Viscosity: 9.9-11.1 cS@99C
Boiling Point: 200 deg C
Freezing/Melting Point:20-25 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.126 @ 25°C
Molecular Formula:HO-[CH2CH2O]n-H
Molecular Weight:570 - 630
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
No specific conditions to avoid noted.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 25322-68-3:
TQ3500000; TQ3520000; TQ3560000; TQ3580000; TQ3600000;
TQ3610000; TQ3620000; TQ3630000; TQ3650000; TQ3675000;
TQ3700000; TQ3800000; TQ3850000; TQ4025000; TQ4026000;
TQ4027000; TQ4028000; TQ4030000; TQ4040000; TQ4041000;
TQ4050000; TQ4070000; TQ4100000; TQ4105000; TQ4110000;
TQ4950000; TQ5090000; TR1579850; ZD2465300
LD50/LC50:
CAS# 25322-68-3: Draize test,
rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, eye: 100 uL
Mild; Draize test, rabbit, eye: 500
mg Mild; Draize test, rabbit, eye:
500 mg Mild; Draize test, rabbit,
eye: 500 mg Mild; Draize test,
rabbit, eye: 500 mg Mild; Draize
test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, eye: 500 mg/24H
Mild; Draize test, rabbit, eye: 500
mg Mild; Draize test, rabbit, eye:
500 mg/24H Mild; Draize test,
rabbit, skin: 500 mg/24H Mild;
Draize test, rabbit, skin: 500 mg/24H
Carcinogenicity:
CAS# 25322-68-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Fish: Goldfish: LC50 = >5000 mg/L; 24 Hr.; Unspecified Bacteria:
Phytobacterium phosphoreum: EC50 =100,000 mg/L; 15 minutes; Microtox
test
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 25322-68-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 25322-68-3: Not controlled.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 25322-68-3 can be found on the
following state right to know lists: Minnesota.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 25322-68-3: 1
Canada - DSL/NDSL
CAS# 25322-68-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of Not controlled..
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 7/01/1999 Revision #8 Date: 3/16/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
|
|