Conforms to 93/112/EC and ISO 11014-1
MATERIAL SAFETY DATA SHEET
KLARTAN
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
: KLARTAN
Product name
: Tau-fluvalinate
Chemical name of active
ingredient(s)
: R-10834.G
Code no.
: Makhteshim Agan (UK) Limited
Supplier
Unit 16, Thatcham Business Village Colthrop Way
Thatcham
Berkshire RG19 4LW
Tel No: 01635 860555 Fax No: 01635 861555
: National Chemical Emergency Centre
Emergency telephone
Tel: 01865 407333
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
: Preparation
Substance/preparation
Information on hazardous ingredients *
Common name CAS No. % EC Number Symbol R-Phrases
Tau-fluvalinate 102851-06-9 24 Xn, N R22-38-50/53
1,2-ethanediol 000107-21-1 1-10 203-473-3 Xn R22
* Occupational Exposure Limit(s), if available, are listed in section 8
3. HAZARDS IDENTIFICATION
: Not hazardous.
Human health hazards
: Toxic to aquatic organisms, may cause long-term adverse effects in the
Environmental hazards
aquatic environment.
4. FIRST-AID MEASURES
Effects and symptoms
First-aid measures
: Remove victim to fresh air.
Inhalation
: If swallowed, seek medical advice immediately and show this container or
Ingestion
label; administer active carbon in a large amount of water. Never give
anything by mouth to an unconscious person.
Do not induce vomiting.
: Wash off with plenty of water and soap. Remove contaminated clothing.
Skin contact
: Wash out with plenty of water. Consult an eye specialist.
Eye contact
: There is no specific antidote. Treat symptomatically.
Notes to a physician
5. FIRE-FIGHTING MEASURES
Extinguishing media
: Dry chemical, water spray, foam, carbon dioxide.
Suitable
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Conforms to 93/112/EC and ISO 11014-1
MATERIAL SAFETY DATA SHEET
KLARTAN
: Direct water jets.
Not suitable
: Dike fire control water for later disposal. Prevent all discharge into the
Special fire-fighting
environment.
procedures
: Combustion products are toxic and/or irritant. Measures must be taken to
Unusual fire/explosion
prevent the contaminated extinguishing agent from seeping into the ground
hazards
or from spreading uncontrollably.
: Toxic and/or irritating gas.
Hazardous thermal
(de)composition products
: Self-contained breathing apparatus.
Protection of fire-fighters
6. ACCIDENTAL RELEASE MEASURES
: Wear suitable protective clothing, nitrile rubber gloves, safety glasses
Personal precautions
or face shield.
: Do not discharge into drains or the environment.
Environmental precautions
: Collect and contain as much free liquid as possible. Absorb remainder in
Methods for cleaning up
sand or other inert material. Place into a clean container and cover
container loosely for later disposal.
7. HANDLING AND STORAGE
: Avoid contact with skin and eyes. Do not breathe fumes. Wear suitable
Handling
protective clothing, nitrile rubber gloves, safety glasses or face shield.
: Keep only in the original container at a temperature not exceeding 40潞C.
Storage
Keep away from food, drink and animal feedingstuffs.
Packaging materials
: Coextruded polyethylene bottles; Drums with polyethylene liner.
Suitable
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure
Limits
Common name : 1,2-ethanediol
: 100 mg/m3; 39.4 ppm.
TLV (USA)
Personal protective
equipment
: In case of insufficient ventilation, wear suitable respiratory equipment.
Respiratory system
: Wear suitable protective clothing and boots.
Skin and body
: nitrile rubber gloves.
Hands
: Safety goggles or face shield.
Eyes
: Wash hands thoroughly after handling.
Other information
9. PHYSICAL AND CHEMICAL PROPERTIES
: Liquid.
Physical state
: White - yellowish.
Colour
: Characteristic.
Odour
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Conforms to 93/112/EC and ISO 11014-1
MATERIAL SAFETY DATA SHEET
KLARTAN
: 1.07 - 1.11 g/cm3 (20潞C).
Density
: Miscible.
Solubility in water
: 3 - 7 (1% soluzione).
pH
: > 100潞C (Closed cup).
Flash point
: Not flammable (Combustible).
Flammability
: Not explosive.
Explosion properties
10. STABILITY AND REACTIVITY
: Stable under normal conditions.
Stability
: Avoid temperatures above 40潞C.
Conditions to avoid
: strong acids, strong bases.
Materials to avoid
: Not known.
Hazardous reactions
: Emits toxic fumes.
Hazardous decomposition
products
11. TOXICOLOGICAL INFORMATION
: LD50 > 2000 mg/kg, rat.
Acute toxicity - Oral
: LD50 > 2000 mg/kg, rat.
Acute toxicity - Dermal
: LC50 > 5.5 mg/l (4 hours) rat - Tau-fluvalinate.
Acute toxicity - Inhalation
: Not irritating (rabbit).
Skin irritation
: Not irritating (rabbit).
Eye irritation
: Guinea pig maximization test: Non sensitizer
Sensitization
12. ECOLOGICAL INFORMATION
Very toxic to aquatic organisms.
: Fish: LC50 > 0.024 mg/l, 96 hours (rainbow trout).
Ecotoxicity
Algae: EC50 = >100 mg/l (72 hours).
Daphnia: LC50 = 0.011 mg/l (48 hours)
13. DISPOSAL CONSIDERATIONS
: Disposal according to the local legislation.
Methods of disposal
14. TRANSPORT INFORMATION
International transport regulations
: 3082
UN number
Land - Road/Railway
: Environmentally hazardous substance, liquid, N.O.S. (Tau-fluvalinate
Proper shipping name
24%).
:9
ADR/RID Class
: 11 (c)
ADR/RID Item number
: lll
Packing group
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Conforms to 93/112/EC and ISO 11014-1
MATERIAL SAFETY DATA SHEET
KLARTAN
Inland waterways
Sea
: Environmentally hazardous substance, liquid, N.O.S. (Tau-fluvalinate
Proper shipping name
24%).
:9
IMDG Class
: lll
Packing group
: None.
Medical First Aid Guide
(MFAG)
: None.
Emergency Schedules
(EmS)
Air
: Environmentally hazardous substance, liquid, N.O.S. (Tau-fluvalinate
Proper shipping name
24%).
:9
IATA-DGR Class
National transport regulations
No additional national transport regulations are known to the supplier
15. REGULATORY INFORMATION
: This product is provisionally labelled by the supplier in accordance with the
Classification
suppliers understanding of the EU regulations.
:N
Hazard symbol(s)
DANGEROUS FOR THE
ENVIRONMENT (N)
: R51/53: Toxic to aquatic organisms, may cause long-term adverse effects
Risk phrases
in the aquatic environment.
: S29: Do not empty into drains.
Safety phrases
S57: Use appropriate containment to avoid environmental contamination.
: 240 g/l Tau-fluvalinate.
Contains
16. OTHER INFORMATION
: Insecticide
Recommended use
The information contained in the Safety Data sheet is correct to the best of our knowledge at the date of
issue. It is intended as a guide for the safe use, handling, disposal, storage and transportation and is not
intended as a warranty or as a specification. The information relates only to the product specified and may
not be suitable for combinations with other materials or in processes other than those specifically described
herein.
Date of issue: 04/21/2002 Version: 001.00.00 Page 4 of 5
Conforms to 93/112/EC and ISO 11014-1
MATERIAL SAFETY DATA SHEET
KLARTAN
HISTORY
: 04/21/2002
Date of printing
: 04/21/2002
Date previous issue
: 04/21/2002
Date of issue
: 001.00.00
Version
The version-number is made up of three parts; part 1 is a general information code, part 2 a
country-specific code and part 3 a language-specific code
Date of issue: 04/21/2002 Version: 001.00.00 Page 5 of 5
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