|
Section 1 - Chemical Product and Company Identification |
MSDS Name: p-Phenylenediamine
Catalog Numbers:
AC417460000, AC417460010, AC417462500
Synonyms:
1,4-Diaminobenzene
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
|
Section 2 - Composition, Information on Ingredients
|
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 106-50-3 |
p-Phenylenediamine |
99 | 203-404-7 |
|
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Not available.
Appearance: Not available.
Not available.
Target Organs: None.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
|
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
|
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
Flash Point: Not available
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
|
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal.
|
Section 7 - Handling and Storage
|
Handling:
Not available.
Storage:
Not available.
|
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| p-Phenylenediamine
|
0.1 mg/m3 TWA
|
0.1 mg/m3 TWA 25 mg/m3 IDLH
|
0.1 mg/m3 TWA
|
OSHA Vacated PELs:
p-Phenylenediamine:
0.1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
|
Section 9 - Physical and Chemical Properties
|
Physical State: Not available.
Appearance: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.01 mbar @ 20
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:142 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:NH2C6H4NH2
Molecular Weight:108.14
|
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen gas.
Hazardous Polymerization: Has not been reported.
|
Section 11 - Toxicological Information
|
RTECS#:
CAS# 106-50-3:
SS8050000
LD50/LC50:
CAS# 106-50-3:
Draize test,
rabbit, skin: 12500 ug/24H Mild;
Draize test, rabbit, skin: 250 mg/24H
Moderate;
Inhalation, rat: LC50 =
920 mg/m3/4H;
Oral, rat: LD50 = 80
mg/kg;
.
Carcinogenicity:
CAS# 106-50-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
|
Section 12 - Ecological Information
|
No information available.
|
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 - Transport Information
|
| |
US DOT |
Canada TDG |
| Shipping Name: |
PHENYLENEDIAMINES |
PHENYLENEDIAMINES |
| Hazard Class: |
6.1 |
6.1 |
| UN Number: |
UN1673 |
UN1673 |
| Packing Group: |
III |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 106-50-3 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 106-50-3: Effective 10/4/82, Sunset 10/4/92
Chemical Test Rules
CAS# 106-50-3: 40 CFR 799.3300
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 106-50-3: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 106-50-3: immediate.
Section 313
This material contains
p-Phenylenediamine (CAS# 106-50-3, 99%),which is subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR
Clean Air Act:
CAS# 106-50-3 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 106-50-3 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin and if
swallowed.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 60 This material and its container must be disposed of as hazardou
s waste.
S 28A After contact with skin, wash immediately with plenty of water
.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-50-3: 3
Canada - DSL/NDSL
CAS# 106-50-3 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 106-50-3 is listed on the Canadian Ingredient Disclosure List.
|
Section 16 - Additional Information
|
MSDS Creation Date: 5/07/1999
Revision #4 Date: 8/28/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
|
|