Safety Data Sheet according to Directive 91/155/EEC
ALCOPOL 650 Revision 15.09.2003
(dd.mm.yyyy)
1. Identification of the Substance/Preparation and the Company/Undertaking
Product name ALCOPOL 650
Chemical identification Fatty alcohol ethxoylate solution
CAS Number Preparation
Use Surface-active agent
Producer/Supplier CIBA SPEZIALIT脛TENCHEMIE AG
KLYBECKSTRASSE 141
POSTFACH
4002 BASEL
SWITZERLAND
Phone Number +41 (61) 6361111
Telefax +41 (61) 6361212
Information Product Safety and Regulatory Affairs
Telefax +41 (61) 6368601
Emergency Phone Number (24h) +41 (61) 6965151
2. Composition/Information on Ingredients
Substances presenting a health or environmental hazard
EC-Number CAS Number Chemical Name Content Symbol(s) R-Phrase(s)
061827-42-7 Poly(oxy-1,2-ethanediyl), .alpha.-isodecyl- 50 - 100 % Xi R41
.omega.-hydroxy- (9CI)
3. Hazards Identification
Classified as hazardous according to the EU directives.
Xi Irritant
Risk of serious damage to eyes.
May cause slight skin irritation, especially with repeated or prolonged exposure.
May cause irritation to the respiratory system, if mists or sprays may be inhaled.
4. First Aid Measures
Skin contact
Wipe with absorbent paper or textile towels. Wash off with soap and plenty of water. Do not use organic solvents. In
case of dermatitis, seek medical attention.
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. In case of eye irritation, seek medical attention.
Inhalation
Move to fresh air. In case of irritation of respiratory system or mucous membranes, seek medical attention. In case of
indisposition, seek medical attention. In case of prolonged exposure, seek medical attention.
Ingestion
Immediately give plenty (> 500 ml) of water (if possible charcoal slurry). In case of spontaneous vomiting be sure that
vomitus can freely drain due to danger of suffocation. Give water repeatedly. Artificial induction of vomiting should be
restricted to first aid staff. Give nothing by mouth in cases of unconsciousness or convulsion. Seek medical advice.
5. Fire-Fighting Measures
Suitable extinguishing media
Water spray, Carbon dioxide (CO2), Foam, Dry powder
Print Date 15.09.2003 1/5 (13212 A/+EU/E/4)
Safety Data Sheet according to Directive 91/155/EEC
ALCOPOL 650 Revision 15.09.2003
(dd.mm.yyyy)
Extinguishing media which must not be used for safety reasons
High volume water jet
Exposure hazards
Contaminated water from fire hoses or sprinklers, etc., must be prevented from draining into watercourses, sewers, or
the ground water. Sufficient measures must be taken to retain water used for extinguishing. Contaminated water and soil
must be disposed of in conformity with local regulations.
Special protective equipment for firefighters
Wear full protective clothing. Wear self-contained breathing apparatus.
Combustion products
Oxides of carbon; Toxic gases/vapours
6. Accidental Release Measures
Personal precautions
Do not breathe vapours/dust. Remove all sources of ignition. Avoid contact with skin, eyes and clothing.
Environmental precautions
Do not flush into surface water, sanitary sewer or ground water system.
Methods for cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect the spilled
product into suitable containers, which must be tightly sealed and properly labelled. Contain washwater and dispose of
in accordance with local regulations.
7. Handling and Storage
Handling
Harmful. Irritant. Handle and open container with care. Ensure good local exhaust ventilation. Do not eat, drink or smoke
at the workplace.
Storage
Keep away from food and drink. Store in the original container securely closed.
Protect from frost.
8. Exposure Controls / Personal Protection
Exposure limit(s)
CIEL-TWA Ciba internal exposure limit (8 hour time weighted average)
not tested
Technical measures/Precautions
No special precautions required.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment.
Hand protection
Protective gloves
Eye protection
Suitable goggles or face protection
Skin and body protection
Working clothes , Closed footwear
9. Physical and Chemical Properties
Form liquid
Colour colourless
Odour mild
Melting/freezing temperature not applicable
Boiling point/range ca 100 掳C
Relative density 0.98 g/cm3 Typical Value
Flash point > 100 掳C
Print Date 15.09.2003 2/5 (13212 A/+EU/E/4)
Safety Data Sheet according to Directive 91/155/EEC
ALCOPOL 650 Revision 15.09.2003
(dd.mm.yyyy)
Ignition Temperature not applicable
Oxidising properties not tested
Self-ignition temperature not applicable
Assessment for water solubility soluble
Solubility not tested
Vapour pressure 25 掳C 32 mbar Typical Value
Partition coefficient; Log Pow not tested
pH-value 7.0 Typical Value
Kinematic viscosity not tested
Explosive properties not applicable
Evaporation rate not tested
Vapour density not tested
10. Stability and Reactivity
Decomposition temperature not tested
Conditions to avoid No special conditions.
Materials to avoid Strong acids, strong bases and
strong oxidising agents.
Hazardous decomposition products Oxides of carbon, Toxic
gases/vapours
11. Toxicological Information
Acute oral toxicity < 2000 mg/kg Conventional
LD50
Rat Method
Acute dermal toxicity not tested
Acute Inhalation Toxicity not tested
Acute eye irritation/corrosion risk of serious damage to Conventional
Rabbit eyes Method
Acute dermal not irritant Conventional
irritation/corrosion Method
Rabbit
Acute skin sensitisation not tested
12. Ecological Information
Acute toxicity to fish not tested
Acute toxicity to daphnia not tested
Acute toxicity to bacteria not tested
Acute toxicity to algae not tested
Print Date 15.09.2003 3/5 (13212 A/+EU/E/4)
Safety Data Sheet according to Directive 91/155/EEC
ALCOPOL 650 Revision 15.09.2003
(dd.mm.yyyy)
Biodegradability not tested
Ecotoxic effects
Do not discharge product uncontrolled into the environment.
13. Disposal Considerations
Waste from residues / unused products
Residual chemical should be disposed by incineration or by other modes of disposal in compliance with local legislation.
Contaminated packaging
Contaminated packaging material should be treated equivalent to residual chemical. Clean packaging material should be
subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
14. Transport Information
Flash point > 100 掳C
ADR/RID Class: Free
IMO Class: Free
ICAO Class: Free
15. Regulatory Information
Classification Self-classification
Symbol(s) Xi Irritant
R-Phrase(s) R41 Risk of serious damage to eyes.
S-Phrase(s) S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S39 Wear eye/face protection.
Contains Fatty alcohol ethoxylate
Additional labeling information Safety data sheet available for professional user on request.
16. Other Information
R-phrases from chapter 2 R41 Risk of serious damage to eyes.
Essential changes Section 2 ; Section 3 ; Section 11 ; Section 15
ALCOPOL is a registered trademark.
Print Date 15.09.2003 4/5 (13212 A/+EU/E/4)
Safety Data Sheet according to Directive 91/155/EEC
ALCOPOL 650 Revision 15.09.2003
(dd.mm.yyyy)
Important
THIS MATERIAL IS NOT INTENDED FOR USE IN PRODUCTS FOR WHICH PROLONGED
CONTACT WITH MUCOUS MEMBRANES, BODY FLUIDS OR ABRADED SKIN, OR
IMPLANTATION WITHIN THE HUMAN BODY, IS SPECIFICALLY INTENDED, UNLESS THE
FINISHED PRODUCT HAS BEEN TESTED IN ACCORDANCE WITH NATIONALLY AND
INTERNATIONALLY APPLICABLE SAFETY TESTING REQUIREMENTS. BECAUSE OF THE
WIDE RANGE OF SUCH POTENTIAL USES, CIBA IS NOT ABLE TO RECOMMEND THIS
MATERIAL AS SAFE AND EFFECTIVE FOR SUCH USES AND ASSUMES NO LIABILITY FOR
SUCH USES.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity
with any legal regulation. The information contained herein is based on the present state of our knowledge and is
intended to describe our products from the point of view of safety requirements. It should not therefore be construed as
guaranteeing specific properties.
Print Date 15.09.2003 5/5 (13212 A/+EU/E/4)
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