MSDS: CIBACRON ORANGE LS-BR HC
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: CIBACRON ORANGE LS-BR HC
MSDS CODE : C1258884AL
VERSION : 5
UPDATED : December 2003
Hazardous according to criteria of Worksafe Australia
:
=--------------------------------------------------------------------=
COMPANY DETAILS
=--------------------------------------------------------------------=
CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
=--------------------------------------------------------------------=
Attn: Attention:
CHEMICAL SAFTEY OFFICER
or
EMERGENCY RESPONCE SERVICES
=--------------------------------------------------------------------=
IDENTIFICATION
=--------------------------------------------------------------------=
PRODUCT NAME ..: CIBACRON ORANGE LS-BR HC
Other name(s)..: AZO DYE PREPARATION
Correct Shipping name: NOT APPLICABLE
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
_________________________________
Appearance. . . . . . : BLACK POWDER WITH NO ODOUR
Boiling/Melting point : >300 (deg.C)
Vapour pressure . . . : <0.0001 mba (Pascals @ 20 deg.C)
Density . . . . . . . : 400 kg/m3(Bulk) (g/cc @ 20 deg.C)
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : 100 g/l at 60oC (g/L @ 20 deg.C)
_________________________________
Autoigntion temperature : >400 oC
Partition coefficient : ca. -4.3 log pow
pH :7-8
Ignition Temperature : > 500 oC
Thermal Decomposition : > 270 oC
HAZARD CODE : *XI* IRRITANT
=--------------------------------------------------------------------=
_________________________________
Chemical Entity CAS No. Proportion
Sodium 2,2'-[(1-Methyl-1,2-ethanediyl)bi 149850-31-7 60-70 %
s[imino(6-fluoro-1,3,5-triazinediyl)imin
o[2-[(aminocarbonyl)amino]phenylene]azo]
]bis[5-[(4-sulfophenyl)azo]benzenesulfon
ate
NON HAZARDOUS COMPONENTS To 100 %
=--------------------------------------------------------------------=
HEALTH HAZARD INFORMATION
=--------------------------------------------------------------------=
_________________________________
Page 1 of 4
MSDS: CIBACRON ORANGE LS-BR HC
Swallowed : SLIGHT (Oral,Rat LD50) >2000 mg/kg >2000
mg/kg (Dermal, Rat LD50).
Eye . . . : NON-IRRITANT EC 83 OECD 405 RABBIT
Skin . . : NON-IRRITANT - EC 83 OECD 404 RABBIT. SKIN
SENSITIZING - EC 83 OECD 406 GUINEA PIG. "REFER
TO HEALTH EFFECTS, CHRONIC".
Inhaled . : NOT YET AVAILABLE, BUT MAY CAUSE RESPIRATORY
SENSITIZATION (CHRONIC EFFECT) - SEE "HEALTH
EFFECTS" BELOW.
_________________________________
CASES OF RESPIRATORY SENSITIZATION HAVE BEEN OBSERVED WITH SOME DYES
AND CARE SHOULD BE TAKEN TO AVOID INHALATION.
SKIN SENSITISATION: EXPOSURE OF SKIN TO A SENSITISING AGENT TENDS TO
RESULT IN RESPONSES SUCH AS HIVES OR EXZEMA. SHOULD AN INDIVIDUAL
BECOME SENSITISED, A DOCTOR SHOULD BE CONSULTED AND ALL CONTACT WITH
THE SENSITISING PRODUCT MUST CEASE IMMEDIATELY.
_________________________________
Swallowed : WASH OUT MOUTH WITH WATER, DRINK PLENTY OF WATER
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES.
Skin . . : CLEAN CONTAMINATED AREA WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING. SEEK
MEDICAL ATTENTION.
Inhaled . : REMOVE PATIENT TO FRESH AIR, REST. IF SYMPTOMS OF
ASTHMA OR BREATHING DIFFICULTIES OCCUR, SEEK
MEDICAL ATTENTION. ASSIST BREATHING (OXY-VIVA
EQUIP) UNTIL HELP ARRIVES.
First aid facility: DELUGE SAFETY SHOWER SHOULD BE LOCATED NEAR WORK
AREA.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
=--------------------------------------------------------------------=
=--------------------------------------------------------------------=
PRECAUTIONS FOR USE
=--------------------------------------------------------------------=
_________________________________
TWA : 1 mg/m3 Sensitiser (Recommended by CIA-UK)
AVOID EXCEEDING EXPOSURE LIMITS BY USE OF VENTILATION AND/OR PERSONAL
PROTECTION
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
AVOID DUST FORMATION
_________________________________
WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE LPL OF EXPOSURE IS ATTAINED. ANY STATE REGULATIONS ON
SPEED AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
_________________________________
GLOVES (PVC, LONG IMPERVIOUS), OVERALLS MUST BE WORN AND GLASSES/FACE
SHIELD ARE RECOMMENDED TO BE WORN WHEN USING THIS PRODUCT.
PARTICULATE FILTER CLASS P1 (DUST MASK) IS REQUIRED TO BE WORN WHEN
POSITIVE LOCAL VENTILATION IN OPERATION, OTHERWISE THE FOLLOWING
AS1716 RESPIRATORY PROTECTION MUST BE WORN.
FOLLOW GOOD WORKING PRACTICE: Handle with care, avoid ingestion,
inhalation, eye or skin contact. Wash hands and face thoroughly
after handling and before eating, drinking or smoking.
Avoid unnecessary personal contact.
_________________________________
KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
=--------------------------------------------------------------------=
SAFE HANDLING INFORMATION
=--------------------------------------------------------------------=
_________________________________
General . . . . . . : KEEP CONTAINERS CLOSED
Storage . . . . . . : ENSURE ADQUATE VENTILATION
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
Page 2 of 4
MSDS: CIBACRON ORANGE LS-BR HC
HAZCHEM Code . . . . : NOT APPLICABLE
IATA Class . . . . . : FREE
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : SENSITIVE >40oC
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
STORE IN A COOL, DRY AREA WITH ADEQUATE VENTILATION.
=--------------------------------------------------------------------=
_________________________________
IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE. DAMPEN
DOWN POWDER AND AVOID DUST. SCOOP INTO MARKED CONTAINERS FOR DISPOSAL
AS CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS: LAND FILL: "NO"
SECURE LAND FILL: "NO" INCINERATION: "YES" HIGH
TEMPERATURE INCINERATION: "SUITABLE" - CONTAMINATED, EMPTY
CONTAINERS MUST BE DISPOSED OF AS CHEMICAL WASTE. NOTE: IF IN DOUBT,
CONTACT CIBA SPECIALTY CHEMICALS TELEPHONE NUMBER ON PAGE 1.
_________________________________
Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
VAPOURS OF CARBON-, NITROGEN-, SULFUR OXIDES AND SOME HYDROGEN
FLUORIDE POSSIBLE IN A FIRE. WEAR SELF CONTAINED BREATHING APPARATUS.
=--------------------------------------------------------------------=
OTHER INFORMATION
=--------------------------------------------------------------------=
_________________________________
BOD 5 . . . . . . . . . . . : 10 mg02/g
COD . . . . . . . . . . . . : 621 mg02/g
TOC . . . . . . . . . . . . : 25.58 %
Fish toxicity . . . . . . . : SPECIES : COMMON CARP, 96HR, OECD 203
LC0 : 100 mg/l
LC50 :>100 mg/l
DAPHNIA TOX. EC50: >100 mg/l, 48 hrs
ALGAE TOXICITY: EC50: >100 mg/l, 72 hrs.
Toxicity to Bacteria . . . : IC50 : >100 mg/l, 3 hrs. OECD 209
OECD Biological degredation : <10 % DOC ANALYSIS, OECD 302B
Organo-halogen content. . . : <0.1%, FLUORINE
Heavy-metal content . . . . : METAL CONTENT UNDER THE ETAD REC. LIMITS
Phosphorous content . . . . : 1 %
NOTE: PREVENT SPILLAGE FROM ENTERING WATERWAYS OR DRAINS.
NOT TOXIC OR HARMFUL TO AQUATIC ORGANISMS.
'NITROGEN CONTENT: ca. 17%'
BIOELIMINATION TEST SUMMARY: POORLY ELIMINATED BY ADSORPTION ON
EFFLUENT TREATMENT SLUDGE. BEHAVIOUR IN TREATMENT PLANTS: NO
INHIBITION. NO NITIRIFCATION INHIBITION KNOWN. TESTED MATERIAL:
PRODUCT/ACTIVE COMPONENT.
=--------------------------------------------------------------------=
_________________________________
EEC classification/labelling: * XI * IRRITANT
R-phrase: R43: MAY CASUE SENSITISATION BY SKIN CONTACT.
S-phrase: S22: DO NOT BREATHE DUST.
S24: AVOID CONTACT WITH SKIN.
S37: WEAR SUITABLE GLOVES.
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
=--------------------------------------------------------------------=
CONTACT POINT
=--------------------------------------------------------------------=
Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0408 023 891
or MR EFKAN KOCH on 03-9282-0673
Page 3 of 4
MSDS: CIBACRON ORANGE LS-BR HC
<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<----->>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>
______________________________________________________________________
=--------------------------------------------------------------------=
Authorised by: KOCHEF1 Date: 22 December 03
=--------------------------------------------------------------------=
Page 4 of 4
|