MSDS: CIBAFIX ECO
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: CIBAFIX ECO
MSDS CODE : C1377091E4
VERSION : 3
UPDATED : April 2004
Not classified as hazardous according to criteria of Worksafe Aust.
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn: Attention:
CHEMICAL SAFTEY OFFICER
or
EMERGENCY RESPONCE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: CIBAFIX ECO
Other name(s)..: AQUEOUS SOLUTION BASED ON POLYETHYLENE POLYAMINE
Correct Shipping name: ENVIRONMENTALLY HAZARDOUS SUBS,LIQ.,NOS
UN Number . . . . . : 3082
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 group . . : III
HAZCHEM Code . . . . : 2X
Poison Schedule . . : none allocated
USE:
TEXTILE CHEMICAL
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Appearance. . . . . . : YELLOW LIQUID,CHARACTERISTIC ODOUR (AMINE)
Boiling/Melting point : ca 100 (deg.C)
Vapour pressure . . . : NOT AVAILABLE
Specific Gravity. . . : NOT AVAILABLE
Density . . . . . . . : NOT AVAILABLE
Flash Point . . . . . : > 100 (deg.C method)
Flammability Limits . : not applicable
Solubility in water . : MISCIBLE (g/L @ 20 deg.C)
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Oxidising properties : NONE
pH : 6.5 - 8.5
Viscosity : 10 mPas AT 25 oC
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Chemical Entity CAS No. Proportion
CYANOGUANIDINE POYMER WITH N-(2-AMINOETH > 25 %
YL)-1,2-ETHANEDIAMINE
NON HAZARDOUS INGREDIENTS TO 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral,Rat LD50) >2000 mg/kg
Eye . . . : NON-IRRITANT - EC 83 OECD 405 RABBIT
Skin . . : NON-IRRITANT - EC 83 OECD 404 RABBIT.
NOT SKIN SENSITIZING - EC 83 OECD 406 GUINEA PIG.
Inhaled . : NOT YET AVAILABLE
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MSDS: CIBAFIX ECO
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NONE KNOWN
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Swallowed : WASH OUT MOUTH WITH WATER, DRINK PLENTY OF WATER
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING.
Inhaled . : REMOVE PATIENT TO FRESH AIR AND REST
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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AVOID EXCEEDING EXPOSURE LIMITS BY USE OF VENTILATION AND/OR PERSONAL
PROTECTION
AVOID CREATING AEROSOLS.
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE EXPOSURE LIMITS ARE MET. STATE REGULATIONS ON SPEED
AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS), OVERALLS AND GLASSES/FACE SHIELD ARE
RECOMMENDED TO BE WORN WITH THIS PRODUCT.
Where sufficient ventilation is not available, avoid breathing vapours
by using an AS 1716 approved half-face filter respirator type A -
class 1, suitable for organic vapours.
FOLLOW GOOD WORKING PRACTICE: Handle with care, avoid ingestion,
inhalation, eye or skin contact. Wash hands and face thoroughly
after handling and before eating, drinking or smoking.
Avoid unnecessary personal contact.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN COOL, DRY AREA WITH VENTILATION
Storage . . . . . . : STORE IN A BUNDED AREA (CLASS 9 GOODS)
UN Number . . . . . : 3082
Dangerous Goods Class Packaging
and Subsidiary Risk : 9 group . . : III
HAZCHEM Code . . . . : 2X
IATA Class . . . . . : 9
IMDG Reference . . . : 9
Incompatible DG Classes : KEEP CONTAINERS CLOSED
Emergency Procedure Guide Date: CONTAIN SPILL
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE -
CONTAIN FIRST, SOAK UP ALL RESIDUES IN INERT ABSORBANCE MATERIAL (i.e.
VERMICULITE, SAND).PLACE INTO MARKED CONTAINERS FOR DISPOSAL AS
CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH
TEMPERATURE INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY
CONTAINERS MUST BE DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT,
CONTACT CIBA SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
NONE KNOWN, VAPOURS OF NOx POSSIBLE IN A FIRE. WEAR SELF CONTAINED
BREATHING APPARATUS.
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MSDS: CIBAFIX ECO
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 122 mgO2/Kg
COD . . . . . . . . . . . . : 601 mgO2/Kg
TOC . . . . . . . . . . . . : 13.6%
Fish toxicity . . . . . . . : SPECIES : ZEBRA FISH, 96 HR.
LC0 : ca. 1 mg/l
LC50 : 5 mg/l
EC50(DAPHNIA): 4 mg/l, 48 Hr, OECD 202
ca 10% NITROGEN CONTENT
Toxicity to Bacteria . . . : IC50 : >100 MG/L, 3 hr.
OECD Biological degredation : < 10%, TOC/DOC ANALYSIS, OECD 303A (MOD)
Alga, growth inhibition . . : EC50: 0.1 mg/l, 72 Hr, OECD 201
Organo-halogen content. . . : NOT APPLICABLE
Heavy-metal content . . . . : UNDER ETAD RECOMMENDED LIMITS FOR TRACE
Phosphorous content . . . . : N/AP %
R51/53: TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE
EFFECTS IN THE AQUATIC ENVIRONMENT.
S61: AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/
SAFETY DATA SHEETS.
POORLY ELIMINATED BY ADSORPTION ON EFFLUENT TREATMENT SLUDGE
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EEC classification/labelling: * NOT CLASSIFIED AS HAZARDOUS *
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: KOCHEF1 Date: 25 April 04
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