MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, European Union Standards, Australian WorkSafe, and the Japanese Industrial Standard JIS Z 7250: 2000
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
Silverback Ink
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Water-Based Ink
SYNONYMS: Not Applicable
PRODUCT USE: Various Uses
U.N. NUMBER: None Allocated
U.N. DANGEROUS GOODS CLASS/SUBSIDIARY RISK: None Allocated
HAZCHEM CODE (AUSTRALIA): None Allocated
POISONS SCHEDULE NUMBER (AUSTRALIA): None Allocated
SUPPLIER/MANUFACTURER'S NAME: SILVERBACK INK
ADDRESS: 4869 Fountain Ave
Los Angeles, CA 90029, USA
INFORMATION PHONE: 01-323-244-1967
EMERGENCY PHONE: (800) 424-9300 (CHEMTREC)
INTERNATIONAL: 1-703-527-3887
SUPPLIER/IMPORTER'S NAME (AUSTRALIA):
ADDRESS:
EMERGENCY PHONE:
BUSINESS PHONE:
DATE OF PREPARATION: March 8, 2007
2. COMPOSITION and INFORMATION ON INGREDIENTS
EU LABELING/CLASSIFICATION: This product does not meet the definition of any hazard class, as defined by the
European Union Council Directives 67/548/EEC and 2001/59/EC. (See Section 15 for details on classification)
CHEMICAL NAME CAS # EINECS # % w/v EU CLASSIFICATION FOR COMPONENTS
SILVERBACK INK X1 & SILVERBACK INK X2
HAZARD CLASSIFICATION: Not applicable
Witch Hazel 68916-39-2 Unlisted 30?0
RISK PHRASES: Not applicable
Proprietary Black Pigment HAZARD CLASSIFICATION: Not classified by manufacturer
3?
RISK PHRASES: Not applicable
None of the other components in this product contribute significantly to the
Water and other components. Each of the other components is present Balance
hazards associated with this product. All hazard information relevant to this
in less than 1 percent concentration (0.1% concentration for potential
product is provided in this Material Safety Data Sheet, per the requirements of
carcinogens, reproductive toxins, respiratory tract sensitizers, and
the US Federal Occupational Safety and Health Administration Standard (29
mutagens).
CFR 1910.1200), US State equivalent standards, and Canadian Workplace
Hazardous Materials Identification System Standards (CPR 4).
SILVERBACK INK X3 & SILVERBACK INK X4
HAZARD CLASSIFICATION: Not applicable
Witch Hazel 68916-39-2 Unlisted 30?0
RISK PHRASES: Not applicable
Proprietary Black Pigment HAZARD CLASSIFICATION: Not classified by manufacturer
7?3
RISK PHRASES: Not applicable
None of the other components in this product contribute significantly to the
Water and other components. Each of the other components is present Balance
hazards associated with this product. All hazard information relevant to this
in less than 1 percent concentration (0.1% concentration for potential
product is provided in this Material Safety Data Sheet, per the requirements of
carcinogens, reproductive toxins, respiratory tract sensitizers, and
the US Federal Occupational Safety and Health Administration Standard (29
mutagens).
CFR 1910.1200), US State equivalent standards, and Canadian Workplace
Hazardous Materials Identification System Standards (CPR 4).
See Section 15 for full EU classification information of product and components.
NOTE: ALL Canadian WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance
with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. The MSDS is also prepared to include all European Union required
information under EU Directives.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Product Description: This product is a black liquid that has a mild witch hazel odor.
Health Hazards: The primary health hazard associated with this material is the potential for mild irritation of
contaminated tissue. The ink may stain skin, eyes, other contaminated tissue, and objects. Flammability Hazards: This
material is not flammable. Reactivity Hazards: This material is not reactive. Environmental Hazards: This material
may have adverse effects when released into the environment. Emergency Recommendations: Emergency
responders must wear the personal protective equipment suitable for the situation to which they are responding.
SILVERBACK INK MSDS
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3. HAZARD IDENTIFICATION (Continued)
EU LABELING/CLASSIFICATION: This product does not meet the
definition of any hazard class, as defined by the European Union Council HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
Directives 67/548/EEC and 2001/59/EC. (See Section 15 for details on
classification)
(BLUE) 1
HEALTH HAZARD
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most
significant routes of occupational overexposure are inhalation and contact
with skin and eyes. The symptoms of overexposure to this material, via route
of entry, are as described on the following page.
FLAMMABILITY HAZARD (RED) 0
INHALATION: This product does not normally present a significant inhalation
hazard under anticipated circumstances of use. Inhalation of vapors, mists,
or sprays of this material, may mildly irritate the nose, throat, and other
tissues of the respiratory system.
PHYSICAL HAZARD (YELLOW) 0
CONTACT WITH SKIN or EYES: Due to the colorants, skin contact may
discolor contaminated areas. Skin contact may cause mild irritation in
sensitive individuals. Repeated or prolonged skin overexposure may cause
PROTECTIVE EQUIPMENT
dermatitis (dry, red skin). Eye contact with this material can mildly irritate the
eyes, causing discomfort, tearing, and redness. Because the eye tissue may
be stained, vision may be temporarily blurred. EYES HANDS BODY
RESPIRATORY
SKIN ABSORPTION: The components of this product are not known to be
absorbed through intact skin. SEE SECTION 8 SEE SECTION 8
INGESTION: Though not anticipated to be a significant route of occupational
exposure, ingestion of large quantities of this material may cause nausea,
vomiting, diarrhea, and discoloration of the mouth, teeth, and tissues of the For Routine Industrial Use and Handling Applications
throat. Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
INJECTION: Accidental injection of this liquid (as may occur by a puncture 3 = Serious 4 = Severe * = Chronic hazard
with a contaminated object) will cause local pain, irritation, and redness.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of overexposure, the
following symptoms may be observed:
ACUTE: The ink may stain hair, skin, and other contaminated tissue. Acute exposure to this material via skin contact, eye
contact, and inhalation may mildly irritate contaminated tissue. Ingestion of large amounts may cause nausea, vomiting,
diarrhea.
CHRONIC: Repeated or prolonged skin overexposure may cause dermatitis (dry, red skin). Refer to Section 11
(Toxicology Information) for additional data.
TARGET ORGANS: ACUTE: Skin, central nervous system, eyes. CHRONIC: Skin, kidneys, liver, reproductive system.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for
medical attention if necessary. Take a copy of the label and MSDS to health professional with victim.
SKIN EXPOSURE: If this material contaminates the skin, immediately begin decontamination with running water and soap.
The minimum recommended flushing time is 15 minutes. Remove exposed or contaminated clothing, taking care not to
contaminate eyes. The contaminated individual must seek medical attention if any adverse effect occurs.
EYE EXPOSURE: If vapors, sprays, or mists of this material enter the eyes, open the contaminated individual's eyes while
under gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum
flushing is for 15 minutes. The contaminated individual must seek medical attention if any adverse effect occurs.
INHALATION: If vapors, sprays, or mists of this material are inhaled, remove the contaminated individual to fresh air. If
necessary, remove or cover gross contamination to avoid exposure to rescuers. Seek medical attention if adverse effect
occurs.
INGESTION: If this material is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water if
conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or
unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down position if possible) to
maintain an open airway and prevent aspiration.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing dermatitis and other skin conditions may be
aggravated by prolonged overexposures to this material.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
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5. FIRE-FIGHTING MEASURES
FLASH POINT: Not flammable.
NFPA RATING
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %): FLAM MAB ILITY
Not applicable.
Not applicable.
0
FIRE EXTINGUISHING MATERIALS:
Water Spray: YES (for cooling) Carbon Dioxide: YES
1 0
HEALTH INSTAB ILITY
Foam: YES Dry Chemical: YES
Halon: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire, this
material may decompose and produce irritating vapors and toxic gases (e.g.,
carbon oxides). OTHER
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
Explosion Sensitivity to Static Discharge: Not sensitive. 3 = Serious 4 = Severe
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should
wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment.
Due to the presence of colorants, the runoff water from these products can discolor contaminated objects. If possible,
prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. If necessary,
rinse fire-response equipment with soapy water before returning it to service.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: For incidental spills (e.g., less than 1 L of liquid from a bottle), wear rubber gloves,
splash goggles, and appropriate body protection. Trained personnel following pre-planned procedures should handle
non-incidental releases (e.g., 10 L of liquid leaking from a crate of several containers). In the event of a non-incidental
spill, clear the area and protect people. The minimum personal protective equipment for response to a non-incidental spill
is as follows: rubber gloves, rubber boots, face shield, and Tyvek suit. The minimum level of personal protective
equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B: triple-gloves
(rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-
Contained Breathing Apparatus. Absorb spilled liquid with polypads or other suitable absorbent materials. Rinse area
thoroughly with soapy water after liquid has dried. Decontaminate the area thoroughly. If necessary, discard all stained
response equipment or rinse with soapy water before returning such equipment to service. Place all spill residue in an
appropriate container and seal. Dispose of in accordance with applicable U.S. Federal, State, and local procedures or
appropriate standards of Canada, Australia, or EU Member States (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this material ON YOU or IN YOU. Wash
thoroughly after handling this material. Do not eat, drink, smoke, or apply cosmetics while handling this material. Avoid
breathing vapors or mists generated by this material. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Keep container tightly closed when not in use. Store containers in a cool, dry location, away from direct sunlight, sources of
intense heat, or where freezing is possible. Store containers away from incompatible chemicals (see Section 10, Stability
and Reactivity). Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged.
Empty containers may contain residual liquid or vapors; therefore, empty containers should be handled with care.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if
necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures and
appropriate Canadian standards.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained
below the limits provided in this section. Use local exhaust ventilation. Normal office ventilation conforming to the American
Society of Heating, Refrigerating, and Air Conditioning Engineers (ASHRAE) Standards is adequate under normal
circumstances of use. Persons using this material should consult a qualified Ventilation Engineer and/or Industrial Hygienist
if concerns about exposures arise. If necessary, refer to Australian National Code of Practice for the Control of Workplace
Hazardous Substances [NOHSC: 2007 (1994)] for further information. As with all chemicals, ensure proper
decontamination equipment (e.g., eyewash/safety shower stations) is available near areas where this material is used as
necessary.
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8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
EXPOSURE LIMITS/GUIDELINES:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
NIOSH-RELs NIOSH
ACGIH-TLVs OSHA-PELs OTHER
TWA STEL TWA STEL TWA STEL IDLH
ppm ppm ppm ppm ppm ppm ppm ppm
Witch Hazel 68916-39-2 NE NE NE NE NE NE NE NE
Proprietary Black Pigment NE NE NE NE NE NE NE NE
NE = Not Established. See Section 16 for Definitions of Terms Used.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: Not established.
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations
found in 29 CFR Subpart I (beginning at 1910.132), equivalent standards of Canada (including CSA Standard Z94.4-02 and CSA Standard
Z94.3-02), standards of EU member states (including EN 529:2005 for respiratory PPE, CEN/TR 15419:2006 for hand protection, and CR
13464:1999 for face/eye protection), or standards of Australia (including AS/NZS 1715:1994 for respiratory PPE, AS/NZS 4501.2:2006 for
protective clothing, AS/NZS 2161.1:2000 for glove selection, and AS/NZS 1336:1997 for eye protection). Please reference applicable
regulations and standards for relevant details.
RESPIRATORY PROTECTION: Respiratory protection is not generally needed when using this product. Maintain airborne
contaminant concentrations below limits listed in this section. In instances where inhalable mists or sprays of product may
be generated, and respiratory protection is necessary, use only respiratory protection authorized in the U.S. Federal OSHA
Respiratory Protection Standard (29 CFR 1910.134), or equivalent U.S. State standards, Canadian CSA Standard Z94.4-
02, the European Standard EN 529:2005, and EU member states, or the Australian Standard 1716-Respiratory Protective
Devices, the Australian Standard 1715-Selection, Use, and Maintenance of Respiratory Protective Devices, as well as
requirements of Japan. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-
facepiece pressure/demand SCBA or a full facepiece, SAR with auxiliary self-contained air supply is required under OSHA's
Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: Depending on the use of this product, splash goggles or safety glasses may be worn. Use goggles or
safety glasses for spill response, as stated in Section 6 (Accidental Release Measures) of this MSDS. If necessary, refer to
U.S. OSHA 29 CFR 1910.133, the European Standard CR 13464:1999 and the Canadian CSA Standard Z94.3-02,
Industrial Eye and Face Protectors, the Australian Standard 1337-Eye Protection for Industrial Applications and Australian
Standard 1336-Recommended Practices for Eye Protection in the Industrial Environment, as well as requirements of
Japan for further information.
HAND PROTECTION: Wear butyl rubber, neoprene, or nitrile rubber or latex gloves for routine use. If necessary, refer to
U.S. OSHA 29 CFR 1910.138 appropriate Standards of Canada, the European Standard CEN/TR 15419:2006 or the
Australian Standard 2161-Industrial Safety Gloves and Mittens for further information.
BODY PROTECTION: Use body protection appropriate for task, such as a lab coat. If necessary, use body protection
appropriate for task (e.g., Tyvek suit, rubber apron). If necessary, refer appropriate Standards of Canada, the European
Standard CEN/TR 15419:2006 the to Australian Standard 3765-Clothing for Protection Against Hazardous Chemicals for
further information. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the
soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in U.S.
OSHA 29 CFR 1910.136 and the Canadian CSA Standard Z195-02, Protective Footwear.
9. PHYSICAL and CHEMICAL PROPERTIES
VAPOR DENSITY (air = 1): Not established. EVAPORATION RATE (n-BuAc = 1): Not established.
SPECIFIC GRAVITY (water = 1): Not established. MELTING/FREEZING POINT: Not established.
SOLUBILITY IN WATER: Soluble BOILING POINT: Not established
VAPOR PRESSURE: Not established. pH: Not established.
ODOR THRESHOLD: Not established.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
APPEARANCE, ODOR AND COLOR: This product is a black liquid that has a mild witch hazel odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The odor and color of this product may be distinguishing
characteristics.
10. STABILITY and REACTIVITY
STABILITY: Stable under conditions of normal temperature and pressure.
DECOMPOSITION PRODUCTS: If exposed to extremely high temperatures, this product can decompose to generate
carbon oxides.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers, water-reactive materials.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Exposure to or contact with extreme temperatures and incompatible chemicals.
SILVERBACK INK MSDS
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PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Specific toxicology data currently available for components of this product listed in Section 2 (Composition
and Information on Ingredients) by CAS # are as follows.
WITCH HAZEL:
TDLo (Subcutaneous-Rat) 2920 mg/kg/73 weeks-intermittent: Tumorigenic: equivocal tumorigenic agent by RTECS criteria, tumors at site of application
Mutation in Microorganisms (Bacteria-Salmonella typhimurium) 5 mg/plate
SUSPECTED CANCER AGENT: The components of this product listed in Section 2 (Composition and Information on
Ingredients) by CAS # are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAL/OSHA and
therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: Acute exposure to this material via skin contact, eye contact, and inhalation may mildly irritate
contaminated tissue.
SENSITIZATION TO THE PRODUCT: This product is not currently known to be a sensitizer with prolonged or repeated use.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of components of this
product listed in Section 2 (Composition and Information on Ingredients) by CAS # on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans. The Witch Hazel component of this
product was evaluated for the induction of sex-linked recessive lethal mutations in Drosophila melanogaster by the
National Toxicology Program. Canton-S wild-type males were treated with concentrations of the witch hazel that result
in approximately 30% mortality. Following treatment, males were mated individually to 3 harems of Basc virgin females
to produce 3 broods for analysis. The concentrations of witch hazel tested by injection (500,000 ppm) or feeding
(500,000 ppm) were negative in this assay.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage
to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that
interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) established for the
components of this product.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: This product is relatively stable under ambient environmental conditions.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to plant or animal life, especially if large
volumes of this product are released. Plants may be discolored and damaged (depending on the severity of the
contamination).
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful to aquatic plant or animal life, especially if large
volumes of this product are released into a body of water.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or with regulations of Canada, Australia, or EU Member States. This material, if unaltered by use, may be
disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
U.S. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product.
EWC WASTE CODES: Wastes from MFSU and Removal of Printing Inks: 08 03 99: Wastes Not Otherwise Specified
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Not Regulated
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable
UN IDENTIFICATION NUMBER: Not Applicable
PACKING GROUP: Not Applicable
DOT LABEL(S) REQUIRED: Not Applicable
EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2004: Not Applicable
MARINE POLLUTANT: The components of this product listed in Section 2 (Composition and Information on Ingredients) by CAS # are
not designated by the DOT to be Marine Pollutants (per Appendix B to 49 CFR 172.101).
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT classified
as dangerous goods, per regulations of Transport Canada.
SILVERBACK INK MSDS
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14. TRANSPORTATION INFORMATION (Continued)
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is NOT classified as
dangerous goods.
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is NOT classified as
dangerous goods.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This product is NOT classified by the United Nations Economic Commission for Europe to be dangerous goods.
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS GOODS
BY ROAD OR RAIL: This product is NOT classified as dangerous goods, per regulations of the Australian Federal Office
of Road Safety.
15. REGULATORY INFORMATION
ADDITIONAL UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product listed in Section 2 (Composition and
Information on Ingredients) by CAS # are not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of
the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this material.
The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40
CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
U.S. TSCA INVENTORY STATUS: The components of this product listed in Section 2 (Composition and Information on
Ingredients) by CAS # are listed on the TSCA Inventory.
U.S. HAZARDOUS AIR POLLUTANT (HAPs): The components of this product listed in Section 2 (Composition and
Information on Ingredients) by CAS # are not listed by the EPA under section 112(b) of the Clean Air Act as a `HAP'.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The components of this
product listed in Section 2 (Composition and Information on Ingredients) by CAS # are not on the Proposition 65 Lists.
ANSI LABELING (Z129.1): CAUTION! MAY CAUSE SKIN, EYE, AND RESPIRATORY TRACT IRRITATION. MAY
DISCOLOR CONTAMINATED SKIN, EYES, HAIR, AND CLOTHES. Use with adequate ventilation. Avoid contact of liquid
with skin, eyes, and clothing. Avoid exposure to vapors, mists, or sprays. Wash thoroughly after handling. Wear
appropriate hand and eye protection. FIRST-AID: In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. If inhaled, remove to fresh air. If swallowed, do not induce vomiting. Get medical
attention if irritation develops or persists or if any other adverse effect occurs. IN CASE OF FIRE: Use water fog, dry
chemical, or CO2, or alcohol foam. IN CASE OF SPILL: Absorb spill with inert materials (e.g., polypads, dry sand). Rinse
area with soapy water. Consult Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product listed in Section 2 (Composition and
Information on Ingredients) by CAS # are listed on the DSL Inventory.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITY SUBSTANCES LISTS: The components of this
product listed in Section 2 (Composition and Information on Ingredients) by CAS # are not on the CEPA Priority Substances
Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS: Not applicable.
EUROPEAN UNION INFORMATION:
EU LABELING/CLASSIFICATION: This product does not meet the definition of any hazard class, as defined by the
European Union Council Directives 67/548/EEC and 2001/59/EC. (See Section 15 for details on classification)
EUROPEAN UNION ANNEX II HAZARD SYMBOL: Not applicable.
AUSTRALIAN INFORMATION FOR PRODUCT:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: The components of this product listed in
Section 2 (Composition and Information on Ingredients) by CAS # are listed on the AICS.
HAZARDOUS SUBSTANCES INFORMATION SYSTEM (HSIS): The components of this product listed in Section 2
(Composition and Information on Ingredients) by CAS # are not listed in the HSIS.
STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable.
LABELING AND CLASSIFICATION: This product does not meet the definition of any hazard class, based a review of the
regulation [NOHSC: 10005 (1994)].
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
800/441-3365
DATE OF PRINTING: April 26, 2007
SILVERBACK INK MSDS
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16. OTHER INFORMATION (Continued)
The data in this Material Safety Data Sheet is true and accurate to the best of Silverback Ink knowledge. However, since data, safety standards, and government regulations are subject to change
conditions of handling, use, or misuse are beyond Silverback Ink control, Silverback Ink MAKES NO WARRANTY, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. The user is required to comply with all laws and regulations
relating to the purchase, use, storage, and disposal of the product. User must be familiar with and follow generally accepted safe handling procedures of chemicals, and is solely responsible for any
effects caused by its misuse or mixing of this chemical with any other substance.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each
constituent.
HAZARD RATINGS (continued):
EXPOSURE LIMITS IN AIR: HEALTH HAZARD (continued):
CEILING LEVEL: The concentration that shall not be exceeded during any part of the 1 (continued): Oral Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or
working exposure. Rabbit: > 1000-2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2
DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have been (Moderate Hazard: Temporary or transitory injury may occur. Skin Irritation:
shown to increase the mutant frequency in the progeny of exposed humans. 2: Germ Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation:
cell mutagens which have been shown to increase the mutant frequency in the progeny Moderately to severely irritating and/or corrosive; reversible corneal opacity; corneal
of exposed mammals. 3A: Substances which have been shown to induce genetic involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat:
damage in germ cells of human of animals, or which produce mutagenic effects in > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation
somatic cells of mammals in vivo and have been shown to reach the germ cells in an Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.);3 (Serious Hazard: Major injury likely unless
active form. 3B: Substances which are suspected of being germ cell mutagens prompt action is taken and medical treatment is given; high level of toxicity; corrosive.
because of their genotoxic effects in mammalian somatic cell in vivo; in exceptional Skin Irritation: Severely irritating and/or corrosive; may destroy dermal tissue, cause
cases, substances for which there are no in vivo data, but which are clearly mutagenic skin burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye
in vitro and structurally related to known in vivo mutagens. 4: Not applicable (Category Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or
4 carcinogenic substances are those with non-genotoxic mechanisms of action. By irritation persisting for more than 21 days. Draize > 80 with effects irreversible in 21
definition, germ cell mutagens are genotoxic. Therefore, a Category 4 for germ cell days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 20-
mutagens cannot apply. At some time in the future, it is conceivable that a Category 4 200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard:
could be established for genotoxic substances with primary targets other than DNA Life-threatening; major or permanent damage may result from single or repeated
[e.g. purely aneugenic substances] if research results make this seem sensible.) 5: exposure. Skin Irritation: Not appropriate. Do not rate as a "4", based on skin irritation
Germ cell mutagens, the potency of which is considered to be so low that, provided the alone. Eye Irritation: Not appropriate. Do not rate as a "4", based on eye irritation
MAK value is observed, their contribution to genetic risk for humans is expected not to alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 20
be significant. mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the FLAMMABILITY HAZARD:
developing embryo or fetus has been unequivocally demonstrated. Exposure of 0 (Minimal Hazard-Materials that will not burn in air when exposure to a temperature of
pregnant women can cause damage of the developing organism, even when MAK and 815.5癈 [1500癋] for a period of 5 minutes.); 1 (Slight Hazard-Materials that must be
BAT (Biological Tolerance Value for Working Materials) values are observed. Group pre-heated before ignition can occur. Material require considerable pre-heating, under
B: Currently available information indicates a risk of damage to the developing embryo all ambient temperature conditions before ignition and combustion can occur, Including:
or fetus must be considered to be probable. Damage to the developing organism Materials that will burn in air when exposed to a temperature of 815.5癈 (1500癋) for a
cannot be excluded when pregnant women are exposed, even when MAK and BAT period of 5 minutes or less; Liquids, solids and semisolids having a flash point at or
values are observed. Group C: There is no reason to fear a risk of damage to the
above 93.3癈 [200癋] (e.g. OSHA Class IIIB, or; Most ordinary combustible materials
developing embryo or fetus when MAK and BAT values are observed. Group D:
[e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials that must be moderately heated
Classification in one of the groups A-C is not yet possible because, although the data
or exposed to relatively high ambient temperatures before ignition can occur.
available may indicate a trend, they are not sufficient for final evaluation.
Materials in this degree would not, under normal conditions, form hazardous
IDLH-Immediately Dangerous to Life and Health: This level represents a
atmospheres in air, but under high ambient temperatures or moderate heating may
concentration from which one can escape within 30-minutes without suffering escape-
release vapor in sufficient quantities to produce hazardous atmospheres in air,
preventing or permanent injury.
Including: Liquids having a flash-point at or above 37.8癈 [100癋]; Solid materials in
LOQ: Limit of Quantitation.
the form of course dusts that may burn rapidly but that generally do not form explosive
MAK: Federal Republic of Germany Maximum Concentration Values in the workplace.
atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and
NE: Not Established. When no exposure guidelines are established, an entry of NE is
create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily
made for reference.
give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that can be ignited
NIC: Notice of Intended Change.
under almost all ambient temperature conditions. Materials in this degree produce
NIOSH CEILING: The exposure that shall not be exceeded during any part of the
hazardous atmospheres with air under almost all ambient temperatures, or, unaffected
workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a
by ambient temperature, are readily ignited under almost all conditions, including:
15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at
Liquids having a flash point below 22.8癈 [73癋] and having a boiling point at or above
any time during a workday.
38癈 [100癋] and below 37.8癈 [100癋] [e.g. OSHA Class IB and IC]; Materials that on
NIOSH RELs: NIOSH's Recommended Exposure Limits.
account of their physical form or environmental conditions can form explosive mixtures
PEL-Permissible Exposure Limit: OSHA's Permissible Exposure Limits. This
with air and are readily dispersed in air [e.g., dusts of combustible solids, mists or
exposure value means exactly the same as a TLV, except that it is enforceable by
droplets of flammable liquids]; Materials that burn extremely rapidly, usually by reason
OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the
of self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4
June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58:
(Severe Hazard-Materials that will rapidly or completely vaporize at atmospheric
40191). Both the current PELs and the vacated PELs are indicated. The phrase,
pressure and normal ambient temperature or that are readily dispersed in air, and
"Vacated 1989 PEL," is placed next to the PEL that was vacated by Court Order.
which will burn readily, including: Flammable gases; Flammable cryogenic materials;
SKIN: Used when a there is a danger of cutaneous absorption.
Any liquid or gaseous material that is liquid while under pressure and has a flash point
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute
below 22.8癈 [73癋] and a boiling point below 37.8癈 [100癋] [e.g. OSHA Class IA;
time-weighted average (TWA) exposure that should not be exceeded at any time
Material that ignite spontaneously when exposed to air at a temperature of 54.4癈
during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-
TWA. [130癋] or below [e.g. pyrophoric]).
TLV-Threshold Limit Value: An airborne concentration of a substance that PHYSICAL HAZARD:
represents conditions under which it is generally believed that nearly all workers may 0 (Water Reactivity: Materials that do not react with water. Organic Peroxides:
be repeatedly exposed without adverse effect. The duration must be considered, Materials that are normally stable, even under fire conditions and will not react with
including the 8-hour. water. Explosives: Substances that are Non-Explosive. Unstable Compressed Gases:
TWA-Time Weighted Average: Time Weighted Average exposure concentration for No Rating. Pyrophorics: No Rating. Oxidizers: No "0" rating allowed. Unstable
a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. Reactives: Substances that will not polymerize, decompose, condense or self-react.);
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM 1 (Water Reactivity: Materials that change or decompose upon exposure to moisture.
Organic Peroxides: Materials that are normally stable, but can become unstable at
HAZARD RATINGS: This rating system was developed by the National Paint high temperatures and pressures. These materials may react with water, but will not
and Coating Association and has been adopted by industry to identify the degree of release energy. Explosives: Division 1.5 & 1.6 substances that are very insensitive
chemical hazards. explosives or that do not have a mass explosion hazard. Compressed Gases:
HEALTH HAZARD:
Pressure below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated.
Group III; Solids: any material that in either concentration tested, exhibits a mean
Skin Irritation: Essentially non-irritating. PII or Draize = "0". Eye Irritation: Essentially
burning time less than or equal to the mean burning time of a 3:7 potassium
non-irritating, or minimal effects which clear in < 24 hours [e.g. mechanical irritation].
bromate/cellulose mixture and the criteria for Packing Group I and II are not met.
Draize = "0". Oral Toxicity LD50 Rat: < 5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit:
Liquids: any material that exhibits a mean pressure rise time less than or equal to the
< 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor
pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for
reversible Injury may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly
Packing Group I and II are not met.
irritating. Eye Irritation: Slightly or mildly irritating.
SILVERBACK INK MSDS
Page 7 of 9
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
RATINGS (continued): RATINGS (continued):
PHYSICAL HAZARD (continued): HEALTH HAZARD (continued): 3 (continued): Materials whose LD50 for acute
1 (continued): Unstable Reactives: Substances that may decompose, condense or dermal toxicity is greater than 40 mg/kg but less than or equal to 200 mg/kg.
self-react, but only under conditions of high temperature and/or pressure and have little Materials whose LD50 for acute oral toxicity is greater than 5 mg/kg but less than or
or no potential to cause significant heat generation or explosive hazard. Substances equal to 50 mg/kg. Any liquid whose saturated vapor concentration at 20癈 (68癋) is
that readily undergo hazardous polymerization in the absence of inhibitors.); 2 (Water equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is
Reactivity: Materials that may react violently with water. Organic Peroxides: Materials less than or equal to 3000 ppm and that does not meet the criteria for degree of
that, in themselves, are normally unstable and will readily undergo violent chemical hazard 4. Compressed liquefied gases with boiling points between -30癈 (-22癋)
change, but will not detonate. These materials may also react violently with water. and -55癈 (-66.5癋) that cause frostbite and irreversible tissue damage. Materials
Explosives: Division 1.4 ?Explosive substances where the explosive effect are largely that are respiratory irritants. Cryogenic gases that cause frostbite and irreversible
confined to the package and no projection of fragments of appreciable size or range are tissue damage. Materials that are corrosive to the respiratory tract. Materials that
expected. An external fire must not cause virtually instantaneous explosion of almost are corrosive to the eyes or cause irreversible corneal opacity. Materials that are
the entire contents of the package. Compressed Gases: Pressurized and meet OSHA corrosive to the skin. 4 (materials that, under emergency conditions, can be lethal):
definition but < 514.7 psi absolute at 21.1癈 (70癋) [500 psig]. Pyrophorics: No Rating. Gases and vapors whose LC50 for acute inhalation toxicity less than or equal to
Oxidizers: Packing Group II Solids: any material that, either in concentration tested, 1,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is less than or
exhibits a mean burning time of less than or equal to the mean burning time of a 2:3 equal to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or
potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. equal to 40 mg/kg. Materials whose LD50 for acute oral toxicity is less than or equal
Liquids: any material that exhibits a mean pressure rise time less than or equal to the to 5 mg/kg. Any liquid whose saturated vapor concentration at 20癈 (68癋) is equal
pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is less than
the criteria for Packing Group I are not met. Unstable Reactives: Substances that may or equal to 1000 ppm.
polymerize, decompose, condense, or self-react at ambient temperature and/or FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire
pressure, but have a low potential for significant heat generation or explosion. conditions, including intrinsically noncombustible materials such as concrete, stone,
Substances that readily form peroxides upon exposure to air or oxygen at room and sand: Materials that will not burn in air when exposed to a temperature of 816癈
temperature); 3 (Water Reactivity: Materials that may form explosive reactions with (1500癋) for a period of 5 minutes in according with Annex D. 1 Materials that must
water. Organic Peroxides: Materials that are capable of detonation or explosive be preheated before ignition can occur. Materials in this degree require considerable
reaction, but require a strong initiating source, or must be heated under confinement preheating, under all ambient temperature conditions, before ignition and
before initiation; or materials that react explosively with water. Explosives: Division 1.2 combustion can occur: Materials that will burn in air when exposed to a temperature
?Explosive substances that have a fire hazard and either a minor blast hazard or a of 816癈 (1500癋) for a period of 5 minutes in accordance with Annex D. Liquids,
minor projection hazard or both, but do not have a mass explosion hazard.
solids and semisolids having a flash point at or above 93.4癈 (200癋) (i.e. Class IIIB
Compressed Gases: Pressure > 514.7 psi absolute at 21.1癈 (70癋) [500 psig].
liquids). Liquids with a flash point greater than 35癈 (95癋) that do not sustain
Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any material that, in either
combustion when tested using the Method of Testing for Sustained Combustibility,
concentration tested, exhibits a mean burning time less than the mean burning time of
per 49 CFR 173, Appendix H or the UN Recommendation on the Transport of
a 3.:2 potassium bromate/cellulose mixture. Liquids: Any material that spontaneously
Dangerous Goods, Model Regulations (current edition) and the related Manual of
ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise
Tests and Criteria (current edition). Liquids with a flash point greater than 35癈
time less than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture.
(95癋) in a water-miscible solution or dispersion with a water non-combustible
Unstable Reactives: Substances that may polymerize, decompose, condense or self-
liquid/solid content of more than 85 percent by weight. Liquids that have no fire point
react at ambient temperature and/or pressure and have a moderate potential to cause
when tested by ASTM D 92 Standard Test Method for Flash and Fire Points by
significant heat generation or explosion.); 4 (Water Reactivity: Materials that react
Cleveland Open Cup, up to a boiling point of the liquid or up to a temperature at
explosively with water without requiring heat or confinement. Organic Peroxides:
which the sample being tested shows an obvious physical change. Combustible
Materials that are readily capable of detonation or explosive decomposition at normal
pellets with a representative diameter of greater than 2 mm (10 mesh). Solids
temperature and pressures. Explosives: Division 1.1 & 1.2-explosive substances that
containing greater than 0.5 percent by weight of a flammable or combustible solvent
have a mass explosion hazard or have a projection hazard. A mass explosion is one
are rated by the closed up flash point of the solvent. Most ordinary combustible
that affects almost the entire load instantaneously. Compressed Gases: No Rating.
materials. 2 Materials that must be moderately heated or exposed to relatively high
Pyrophorics: Add to the definition of Flammability "4". Oxidizers: No "4" rating.
ambient temperatures before ignition can occur. Materials in this degree would not
Unstable Reactives: Substances that may polymerize, decompose, condense or self-
under normal conditions form hazardous atmospheres with air, but under high
react at ambient temperature and/or pressure and have a high potential to cause
ambient temperatures or under moderate heating could release vapor in sufficient
significant heat generation or explosion.).
quantities to produce hazardous atmospheres with air: Liquids having a flash point at
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD or above 37.8癈 (100癋) and below 93.4癈 (200癋) (i.e. Class II and Class IIIA
RATINGS: liquids.) Solid materials in the form of powders or coarse dusts of representative
HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but
hazard beyond that of ordinary combustible materials): Gases and vapors whose LC50 that generally do not form explosive mixtures in air. Solid materials in fibrous or
for acute inhalation toxicity is greater than 10,000 ppm. Dusts and mists whose LC50 shredded form that burn rapidly and create flash fire hazards, such as cotton, sisal
for acute inhalation toxicity is greater than 200 mg/L. Materials whose LD50 for acute and hemp. Solids and semisolids that readily give off flammable vapors. Solids
dermal toxicity is greater than 2000 mg/kg. Materials whose LD50 for acute oral containing greater than 0.5 percent by weight of a flammable or combustible solvent
toxicity is greater than 2000 mg/kg. Materials that are essentially non-irritating to the are rated by the closed cup flash point of the solvent. 3 Liquids and solids that can
respiratory tract, eyes and skin. 1 (materials that, under emergency conditions, can be ignited under almost all ambient temperature conditions. Materials in this degree
cause significant irritation): Gases and vapors whose LC50 for acute inhalation produce hazardous atmospheres with air under almost all ambient temperatures or,
toxicity is greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and though unaffected by ambient temperatures, are readily ignited under almost all
mists whose LC50 for acute inhalation toxicity is greater than 10 mg/L but less than or conditions: Liquids having a flash point below 22.8癈 (73癋) and having a boiling
equal to 200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than point at or above 37.8癈 (100癋) and those liquids having a flash point at or above
1000 mg/kg but less than or equal to 2000 mg/kg. Materials whose LD50 for acute 22.8癈 (73癋) and below 37.8癈 (73癋) and below 37.8癈 (100癋) (i.e. Class IB and
oral toxicity is greater than 500 mg/kg but less than or equal to 2000 mg/kg. IC liquids). Materials that, on account of their physical form or environmental
Materials that cause slight to moderate irritation to the respiratory tract, eyes and conditions, can form explosive mixtures with air and are readily dispersed in air.
skin. 2 (materials that, under emergency conditions, can cause temporary Flammable or combustible dusts with a representative diameter less than 420
incapacitation or residual injury): Gases and vapors whose LC50 for acute inhalation microns (40 mesh). Materials that burn with extreme rapidity, usually by reason of
toxicity is greater than 3,000 ppm but less than or equal to 5,000 ppm. Dusts and self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids
mists whose LC50 for acute inhalation toxicity is greater than 2 mg/L but less than or containing greater than 0.5 percent by weight of a flammable or combustible solvent
equal to 10 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 200 are rated by the closed cup flash point of the solvent. 4 Materials that will rapidly or
mg/kg but less than or equal to 1000 mg/kg. Materials whose LD50 for acute oral completely vaporize at atmospheric pressure and normal ambient temperature or
toxicity is greater than 50 mg/kg but less than or equal to 500 mg/kg. Any liquid that are readily dispersed in air and will burn readily: Flammable gases. Flammable
whose saturated vapor concentration at 20癈 (68癋) is equal to or greater than one- cryogenic materials. Any liquid or gaseous materials that is liquid while under
fifth its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 5000 ppm pressure and has a flash point below 22.8癈 (73癋) and a boiling point below 37.8癈
and that does not meet the criteria for either degree of hazard 3 or degree of hazard (100癋) (i.e. Class IA liquids). Materials that ignite when exposed to air, Solids
4. Compressed liquefied gases with boiling points between -30癈 (-22癋) and -55癈 containing greater than 0.5 percent by weight of a flammable or combustible solvent
(-66.5癋) that cause severe tissue damage, depending on duration of exposure. are rated by the closed cup flash point of the solvent.
Materials that are respiratory irritants. Materials that cause severe, but reversible
irritation to the eyes or are lachrymators. Materials that are primary skin irritants or
sensitizers. 3 (materials that, under emergency conditions, can cause serious or
permanent injury): Gases and vapors whose LC50 for acute inhalation toxicity is
greater than 1,000 ppm but less than or equal to 3,000 ppm. Dusts and mists whose
LC50 for acute inhalation toxicity is greater than 0.5 mg/L but less than or equal to 2
mg/L.
SILVERBACK INK MSDS
Page 8 of 9
DEFINITIONS OF TERMS (Continued)
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD TOXICOLOGICAL INFORMATION:
RATINGS (continued): Human and Animal Toxicology: Possible health hazards as derived from human
data, animal studies, or from the results of studies with similar compounds are
INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even
presented. Definitions of some terms used in this section are: LD50 - Lethal Dose
under fire conditions: Materials that have an estimated instantaneous power density
(solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal
(product of heat of reaction and reaction rate) at 250癈 (482癋) below 0.01 W/mL.
Concentration (gases) which kills 50% of the exposed animals; ppm concentration
Materials that do not exhibit an exotherm at temperatures less than or equal to 500癈 3
expressed in parts of material per million parts of air or water; mg/m concentration
(932癋) when tested by differential scanning calorimetry. 1 Materials that in
expressed in weight of substance per volume of air; mg/kg quantity of material, by
themselves are normally stable, but that can become unstable at elevated
weight, administered to a test subject, based on their body weight in kg. Other
temperatures and pressures: Materials that have an estimated instantaneous power
measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo
density (product of heat of reaction and reaction rate) at 250癈 (482癋) at or above 0.01
the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo,
W/mL and below 10 W/mL. 2 Materials that readily undergo violent chemical change
LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.
at elevated temperatures and pressures: Materials that have an estimated Cancer Information: The sources are: IARC - the International Agency for
instantaneous power density (product of heat of reaction and reaction rate) at 250癈 Research on Cancer; NTP - the National Toxicology Program, RTECS - the
(482癋) at or above 10 W/mL and below 100W/mL. 3 Materials that in themselves are Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC
capable of detonation or explosive decomposition or explosive reaction, but that and NTP rate chemicals on a scale of decreasing potential to cause human cancer
require a strong initiating source or that must be heated under confinement before with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other
initiation: Materials that have an estimated instantaneous power density (product of Information: BEI - ACGIH Biological Exposure Indices, represent the levels of
heat of reaction and reaction rate) at 250癈 (482癋) at or above 100 W/mL and below determinants which are most likely to be observed in specimens collected from a
1000 W/mL. Materials that are sensitive to thermal or mechanical shock at elevated healthy worker who has been exposed to chemicals to the same extent as a worker
temperatures and pressures. 4 Materials that in themselves are readily capable of with inhalation exposure to the TLV.
detonation or explosive decomposition or explosive reaction at normal temperatures
ECOLOGICAL INFORMATION:
and pressures: Materials that have an estimated instantaneous power density (product
EC is the effect concentration in water. BCF = Bioconcentration Factor, which is
of heat of reaction and reaction rate) at 250癈 (482癋) of 1000 W/mL or greater.
used to determine if a substance will concentrate in lifeforms which consume
Materials that are sensitive to localized thermal or mechanical shock at normal
contaminated plant or animal matter. TLm = median threshold limit; Coefficient of
temperatures and pressures.
Oil/Water Distribution is represented by log Kow or log Koc and is used to assess
FLAMMABILITY LIMITS IN AIR: a substance's behavior in the environment
Much of the information related to fire and explosion is derived from the National Fire
REGULATORY INFORMATION:
Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid
U.S. and CANADA:
gives off sufficient vapors to form an ignitable mixture with air. Autoignition
ACGIH: American Conference of Governmental Industrial Hygienists, a
Temperature: The minimum temperature required to initiate combustion in air with no
professional association which establishes exposure limits.
other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will
This section explains the impact of various laws and regulations on the material.
explode or ignite in the presence of an ignition source. UEL - the highest percent of
EPA is the U.S. Environmental Protection Agency. NIOSH is the National Institute
vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
of Occupational Safety and Health, which is the research arm of the U.S.
Occupational Safety and Health Administration (OSHA). WHMIS is the Canadian
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
Department of Transportation and the Transport Canada, respectively. Superfund
Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-
Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act
(TSCA); Marine Pollutant status according to the DOT; the Comprehensive
Environmental Response, Compensation, and Liability Act (CERCLA or
Superfund); and various state regulations. This section also includes information
on the precautionary warnings which appear on the material's package label.
OSHA - U.S. Occupational Safety and Health Administration.
EUROPEAN and INTERNATIONAL:
The DFG: This is the Federal Republic of Germany's Occupation Health Agency,
similar to the U.S. OSHA. EU is the European Union (formerly known as the EEC,
European Economic Community). EINECS: This is the European Inventory of
Now-Existing Chemical Substances. The ARD is the European Agreement
Concerning the International Carriage of Dangerous Goods by Road and the RID
are the International Regulations Concerning the Carriage of Dangerous Goods by
Rail. AICS is the Australian Inventory of Chemical Substances. METI is the
Japanese Ministry of Economy, Trade, and Industry.
SILVERBACK INK MSDS
Page 9 of 9
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