MATERIAL SAFETY DATA SHEET
CREW SUPER BLUE MILD ACID BOWL CLEANER
HMIS NFPA Personal protective equipment
Health 3 3
Fire Hazard 0 0
Reactivity 0 0
Version Number: 1 Preparation date: 2007-05-16
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: CREW SUPER BLUE MILD ACID BOWL CLEANER
MSDS #: 126684-003
Product code: 04559, 4476081
Recommended use: Restroom Care.
Manufacturer, importer, supplier:
US Headquarters Canadian Headquarters
JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc.
8310 16th St. 2401 Bristol Circle
Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1
Phone: 1-888-352-2249 Phone: 1-800-668-3131
MSDS Internet Address:
www.johnsondiversey.com
Emergency telephone number: 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (M茅xico)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING. CAUSES EYE AND SKIN IRRITATION.
Principle routes of exposure: Eye contact. Skin contact. Inhalation.
Eye contact: Severe eye irritation.
Skin contact: Moderately irritating to the skin.
Inhalation: May be irritating to nose, throat, and respiratory tract.
Ingestion: May cause irritation to mouth, throat and stomach .
3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - Rat
Rabbit
Benzenesulfonic acid, mono-c10-14- 85117-49-3 1 - 5% =650 mg/kg Not available Not available
alkyl derivs.
Oxalic acid 6153-56-6 1 - 5% =7500 mg/kg Not available Not available
4. FIRST AID MEASURES
Eye contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical
attention.
Skin contact: Flush immediately with plenty of water. If irritation persists, get medical attention.
Inhalation: If breathing is affected, remove to fresh air. Get medical attention.
Ingestion: Give a cupful of water or milk . THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER.
DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person.
Aggravated Medical Conditions: Persons with pre-existing skin disorders may be more susceptable to irritating effects.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Specific hazards: Not applicable
Unusual hazards: None known
Specific methods: No special methods required
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
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5. FIRE-FIGHTING MEASURES
Extinguishing media which must not be used for safety reasons: No information available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment
Environmental precautions Clean-up methods - large spillage. Soak up with inert absorbent material. Sweep up and shovel into
and clean-up methods: suitable containers for disposal. Use a water rinse for final clean-up.
7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Do not taste or swallow. Remove and wash contaminated clothing and footwear before re-use. Wash
thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the
empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
No special ventilation requirements. General room ventilation is adequate.
Personal Protective Equipment
Eye protection: Chemical-splash goggles.
Hand protection: Chemical-resistant gloves
Skin and body protection: No special protective clothing is required.
Respiratory protection: No special protective clothing is required.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Bulk density: No information available
pH: 1.25 Dilution pH: 1.25
Appearance: Liquid Vapor density: No information available
Color: Clear Dark Blue Evaporation Rate No information available
Odor: Citrus Boiling point/range: Not determined
Specific gravity: 1.007 Melting point/range: Not determined
Density: 8.40 lbs/gal Decomposition temperature: Not determined
VOC: 0.6% * Autoignition temperature: No information available
Flash point: >200掳F >93.3掳C Partition coefficient (n-octanol/water): No information available
Solubility: Easily soluble Solubility in other solvents: No information available
Viscosity: No information available Elemental Phosphorus: 0 %P
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Stability: The product is stable.
Polymerization: Hazardous polymerization does not occur.
Hazardous decomposition products: None reasonably foreseeable.
Materials to avoid: Do not mix with chlorinated products. Strong bases.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Oral LD50 estimated to be greater than 5000 mg/kg
Component Information: See Section 3
Chronic toxicity: None known
Specific effects
Carcinogenic effects: None known
Mutagenic effects: None known
Reproductive toxicity: None known
Target organ effects: None known
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12. ECOLOGICAL INFORMATION
Environmental Information: No data available
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Dispose of according to all federal, state and local applicable regulations
RCRA Hazard Class: D002
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Australia (AICS), Philippines (PICCS),
China (IECSC).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Alcohol ethoxylates 68439-46-3 - - - -
Oxalic acid 6153-56-6 X X X X
Dodecylbenzene sulfonic acid 68584-22-5 - - - -
CERCLA/ SARA
SARA 311/312 Hazard Categories
Immediate: X
Delayed: -
Fire: -
Reactivity: -
Sudden Release of Pressure: -
Canada
WHMIS hazard class: D2B Toxic materials.
16. OTHER INFORMATION
Reason for revision: Not applicable
Prepared by: NAPRAC
Additional advice: None
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.
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