Material Safety Data Sheet
Freeman NO. 60 Pattern Coating
Date of Preparation: January 3, 2007 Revision:
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Freeman NO. 60 Pattern Coating HMIS
Chemical Family: Solvent 2
H
CAS Number: N/A 3
F
Other Designations: N/A 0
R
General Use: N/A PPE鈥?
Manufacturer: Freeman Manufacturing and Supply Company, Avon, OH 44011, Phone (440) 934-1902, 鈥燬ec. 8
FAX (440) 934-7200, Hours of Operation (8-5), Emergency phone number 1-800-424-9300.
Emergency Overview
Flammable, Inhalation, Irritant
Section 2 - Composition / Information on Ingredients
% wt or
Ingredient Name CAS Number
% vol
n-Butyl Acetate 123-86-4 15-25
Methyl Isobutyl Ketone 108-10-1 5-15
Isopropyl Acetate 108-21-4 <5
Butyl Benzyl Phthalate 85-68-7 <5
Anhyd. Isopropyl Alcohol 67-63-0 <5
VM&P Naphtha 64742-89-8 <5
Methyl Ethyl Ketone 78-93-3 <5
Xylene 1330-20-7 <5
Amyl Acetate 628-63-7 <1
n-Butyl Alcohol 71-36-3 <1
Ethyl Benzene 100-41-4 <1
Ingredient OSHA ACGIH Vapor Pressure
PEL STEL TLV STEL
150 ppm 150 ppm 13.0 mm Hg @ 68掳F
n-Butyl Acetate None estab. None estab.
100 ppm 50 ppm 16.0 mm Hg @ 68掳F
Methyl Isobutyl Ketone None estab. None estab.
250 ppm 250 ppm 47.0 mm Hg @ 68掳F
Isopropyl Acetate None estab. None estab.
5 mg/m3 5 mg/m3 N/A
Butyl Benzyl Phthalate None estab. None estab.
400 ppm 400 ppm 33.0 mm Hg @ 68掳F
Isopropyl Alcohol None estab. None estab.
300 ppm 300 ppm 10.2 mm Hg @ 68掳F
VM&P Naphtha None estab. None estab.
200 ppm 200 ppm 78.0 mm Hg @ 68掳F
Methyl Ethyl Ketone None estab. None estab.
100 ppm 50 ppm 14.2 mm Hg @ 100掳F
Xylene None estab. None estab.
100 ppm 100 ppm 4.0 mm Hg @ 68掳F
Amyl Acetate None estab. None estab.
100 ppm 50 ppm 4.4 mm Hg @ 68掳F
n- Butyl Alcohol None estab. None estab.
100 ppm 100 ppm 7.1 mm Hg @ 68掳F
Ethyl Benzene None estab. None estab.
Section 3 - Physical and Chemical Properties
Appearance and Odor: Gray liquid, Strong Solvent Water Solubility: Negligible
Coating V.O.C.: 4.49 lb/gal Boiling Range: 175掳F-464掳F
Material V.O.C.: 4.49 lb/gal Evaporation Rate: Slower than Ether
Vapor Density (Air=1): Heavier than air.
Specific Gravity (H2O=1, at 4 掳C): 1.26
Freeman NO. 60 Pattern Coating Revision:
Section 4 - Fire-Fighting Measures
NFPA
Flash Point: 23掳F (-5掳C)
Flash Point Method: TCC
3
LEL: 0.9% v/v
0
2
UEL: 20 % v/v
鈥?
Extinguishing Media: Foam, CO2, dry chemical
Unusual Fire and Explosion Hazards: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open
flame. Closed containers may explode when exposed to extreme heat. Do not apply to hot surfaces.
Fire-Fighting Instructions: Water spray may be ineffective. Use fog nozzles. Cool fire exposed containers with water.
Section 5 - Stability and Reactivity
Stability: Stable under recommended handling and storage conditions.
Conditions to Avoid: High temperatures
Incompatibility (Materials to Avoid): N/A
Hazardous Decomposition Products: May produce hazardous fumes when heated. Carbon monoxide, oxides of nitrogen.
Hazardous Polymerization: Will not occur.
Section 6 - Health Hazard Information
Potential Health Effects
Inhalation: Anesthetic. Irritation of the respiratory tract or acute nervous system depression characterized by headache,
dizziness, staggering gait, confusion, unconsciousness, or coma.
Skin and Eye Contact: Primary irritation.
Skin: Prolonged or repeated exposure to this material may cause redness and burning, during, and cracking of the skin and
dermatitis. Person with pre-existing skin disorders may be more susceptible.
Ingestion: Do not induce vomiting. Consult a physician or poison control center.
Health Hazards (Acute and Chronic): Pre-existing heart disorders may be aggravated by exposure to this material.
Carcinogenicity: IARC, NTP, and OSHA do not any component as carcinogenic. Contains very low levels of Benzene as an
impurity of Xylene. Benzene is classified by the State of California as a cancer hazard.
Medical Conditions Aggravated by Long-Term Exposure: Any medical condition, allergy, or sensitization can become worse
upon exposure.
Emergency and First Aid Procedures
Inhalation: Remove from exposure. Restore breathing. Keep warm and quiet. Notify a physician.
Eyes: Flush immediately with large amounts of water for 15 minutes. See a physician.
Skin: Wash affected areas thoroughly with soap and water. Remove contaminated clothing.
Ingestion: Do not induce vomiting. Consult a physician or poison control center.
Section 7 - Spill, Leak, and Disposal Procedures
Spill /Leak Procedures: Remove all sources of ignition. Ventilate area. Remove with inert absorbent and non-sparking tools.
Disposal: Disposal in accordance with local, state, and federal regulation. Incinerate in approved facility. Do not incinerate
closed containers. Emptied containers may retain hazardous residue and explosive vapors. Contact your supplier or a licensed
contractor for detailed recommendations. Follow applicable Federal, state, and local regulations.
State Regulations:
California Proposition 65: Contains - Benzene, butyl benzyl phthalate, xylene and ethyl benzene
Materials on the New Jersey Right to Know List: Amyl acetate, methyl isobutyl ketone, butyl benzyl phthalate, isopropyl
acetate, n-butyl acetate, isopropyl alcohol, methyl ethyl ketone, isobutyl alcohol, xylene, ethyl benzene and talc (CAS #
14807-96-6)
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Revision: Freeman NO. 60 Pattern Coating
Materials on the Pennsylvania Right to Know List: Amyl acetate, methyl isobutyl ketone, butyl benzyl pthalate, isopropyl
acetate, n-butyl acetate, isopropyl alcohol, methyl ethyl ketone,; isobutyl alcohol, xylene, ethyl benzene and talc (CAS
# 14807-96-6)
Materials on the Massachusetts Right to Know List: Amyl acetate, methyl isobutyl ketone, butyl benzyl phthalate
isopropyl acetate, n-butyl acetate, isopropyl alcohol, methyl ethyl ketone, isobutyl alcohol, xylene and ethyl benzene
Regulatory Information:
TSCA Inventory Status: All ingredients listed on TSCA Inventory.
Section 8 - Exposure Controls / Personal Protection
Ventilation: In restricted ventilation areas use Bureau of Mines approved chemical mechanical filters designed to remove a
combination of particulate and gas/vapor. In confined areas use Bureau of Mines approved air line type respirator.
Respiratory Protection: In outdoor or open areas use Bureau of Mines approved mechanical filter respirator to remove solid air
borne particles of overspray during spray application.
Protective Gloves: Wear resistant gloves such as: Natural rubber, or neoprene.
Eye Protection: Chemical splash goggles in compliance with OSHA regulation.
Other Protective Clothing or Equipment: To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Work/Hygienic Practices: Wash hands before eating or using the washrooms, smoke in smoking areas only.
Section 9 - Special Precautions and Comments
Handling and Storage:
Handling Precautions: Ground containers when pouring. Avoid free fall of liquid in excess of a few inches. Do not flame cut,
braze or weld.
Storage Requirements: Do not store above 120掳F. Store large quantities in building designed and protected for storage of
NFPA Class Liquids.
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Paint Packaging Authorizations Quantity Limitations
Flammable Liquid 3 a) Exceptions: a) Passenger, Aircraft, or Railcar:
Shipping Symbols: b) Non-bulk Packaging: b) Cargo Aircraft Only:
Hazard Class: 3 c) Bulk Packaging:
ID No.: UN 1263 Vessel Stowage Requirements
Packing Group: II a) Vessel Stowage:
Label: Flammable Liquid b) Other:
Special Provisions (172.102):
Prepared By:
Revision Notes:
Disclaimer: The following supersedes Buyer鈥檚 documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty,
strict of liability arising in connection with the product(s). Buyer鈥檚 sole remedy and Seller鈥檚 sole liability for any claims shall be
Buyer鈥檚 purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its
intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which
prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the
human body is intended.
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