MSDS:
MATERIAL SAFETY DATA SHEET
PRODUCT NAME:
MSDS CODE : July
VERSION : 2002
UPDATED : Page 1 of 5
CIBACRON BRILLIANT BLUE LS-G HC MSDS: C1881725AO : 5
:
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COMPANY DETAILS
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CIBA SPECIALTY CHEMICALS
235 Settlement Road Unit 10, 43-51 College Street
THOMASTOWN VIC 3074 GLADESVILLE NSW 2111
Phone: (03) 9282 0600 Phone: (02) 9879 2500
Fax: (03) 9465 0031 Fax: (02) 9879 2501
Emergency All Hours; AUS:1800 033 111 NZL:0800 734 607
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Attn: Attention:
CHEMICAL SAFTEY OFFICER
or
EMERGENCY RESPONCE SERVICES
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IDENTIFICATION
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PRODUCT NAME ..: CIBACRON BRILLIANT BLUE LS-G HC
Other name(s)..: DIOXAZINE DYE PREPARATION
Correct Shipping name: NOT APPLICABLE
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
Poison Schedule . . : NONE ALLOCATED
USE:
TEXTILE DYE
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Appearance. . . . . . : BLUE POWDER WITH NO ODOUR.
Boiling/Melting point : > 400 (deg.C)
Vapour pressure . . . : < 0.000001 (Pascals @ 20 deg.C)
Density . . . . . . . : NOT AVAILABLE
Flash Point . . . . . : NOT APPLICABLE
Flammability Limits . : not applicable
Solubility in water . : 30 g/l at 25 oC (g/L @ 20 deg.C)
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SOLUBILITY IN WATER : 80 g/l at 30 oC
OXIDISING PROPERTIES : NONE
AUTO-IGNITION TEMPERATURE: > 400 oC
BULK DENSITY : 487 kg/m3
pH value : 6 - 7 in water (20 g/l)
COLOUR INDEX : REACTIVE BLUE 269
PARTITION COEFFICIENT : < -4 Log Pow
HAZARD CODE : ** Xi ** IRRITANT
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Chemical Entity CAS No. Proportion
C.I REACTIVE BLUE 269 191877-09-5 60 - 70 %
OBSERVE "EXPOSURE LIMIT(S)"
NON HAZARDOUS COMPONENTS TO 100 %
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HEALTH HAZARD INFORMATION
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Swallowed : SLIGHT (Oral Rat, LD50): > 2000 mg/kg.
Page 1 of 4
MSDS:
Eye . . . : RISK OF SERIOUS DAMAGE TO EYES - STAINS THE EYES,
OECD 405 RABBIT
Skin . . : NON-IRRITANT - OECD 404 RABBIT;
DERMAL (RAT, LD50): > 2000 mg/kg;
SKIN SENSITISATION: NOT SENSITIZING OECD 406
GUINEA PIG.
Inhaled . : NOT YET AVAILABLE - SEE "HEALTH EFFECTS - CHRONIC"
BELOW.
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CASES OF RESPIRATORY SENSITIZATION HAVE BEEN OBSERVED WITH SOME DYES
AND CARE SHOULD BE TAKEN TO AVOID INHALATION. SHOULD AN INDIVIDUAL
BECOME SENSITIZED, A DOCTOR SHOULD BE CONSULTED AND ALL CONTACT WITH
THIS DYE MUST CEASE IMMEDIATELY.
AFTER A 28 DAYS FEEDING STUDY WITH RATS, AT CONCENTRATION OF 50
mg/kg/day, NO TREATMENT RELATED ADVERSE EFFECTS WERE OBSERVED.
THE ACUTE TOXICITY DATA WAS TESTED ON THE ACTIVE COMPONENT.
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Swallowed : WASH OUT MOUTH WITH WATER. DRINK PLENTY OF WATER.
SEEK MEDICAL ADVICE.
Eye . . . : RINSE IMMEDIATELY WITH COOL, CLEAN RUNNING WATER
FOR AT LEAST 15 MINUTES. SEEK IMMEDIATE MEDICAL
ATTENTION.
Skin . . : CLEAN CONTAMINATED AREAS WITH SOAP AND PLENTY OF
RUNNING WATER. REMOVE CONTAMINATED CLOTHING.
Inhaled . : REMOVE PATIENT TO FRESH AIR AND REST. IF SYMPTOMS
OF ASTHMA OR BREATHING DIFFICULTIES OCCUR, SEEK
MEDICAL ATTENTION. ASSIST BREATHING (OXY-VIVA
EQUIP) UNTIL HELP ARRIVES.
First aid facility: EYE WASHES AND OXY-VIVA EQUIPMENT.
Advice to Doctor .: TREAT SYMPTOMATICALLY, NO SPECIFIC ANTIDOTE KNOWN.
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PRECAUTIONS FOR USE
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TWA : < 10 mg/m3 RECOMMENDED BY C.I.A - U.K
AVOID EXCEEDING EXPOSURE LIMITS BY USE OF VENTILATION AND/OR PERSONAL
PROTECTION
FOLLOW GOOD WORKING PRACTICE : HANDLE WITH CARE, AVOID INGESTION,
INHALATION, EYE OR SKIN CONTACT.
AVOID DUST FORMATION
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WHEREVER POSSIBLE, THE WORKPLACE MUST BE VENTILATED SUFFICIENTLY TO
ENSURE THAT THE LPL OF EXPOSURE IS ATTAINED. ANY STATE REGULATIONS ON
SPEED AND DIRECTION OF AIRFLOW AWAY FROM OPERATORS MUST BE OBSERVED.
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GLOVES (PVC, LONG IMPERVIOUS) AND OVERALLS ARE RECOMMENDED, SAFETY
GLASSES MUST BE WORN FOR EYE PROTECTION.
PARTICULATE FILTER CLASS P1 (DUST MASK) IS REQUIRED TO BE WORN WHEN
POSITIVE LOCAL VENTILATION IN OPERATION, OTHERWISE THE FOLLOWING
AS1716 RESPIRATORY PROTECTION MUST BE WORN:
HALF FACE MASK: "YES" CANNISTER TYPE: NOT APPLICABLE CARTRIDGE CLASS:
"CLASS P2" FOR POWDERS, AND "CLASS A2" FOR LIQUIDS. PRE FILTER:
RECOMMENDED. FULL FACE MASK: "SUITABLE". AIR SUPPLIED: "YES,
AIR-LINE". COMBINATION ORGANIC VAPOUR PARTICULATE TYPE A2-P2
CARTRIDGE. (MEDIUM CAPACITY/EFFICIENCY FILTER IS SUITABLE.
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KEEP AWAY FROM SOURCES OF IGNITION? - NOT APPLICABLE, NOT FLAMMABLE.
DUST CLOUDS FROM FINELY PARTICULATED PRODUCT MAY BE HAZARDOUS (DUST
EXPLOSION RISK). EQUIPMENT SHOULD BE ADEQUATELY GROUNDED.
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SAFE HANDLING INFORMATION
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General . . . . . . : STORE IN A COOL, DRY AREA WITH ADEQUATE
Storage . . . . . . : VENTILATION. KEEP CONTAINERS CLOSED.
Page 2 of 4
MSDS:
UN Number . . . . . : FREE
Dangerous Goods Class Packaging
and Subsidiary Risk : NOT APPLICABLE group . . : NOT APPLICABLE
HAZCHEM Code . . . . : NOT APPLICABLE
IATA Class . . . . . : FREE
IMDG Reference . . . : FREE
Minimum temperature : NOT APPLICABLE
Maximum temperature : NOT APPLICABLE
Incompatible DG Classes : NONE KNOWN
Incompatible Receptacle : NONE KNOWN
Incompatible Substances : NONE KNOWN
Emergency Procedure Guide Date: NOT APPLICABLE
** KEEP UNPROTECTED PERSON(S) AWAY **
** ENSURE GOOD EXHAUST VENTILATION AT THE WORKPLACE WHERE DUST
FORMATION IS POSSIBLE **
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IN CASE OF SPILL, WEAR PERSONAL PROTECTION AS INDICATED ABOVE -
'DAMPEN DOWN FIRST', 'AVOID CREATING DUST', SCOOP UP AND PLACE INTO
MARKED CONTAINERS FOR DISPOSAL AS CHEMICAL WASTE.
DISPOSE OF ALL WASTE ACCORDING TO STATE REGULATIONS. - LAND FILL: NO.
SECURE LAND FILL: NO INCINERATION: YES HIGH TEMPERATURE INCINERATION:
SUITABLE. CONTAMINATED, EMPTY CONTAINERS MUST BE DISPOSED OF AS
CHEMICAL WASTE. ** NOTE ** : IF IN DOUBT CONTACT CIBA SPECIALTY
CHEMICALS TELEPHONE NUMBER ON PAGE 1.
** KEEP UNPROTECTED PERSON(S) AWAY **
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Extinguishing Media : WATERSPRAY, CO2, FOAM, DRY POWDER - NO
RESTRICTIONS.
Hazardous combustion products:
THERMAL DECOMPOSITION OR BURNING MAY RELEASE OXIDES OF CARBON,
NITROGEN AND SULFUR. SOME HYDROGEN FLOURIDE GAS ALSO POSSIBLE. IN CASE
OF A FIRE, SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
EQUIPMENT MUST BE WORN.
** KEEP UNPROTECTED PERSON(S) AWAY **
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OTHER INFORMATION
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BOD 5 . . . . . . . . . . . : 0 mgO2/g
COD . . . . . . . . . . . . : 720 mgO2/g
Fish toxicity . . . . . . . : SPECIES : ZEBRA FISH
LC0 : 100 mg/l
LC50 : > 100 mg/l, 96 hrs OECD 203
DAPHNIA TOXICITY:
EC50 : > 100 mg/l, 48 hrs OECD 202
Toxicity to Bacteria . . . : IC50 : 1000 mg/l, 3 hrs OECD 209
OECD Biological degredation : < 10 %, DOC ANALYSIS, OECD 302B
Alga, growth inhibition . . : EC50 : > 100 mg/l, 72 hrs OECD 201
Organo-halogen content. . . : 3.3 % CHLORO
Heavy-metal content . . . . : UNDER THE ETAD RECOMMENDED LIMITS
Phosphorous content . . . . : 0.8 %
BIOELIMINATION SUMMARY: NOT READILY BIODEGRADABLE.
NITROGEN CONTENT: 11.1 %.
NOT TOXIC OR HARMFUL TO AQUATIC LIFE. BEHAVIOUR IN TREATMENT PLANTS:
NO INHIBITION. NO NITRIFICATION INHIBITION KNOWN.
TESTED MATERIAL: PRODUCT/ACTIVE COMPONENT.
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EEC classification/labelling: ** Xi ** IRRITANT
R-phrase: R41: RISK OF SERIOUS DAMAGE TO EYES.
S-phrase: S22: DO NOT BREATHE DUST;
S26: IN CASE OF CONTACT WITH EYES, RINSE
IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL
ADVICE;
S39: WEAR EYE/FACE PROTECTION.
SINCE WE CANNOT ANTICIPATE OR CONTROL THE MANY DIFFERENT CONDITIONS
UNDER WHICH THIS INFORMATION AND OUR PRODUCTS MAY BE USED, EACH USER
Page 3 of 4
MSDS:
SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE
INTENDED APPLICATION AND CONFIRM THAT THEY ARE APPROPRIATE.
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CONTACT POINT
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Contact the Product Safety Manager:
MR GRAHAM DICKINSON on 03-9282-0609 or 0412 023 891
or MR EFKAN KOCH on 03-9282-0673
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Authorised by: DEANGGU1 Date: 13 July 02
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