MATERIAL SAFETY DATA SHEET
Date: 10/29/2003 rev 12/2008 P/N: 20414, 21048, 20659 ?Quadra-K Page 1 of 4
1. Product and Identification
Product Name : Quadra-K Black Ink for Film Positives
Product Number : 99AQK Series Inks
Chemical Name : Inkjet Printing Fluid
Chemical Family : Blend
CAS Number : Blend
2. Composition / Information on Ingredients
Chemical Name Amount CAS number OSHA PEL ACGIH
Dyestuff 10.0 ?25% Blend (1) N/E N/E
Water 70.0 ?95.0% 7732-18-5
Deactivator e 10.0 ?25% Trade Secret N/E N/E
2璓yrol 1.0 ?15% 616-45-5 N/E N/E
Surfactant 1.0 ?15% Trade Secret N/E N/E
Remaining ingredients not considered hazardous under the criteria of OSHA Hazard Communication Standard 29CFR
1910.1200.
Composition Comment: (1) The identity of this dye is considered proprietary by the manufacturer.
3. Hazards Identification
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Emergency Overview
Black liquid with slight odor. This product presents little or no hazard of spilled, and no unusual hazard if involved in a fire.
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EYE : May cause slight irritation.
SKIN : May cause allergic reaction.
INHALATION : May cause irritation if inhaled.
INGESTION : May be harmful if swallowed.
CARCINOGENICITY INFORMATION : No known cancer hazard.
MacDermid Autotype Inc Phone +1-847-818-8262 Toll Free +1-800-323-0632
1675 Winnetka Circle Fax +1-847-818-8280
Rolling Meadows, IL 60008 www.macdermidautotype.com
MATERIAL SAFETY DATA SHEET
Date: 10/29/2003 rev 12/2008 P/N: 20414, 21048, 20659 ?Quadra-K Page 2 of 4
4. FIRST AID MEASURES
EYE CONTACT FIRST AID : Immediately flush eyes with plenty of water. Get medical attention if irritation
develops or persists.
SKIN CONTACT FIRST AID : Wash with soap and water, get medical attention if irritation develops or persists,
wash clothing before reuse.
INHALATION FIRST AID : Although this product is not know to cause respiratory problems, if breathing is
difficult, remove to fresh air and get attention.
INGESTION FIRST AID : If swallowed, get medical attention.
5. FIRE FIGHTING MEASURES
FLAMABLE PROPERTIES : Will not burn.
EXTINGUISHING MEDIA : Use extinguishing media appropriate to surrounding fire.
NFPA RATING : Health ?1, Flammability ?0, Reactivity ?0, Special Hazards ?None.
FIRE AND EXPLOSION HAZARDS : None
FIRE FIGHTING INSTRUTIONS : As in any fire, wear positive pressure self-contained breathing apparatus and full
protective gear.
COMBUSTION PRODUCTS : Decomposition may produce oxides of carbon, nitrogen, sulfur, hydrocarbons, fumes
and smoke.
6. ACCIDENTAL RELEASE MEASURES
SAFEGUARDS (PERSONNEL) : Protect eyes and skin from exposure. Wear appropriate personal protective
equipment. If vapors or mists are generated, wear a NIOSH approved respirator.
CLEAN UP PROCEDURE : Absorb spills with inter material, (e.g. vermiculite, dry sand or earth), treat and dispose
of waste material in accordance with all local, state/provincial, and national requirements.
7. HANDLING AND STORAGE
HANDLING (PERSONNEL) : Avoid contact with eyes, skin and clothing, avoid breathing mists, wash hands
thoroughly after handling.
STORAGE PRECAUTIONS : Keep out of the reaach of children. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINERING CONTROLS : No special ventilation requirements, good general ventilation should be sufficient to
control airborne levels.
EYE/FACE PROTECTION REQUIREMENTS : Wear safety glasses or goggles if splashing is possible.
MATERIAL SAFETY DATA SHEET
Date: 10/29/2003 rev 12/2008 P/N: 20414, 21048, 20659 ?Quadra-K Page 3 of 4
SKIN PROTECTION REQUIREMENTS : Avoid unnecessary skin contact, wear gloves and sleeves. Wash hands
thoroughly after handling.
RESPIRATORY PROTECTION REQUIREMENTS : Under normal use conditions, with adequate ventilation, no
special handling equipment is required.
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: Liquid
COLOR: Black
ODOR: Faint odor
BOILING POINT: ~100 C
VAPOR PRESSURE: N/E Kg/Cm^2
VAPOR DENSITY: N/E (Air = 1)
SOLUBILITY IN WATER: Miscible
MELTING/FREEZING POINT: ~0 C
PH: 7.0 +/- 1.0
% VOLATILES: N/E
VOLATILE ORGANIC COMPOUNDS: (VOC): N/E
10. STABILITY AND REACTIVITY
STABILITY: Stable
POLYMERIZATION: Hazardous polymerization will not occur.
INCOMPAITBILITY WITH OTHER MATERIALS: Incompatible or can react with acids, bases and oxidizers.
DECOMPOSITION: In the case of fire, oxides of carbon, nitrogen, sulfur, hydrocarbons, fumes and smoke may be
produced.
CONDITIONS TO AVOID: None
11. TOXICOLOGICAL INFORMATION
MISCELLANEOUS: The components of this product are not listed by the NTP, IARC, or regulated as a carcinogen
by OSHA. Although not tested, may cause minor irritation based on the ingredients of the product.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL HAZARD: No information available.
13. DISPOSAL COSIDERATION
WASTE DISPOSAL: Treat or dispose of waste in accordance with all local, state/provincial, and national
requirements.
EWC CODE: 08032
MATERIAL SAFETY DATA SHEET
Date: 10/29/2003 rev 12/2008 P/N: 20414, 21048, 20659 ?Quadra-K Page 4 of 4
14. TRANSPORTATION INFORMATION
PRODUCT LABEL: Black Ink for Autotype Film Positives
MISCELLANEOUS: Not a regulated article under DOT, IATA, ADR, or RID.
15. REGULATORY INFORMATION
REGULATORY DISCLOSURES
CALIFORNIA PROPOSITION 65: This product contains no chemicals known to the state of California to cause
cancer, birth defects, or other reproductive harm.
SARA TITLE III, 311/312: this product has been reviewed according to EPA "Hazard Categories" promulgated
under section 311 and 312 of SARA TITLE III, and is considered, under definition, to be an immediate/acute health
hazard.
EEC SYMBOLS AND INDICATIONS OF DANGER: None
R-PHRASES: R36/38 ?Irritating to the eyes and skin.
S-PHRASES: S24/25 ?Avoid contact with skin and eyes.
WHMIS HAZARD SYMBOLS: None
MISCELLANEOUS INFORMATION: This material or all of it's components are listed on the inventory of Existing
Chemicals Substances under the Toxic Substance Control Act (TSCA).
16. OTHER INFORMATION
HMIS RATING: Health ?1, Flammability ?0, Reactivity ?0, Personal Protection Index ?0
ABBREVIATIONS USED IN THIS MSDS: N/A Not available, N/E Not Established
ADDITIONAL INFORMATION: The data in this Material Safety Data Sheet relates to only the specific material
designated herein. It does not relate to use in combination with any other material or in any process.
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The information contained herein is, to the best of our knowledge and belief, accurate. Since the condition of
handling and use are beyond our control, we assume no liability for loss or injury resulting from the use of this
product or the information herein. All chemicals may present unknown health hazards and should be used with
caution. Safe use of this product is the responsibility of the user. No representations or warranties, either
expressed or implied, of merchantability, fitness for a particular purpose or any other nature are made hereunto
with respect to the information contained herein or the product to which the information refers.
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END OF MSDS
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