MATERIAL SAFETY DATA SHEET
REMANUFACTURED CANON CL-31
SECTION 1: IDENTIFICATION
Clover Technologies (815) 431-8100
MANUFACTURER: EMERGENCY NUMBER:
ADDRESS: 4200 Columbus St. INFORMATION NUMBER: (815) 431-8100
Ottawa, IL 61350 DATE OF REVISION: September 12, 2008
SECTION 2: PRODUCT COMPONENTS
INGREDIENTS CAS#. Cyan WT.% Magenta WT.% Yellow WT.%
Diethylene Glycol 111-46-6 1 - 10 1 - 10 1 - 10
2-Pyrrolidone 616-45-5 1 - 10 1 - 10 1 - 10
Glycerin 56-81-5 1-5 1-5
Diethylene Glycol Monobutyl Ether 112-34-5 1-5
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: This product contains cyan (blue), magenta (red), and yellow liquids with a mild odor.
CAUTION! May cause eye and skin irritation. Inhalation of vapors may cause irritation, headache, nausea and central nervous
system effects. Prolonged overexposure may cause damage to the liver and kidneys. May be absorbed through the skin to cause
effects similar to inhalation. Aspiration during swallowing or vomiting may cause lung damage.
See Section 11 for detailed health effects information.
SECTION 4: EMERGENCY and FIRST AID PROCEDURES
INGESTION: Call a poison control center or doctor immediately for treatment advice. If conscious, give one 8 ounce glass of
water to dilute. DO NOT induce vomiting unless directed by medical personnel. Do not give anything by mouth to or induce
vomiting in a person who is unconscious or convulsing.
SKIN CONTACT: Remove contaminated clothing. Wash contact area thoroughly with soap and water. Get medical attention if
irritation develops and persists. Launder contaminated clothing before reuse. Discard contaminated clothing such as shoes that
cannot be decontaminated.
EYE CONTACT: Flush eyes with water for 15 minutes while lifting the upper and lower lids. Get medical attention.
INHALATION: Remove victim to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult have
qualified personnel administer oxygen. Get medical attention.
SECTION 5: FIRE and EXPLOSION HAZARD DATA
FLASH POINT: None
AUTOIGNITION TEMPERATURE: Not available
FLAMMABLE LIMITS: (vol % in air) LEL: 0.8% (diethylene glycol monobutyl ether)
UEL: 24.6% (diethylene glycol monobutyl ether)
EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide and dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should wear full emergency equipment and NIOSH approved
positive pressure self-contained breathing apparatus. Cool fire exposed containers and structures with water.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide, tetrahydrofuran and oxides of nitrogen.
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MATERIAL SAFETY DATA SHEET
REMANUFACTURED CANON CL-31
SECTION 6: ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear appropriate protective clothing as
described in Section 8. Dike spill and absorb with an inert material. Collect into closable containers for proper disposal. . Report
spill as required by local and federal regulations.
SECTION 7: HANDLING and STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers from physical damage. Store in a cool
(68癋), dry area away from oxidizers and other incompatible materials.
Avoid contact with eyes, skin and clothing. Avoid breathing vapors. Use with adequate ventilation. Remove and launder
contaminated clothing before re-use. Wash thoroughly after handling and before eating, drinking, smoking or using toilet facilities.
SECTION 8: EXPOSURE CONTROLS and PERSONAL PROTECTION
INGREDIENTS CAS#. EXPOSURE LIMITS
10 mg/m3 TWA AIHA WEEL
Diethylene Glycol 111-46-6
2-Pyrrolidone 616-45-5 None Established
5 mg/m3 TWA OSHA PEL (respirable fraction) 10 mg/m3
Glycerin 56-81-5
TWA ACGIH TLV
Diethylene Glycol 112-34-5 None Established
Monobutyl Ether
EXPOSURE LIMITS: Use in a well ventilated area.
PERSONAL PROTECTIVE EQUIPMENT: Select in accordance with OSHA 1910.134 and good Industrial Hygiene practice.
PROTECTIVE CLOTHING: Use personal protective equipment to minimize exposure to skin and eye.
SECTION 9: PHYSICAL and CHEMICAL PROPERTIES
BOILING POINT (@760 mmHg): 212癋 FREEZING POINT: Not available
SPECIFIC GRAVITY (H20=1): 1.00 ?1.10 COEFFICIENT of WATER/OIL: Not available
VAPOR PRESSURE: 17.5 mmHg EVAPORATION RATE: < Butyl Acetate
VAPOR DENSITY (Air=1): Heavier than air pH: 6.5-8.5
SOLUBILITY IN WATER: Complete
APPEARANCE: Cyan, Magenta, and Yellow liquids.
SECTION 10: STABILITY and REACTIVITY
STABILITY: Stable.
CONDITIONS TO AVOID: None known.
INCOMPATIBILITY: Strong oxidizing agents, strong acids and strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield carbon monoxide, carbon dioxide,
tetrahydrofuran, and nitrogen oxides.
HAZARDOUS POLYMERIZATION: Will not occur.
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MATERIAL SAFETY DATA SHEET
REMANUFACTURED CANON CL-31
SECTION 11: TOXICOLOGICAL INFORMATION
EYE CONTACT: May cause mild irritation with redness and tearing
SKIN CONTACT: Contact may cause mild skin irritation.
INHALATION: Vapors or mists may cause respiratory irritation with headache, dizziness, nausea, drowsiness, incoordination,
euphoria, visual disturbances, fatigue and unconsciousness.
INGESTION: Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea, severe metabolic acidosis and damage
to the kidneys and liver. Aspiration into the lungs during swallowing or vomiting may cause lung damage.
CHRONIC EFFECTS of OVEREXPOSURE: Prolonged exposure may cause dermatitis. Prolonged or repeated over exposure
may cause damage to the kidneys or liver. Diethylene glycol has been found to be positive in the Ames Assay for mutagenicity.
CARCINOGENICITY: None of the components of this product are listed as a carcinogen by NTP, IARC or OSHA. 2-
pyrrolidione was found to cause birth defects in studies with laboratory animals.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with chronic skin, respiratory, kidney and liver
disorders may be at increased risk from exposure to this material.
TOXICOLOGY DATA: Toxicity values for this chemical are:
Diethylene Glycol: Oral rat LD50: 12,565 mg/kg
Skin Rabbit LD50: 11,890 mg/kg
2-Pyrrolidone: Oral rat LD50: 6,500 mg/kg
Glycerin: Oral rat LD50: 12,600 mg/kg
Skin Rabbit LD50: >10,000 mg/kg
Inhalation Rat LC50: >570 mg/m3/1 hour
Diethylene Glycol Monobutyl Oral rat LD50: 5,660 mg/kg
Ether:
SECTION 12: ECOLOGICAL INFORMATION
Diethylene Glycol: No data available
2-Pyrrolidone: EC50/48 hr daphnia magna > 500 mg/l
LC50/48 hour golden orfe >500 mg/l
Glycerin: No data available
Diethylene Glycol Monobutyl LC50/24 hr Goldfish 2700 mg/l
Ether:
LC50/96 hour menidia beryllina 2000 ppm
SECTION 13: DISPOSAL INFORMATION
WASTE DISPOSAL METHOD: Dispose of in accordance with all local, state and federal regulations.
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MATERIAL SAFETY DATA SHEET
REMANUFACTURED CANON CL-31
SECTION 14: TRANSPORTATION INFORMATION
DOMESTIC TRANSPORTATION
DOT SHIPPING NAME: Not Regulated
DOT HAZARD CLASSIFICATION: Not Regulated
DOT LABELS REQUIRED (49CFR172.101): Not Applicable
UN NUMBER: None
INTERNATIONAL TRANSPORTATION
IMDG SHIPPING NAME: Not Regulated
IMDG CLASS: Not Regulated
UN NUMBER: Not Applicable
IMDG LABEL: None
SECTION 15: REGULATORY INFORMATION
OSHA HAZARD CLASSIFICATION: Irritant, target organ effects
EPA SARA 311 HAZARD CLASSIFICATION: Acute health
SARA TITLE 111 SECTION 313 INFORMATION: This product contains the following chemicals that are regulated under
SARA 313:
COMPONENT CAS # WT%
Glycol Ethers 112-34-5 1 ?10
(Diethylene Glycol Monobutyl Ether)
CERCLA HAZARDOUS SUBSTANCE (40CFR 116): Not applicable
REPORTABLE QUANTITY: Not applicable
CALIFORNIA PROPOSITION 65 INFORMATION: This product contains no California Proposition 65 regulated chemicals.
WHMIS CLASSIFICATION: Class D - Division 2 - Subdivision B (Toxic material causing other chronic effects)
SECTION 16: OTHER INFORMATION
NFPA Rating: Health = 1 Fire = 0 Reactivity = 0
HMIS Rating: Health = 1 Fire = 0 Reactivity = 0
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