Material Safety Data Sheet according 91/155/EC
Product Name : Mipa Holzgrund
Date: 08.04.03 Revision Date: 25.03.03 page/1/5
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1. IDENTIFICATION OF THE PREPARATION AND COMPANY.
Product Name and Code : Mipa Holzgrund
Name, full adress and tel. of Company:
Mipa AG
Am Oberen Moos 1
D-84051 Essenbach
Phone: of the Company: 0049/8703/922-0
Emergency phone : 0049/8703/922-0 Fax: 0049/8703/922-100
e-mail:mipa@mipa-paints.com www.mipa-paints.com
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2. COMPOSITION/INFORMATION ON INGREDIENTS.
Substances presenting a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC.
EINECS-Nr Names
CAS-No. R-phrases Symb. Conc.%
200-751-6 butan-1-ol
71-36-3 10-22-37/38-41-67 Xn 1 - 2.5
211-986-9 dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)-
731-27-1 methanesulphenamide
23-36/37/38-43-48/20-50/53 T,N < 1
265-150-3 Naphtha (petroleum),hydrotreated heavy;low boiling point
64742-48-9 65-66 Xn 75 - 100
Zinkcarboxylat
136-53-8 51/53 N < 1
Extra notices:
(See full text of R phrases under chapter 16)
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3. HAZARDS IDENTIFICATION OF THE PREPERATION.
n.a.
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
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4. FIRST AID MEASURES.
General :
In all causes of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation :
Remove or fresh air, keep patient warm and at rest, if breathing is
irregular or stopped, administer artifical respiration. Give nothing by
mouth. If unconscious place in recovery position and seek medical advice.
Eye contact :
Irrigate copiously with clean, fresh water for at least 10 minutes, holding
the eyelids apart and seek medical advice.
Skin contact :
Remove contaminated clothing. Wash skin thorougly with soap and water or
use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If accidentally swallowed obtain immediate medical attention. Keep at rest.
Do NOT induce vomiting.
____________________________________________________________________________
Material Safety Data Sheet according 91/155/EC
Product Name : Mipa Holzgrund
Date: 08.04.03 Revision Date: 25.03.03 page/2/5
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5. FIRE-FIGHTING MEASURES.
Extinguishing media : recommended : alcohol resistant foam, CO2,
powders, waterspray
not to be used : waterjet.
Recommendations : Fire will produce dense black smoke. Exposure
to decomposition products may cause a health hazard.
Appropriate breathing apparatus may be required.
Cool closed containers exposed to fire with water. Do
not allow run- off from fire fighting to enter drains
or water courses.
____________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES.
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8. Contain and collect
spillage with non-combustible absorbent materials, e.g. sand, earth,
vermiculite, diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Do not allow to enter
drains or watercouses.
Clean preferabily with a detergent; avoid use of solvents.
If the product contaminates lakes, rivers or sewages, inform appropriate
authorities in accordance with local regulations.
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7. HANDLING AND STORAGE.
Handling.
Vapours are heavier than air and may spread along floors. Vapours may form
Explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour concentration higher than
the occupational exposure limits.
Additionally, the product should only be used in areas from which all naked
lights and other sources of ignition have been excluded. Electrical
equipment should be protected to the appropriate standard.
Preperation may charge electrostatically: always use earthing leads when
transferring from one container to another. Operators should wear antistatic
footwear and clothing and floors should be of the conducting type
Keep container tightly closed. Isolate from sources of heat, sparks and open
flame. No sparking tools should be used.
Avoid skin and eye contact. Avoid inhalation of vapour and spray mist.
Smoking, eating and drinking should be prhibited in application area.
For personal protection se Section 8.
Never use pressure to empty : container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Storage.
Although the storage and use of this product is not subject to specific
statutory requirements, observation of the principles of the Highly
Flammable Liquids and Liquefied Petroleum Gases Regulations as appropriate
will be seen as good industrial practice in meeting the general duties of
the Health and Safety at Work Act.
Observe label precaution. Stoage: protected against frost on a dry, well
ventilated place away from sources of heat and direct sunlight.
Keep away from sources of ignition. Keep away from oxidising agents, from
strongly alkaline and strongly acid materials.
No smoking. Prevent unauthorized access. Containers which are opened must
be carefully resealed and kept upright to prevent leakage.
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Material Safety Data Sheet according 91/155/EC
Product Name : Mipa Holzgrund
Date: 08.04.03 Revision Date: 25.03.03 page/3/5
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION.
Engineering Measures.
Provide adequate ventilation. Where reasonably practicable this should be
achieved by the use of local exhaust ventilation and good general
extraction.
If these are not sufficient to maintain concentrations of particulates and
solvent vapour below the OEL, suitable respiratory protection must be worn.
Exposure Limits.
Occupational exposure limit for :
EINECS-No. Names STL mg/m3 LTL mg/m3
200-751-6 butan-1-ol 50 0 ppm
Personal Protection:
Respiratory protection.
When workers are facing concentrations above the exposure limit they must
use appropriate certified respirators.
Hand protection.
For prolonged or repeated contact, use :
Barrier creams may help to protect the exposed areas of the skin, they
should however not be applied once exposure has occured.
Eye protection.
Use safety eyewear designed to protect against splash of liquids.
Skin protection.
Personel should wear antistatic clothings made of natural fiber or of high
temperature resistant synthetic fiber. All parts of the body should be
washed after contact.
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9. PHYSICAL AND CHEMICAL PROPERTIES.
Physical form : liquid Methode
color : see trade name
odor typical
flash point : 41 掳C DIN 53213
viscosity : at 20 oC 12 s 4 mm DIN 53211
density : 0.80 g/cm3
solvent content : 92 %
vapour pressure : mbar
ignition temperature : 200 掳C
boiling point : 107 掳C
solid weight : 8.39 %
solid volume : 7.87 1/100kg
lower explosion limit: 0.6 Vol %
solubility in water : insoluble
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10. STABILITY AND REACTIVITY.
Stabile under recommended storage and handling conditions.(See section 7)
When exposed to high temperatures may produce hazardous decomposition
products such as carbon monoxide and dioxide, smoke, oxides of nitrogen.
Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
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11. TOXICOLOGICAL INFORMATION.
There are no data available on the preparation itself.
Exposure to component solvents vapours concentration in excess of the stated
occupational exposure limit may result in adverse health effect such as
mucous membrane and respiratory system irritation and adverse effect on
kidney, liver and central nervous system.
Material Safety Data Sheet according 91/155/EC
Product Name : Mipa Holzgrund
Date: 08.04.03 Revision Date: 25.03.03 page/4/5
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Symptoms and signs include headache; dizziness, fatigue, muscular weakness,
drowsines and in extreme cases, loss of consciousness. Repeated or
prolonged contact with the preparation may cause removal of natural
fat from the skin resulting in non-allergic contact dermatitis and
absorption through the skin.
The liquid splashed in the eyes may cause irritation and reversible damage.
Remark: The product has not been tested as such, but is categorised
by means of conventional method.(EC-Guidelines 1999/45/EC)
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12. ECOLOGICAL INFORMATION.
The product should not be allowed to enter drains or water courses.
The preparation itself is labelled in accordance with the
conventional dangerous preparations directive (1999/45/EG)
as not dangerous for the environment.
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13. DISPOSAL CONSIDERATIONS.
080111 waste paint and varnish containing organic solvents or
other dangerous substances
Do not allow into drains or water courses.
Empty containers are to be deposited according to the official rules.
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14. TRANSPORT INFORMATION.
Road/rail-transportation
ADR/RID Class: 3
UN-Nr.: 1263
Transport document: Paint
(nicht viskos)
contains:
Packaging group: III
Sea transport
IMDG/Class: 3 Packaging group: III
EMS-Nr.: 3-05
UN-Nr.: 1263
Proper shipping name: PAINT
contains: /
Marine pollutant: n.a.
ICAO/IATA Class: 3 UN Nr. : 1263
Proper shipping name: Paint
/
Packaging group : III
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15. REGULARY INFORMATION.
The requirements of the Classification Packaging and Labelling of
Dangerous Substances Regulations.(EC Guidelines 1999/45/EC)
The product is labelled as follows :
n.a.
Danger classification :
n.a.
contains:
R phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
Material Safety Data Sheet according 91/155/EC
Product Name : Mipa Holzgrund
Date: 08.04.03 Revision Date: 25.03.03 page/5/5
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S phrases:
24 Avoid contact with skin.
38 In case of insufficient ventilation, wear suitable
respiratory equipment.
51 Use only in well-ventilated areas.
23 Do not breathe vapour.
P phrases:
n.a.
Water hazard class: 2
VOC (g/l) DIN ISO 11890: 735.221
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16. OTHER INFORMATION.
Full text of R phrases with no appearing in section 2 :
10 Flammable.
22 Harmful if swallowed.
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
67 Vapours may cause drowsiness and dizziness.
23 Toxic by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitisation by skin contact.
48/20 Harmful: danger of serious damage to health by prolonged
exposure through inhalation.
50/53 Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
The information of this MSDS is based on the present state of our knowledge
and on current EEC and national laws, as the users' working conditions are
beyond our knowledge and control. The product is not to be used for other
purposes than those specified under section 1 without first obtaining
written handling instruction.
It is always the responsibility of the user to take all
necessary steps in order to fulfil the demand laid down in the local rules
and legislation. The information in this MSDS is meant as a description of
the safety requirements of our product : it is not to be considered as a
guarantee of the products' properties.
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