MSDS MATERIAL SAFETY DATA SHEET
RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906
idye Sun Blocker
MSDS No: 401 Effective Date: 11/8/7 Amendatory Date: 11/6/7
1. Product Identification
Product Code: 401
Chemical Family: Stilbene Disulfonic Acid Triazine Derivative
2. Composition/Information on Ingredients
Hazardous
Ingredients % CAS No.
2,2'- (1,2, ethenediyl) bis[5-[[4-(methylamino)-6-[[4- 50-60 180850-95-7
[(methylamino)carbonyl]phenyl]amino]-1,3,5-triazin-
2-yl]amino]-disodium salt (E)-
Non-Hazardous
Ingredients % CAS No.
Sulfuric acid disodium salt 30-40 7757-82-6
Sodium chloride (NaCl) 1.3 7647-14-5
Water 5.8 7732-18-5
3. Physical & Chemical Characteristics
Vapor Pressure: <0.01Pa
Vapor Density: N/A
Solubility in Water: Not Determined
Appearance & Odor: Yellow Solid with no odor
Specific Gravity: N/A
Melting Point: Not Determined
Density: Not Determined
pH: 10-10.5@ 3g/L
Percent Volatile: Not determined
VOC: Not Determined
Partition Coefficient (octanol/Water): Not determined
Decomposition Temperature: >662 degrees F
Flash Point: Not applicable
4. Fire & Explosion Data
Hazards: combustible powder, avoid creating dusty conditions, grounding is required
when emptying into a conductive container, when flammable solvents are present the
container must be inerted or the system otherwise designed to prevent or contain an
explosion. Seek expert advise. In addition, for products packaged in fused-lined (coated)
fiber drums, fiber drums with conductive liners, steel drums, steel pails, and Type "C"
FIBC (bulk bags), or other conductive the following instructions also apply: always
ground this package before emptying, the user is responsible for designing the system to
handle solid and ensuring proper training of employees in system's use.
Fire Fighting Measures: Standard procedure for chemical fires.
Suitable Extinguishing Media: Carbon Dioxide, dry chemical, foam or water mist.
Fire Fighting Equipment: Wear self-contained breathing apparatus and protective suit.
Unusual Hazards: The product can form an explosive dust/air mixture.
Hazardous Combustion Products: Burning may produce toxic combustion products.
5. Reactivity Data
Stable: Stable
Conditions to Avoid: Avoid static discharge
MSDS MATERIAL SAFETY DATA SHEET
RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906
Incompatibility: Strong Oxidizing agents, strong acids, strong bases.
Hazardous Decomposition: No decomposition expected under normal storage conditions.
Hazardous Polymerization: None expected.
6. Health Hazards
Routes of Entry: Ingestion, skin, inhalation, eyes.
Potential Health Effects: Corrosive. Causes eye burns.
OSHA Hazardous Substance: This material is classified as hazardous under OSHA
regulations.
7. Emergency & First Aid Procedures
Inhalation: Remove to fresh air, if not breathing give artificial respiration. If breathing
is difficult, give oxygen and get immediate medical attention.
Eyes: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
Skin: Wash off immediately with soap and plenty of water. Get medical attention if
irritation occurs.
Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean
forward to reduce the risk of aspiration. Seek medical attention immediately.
8. Special Precautions & Spill/Leak Procedures
Handling & Storage: As with all industrial chemicals, use good industrial practices
when handling. Avoid eye, skin and clothing contact. Do not inhale. Do not taste or
swallow. Use only with adequate ventilation. Keep containers tightly closed in a cool,
well-ventilated place.
Steps if Spilled: Sweep up and shovel into suitable containers for disposal. Avoid dust
formation. Wear suitable protective equipment. Should not be released into the
environment.
Waste Disposal: Dispose in accordance with local, state, provincial and federal
regulations.
9. Special Protection Information
Exposure Guidelines: There are no OSHA or ACGIH exposure guidelines available for
component(s) in this product.
Respiratory Protection: Use NIOSH approved respirator as needed to mitigate
exposure.
Ventilation: Work in well ventilated areas. Do not breathe dust.
Skin Protection: Wear chemical resistant gloves and protective clothing.
Eye Protection: Wear safety glasses or goggles to protect against dust particle.
Other Protection: Eye wash station and safety shower should be available in immediate
work area. Select additional protective equipment based upon potential for exposure.
10. Toxicological Information
Acute Oral Toxicity: >LD50: 5000 mg/kg (Rats)
Acute Dermal Toxicity: LD50: 2000 mg/kg (Rats)
Acute Inhalation Toxicity: Not determined
Eye Irritation: (Rabbits) Corrosive
Skin Irritation: (Rabbits) Not an irritant.
Skin Sensitization: Sensitization (Guinea Pig)-does not sensitize
Carcinogenicity (IARC, NTP, OSHA, ACGIH): None of the components in this
product at concentrations greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
Mutagenicity: Reverse Mutation Assay/Ames Test: Non mutagen (OECD 471) in Vitro
MSDS MATERIAL SAFETY DATA SHEET
RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906
Chromosomal aberration Assay (CHO cells)-negative (OECD 473)
Reproductivity Toxicity: Not determined
Teratogenicity: Not determined
Neurotoxicity: Not determined
Subacute Toxicity: Not determined
Subchronic Toxicity: A 28 day oral feed (gavage) was conducted on rats. The No
Observed Effect Level was estimated at 150 mg/kg/day.
Chronic Toxicity: Not determined
Absorption/Distribution/Excretion/Metabolism: Not determined.
Additional Information: The toxicological tests were carried out on the active
component.
11. Ecological Information
Toxicity to Fish: >LC50 120mg/L 96 hour (Rainbow Trout)
Toxicity to Invertebrates: >LC50 120 mg/L 48 hour (Daphnia magna)
Toxicity to Algae: > mg/L EC50 72 hour
Toxicity to Sewage Bacteria: >EC50=1000 mg/L 3 hour
Activated Sludge Respiration Inhibition Test: Not determined
Biochemical Oxygen Demand (BOD): 0 mg O2/g
Total Oxygen Demand: Not determined
Biodegradability: Not determined
Bioaccumulation: Not determined
Additional Environmental Data: Test data for the major active component. Not toxic
or harmful to aquatic organisms.
12. Transport Information
U.S. Department of Transportation (DOT): Not regulated for this mode of transport.
International Maritime Dangerous Goods (IMDG): Not regulated for this mode of
transport.
International Air Transportation Authority (IATA): Not regulated for this mode of
transport.
13. Regulatory Information
OSHA Hazardous Substance: This material is classified as hazardous under OSHA
regulations.
Clean Air Act-Hazardous Air Pollutants (HAP): This product does not contain Air
Pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
Clean Air Act-Volatile Organic Compounds (VOC): This product does not contain
any SOCMI Intermediate or Final Volatile Organic Compounds (VOC) as defined by the
U.S. Clean Air Act Section 111 (40 CFR 60.489).
Clean Air Act-Ozone Depleting Substances (ODS): This product neither contains, nor
was manufactured with, a Class I or Class II ozone depleting substance ODS), as defined
by the U.S. Clean Air Act Section 602 (40 CFR82, Subpt. A, App. A+B).
Clean Water Act-Priority Pollutants (PP): This product does not contain any priority
pollutants listed under the U.S. Clean Water Act Section 307 (2)(1) Priority Pollutant List
(40 CFR 401.15).
Resource Conservation and Recovery Act (RCRA): Not hazardous waste under
RCRA (40 CFR 261.21).
SARA Section 302 Extremely Hazardous Substances (EHS): This product does not
contain any components regulated under Section 302 (40 CFR 355) as Extremely
Hazardous Substances.
Sara Section 304 CERLA Hazardous Substances: This product does not contain any
components regulated under Section 304 (40 CFR 302) as hazardous chemicals for
emergency release notifications ("CERLA" list).
MSDS MATERIAL SAFETY DATA SHEET
RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906
SARA Section 311/312 Hazardous Communication Standard (HCS): Unspecified.
SARA Section 313 Toxic Chemical List (TCL): This product does not contain any
component(s) listed on the Section 313 Toxic Chemical List.
TSCA Section 8(b): Inventory Status: All component(s) comprising this product are
either exempt or listed on the TSCA inventory.
TSCA Section 5(e) Consent Orders: This product is not subject to Section 5(e)
Consent Order.
Components TSCA 5(e) CFR Reference
Status
2,2'- (1,2, ethenediyl) bis[5-[[4-(methylamino)-6-[[4- Listed
[(methylamino)carbonyl]phenyl]amino]-1,3,5-triazin-2-
yl]amino]-disodium salt (E)-
TSCA Significant New Use Rule (SNUR): The following component(s) are subject to a
Significant New Use Rule (SNUR):
Components TSCA SNUR CFR Reference
Status
2,2'- (1,2, ethenediyl) bis[5-[[4-(methylamino)-6-[[4- Listed 40 CFR 721.9785
[(methylamino)carbonyl]phenyl]amino]-1,3,5-triazin-2-
Consent Order
yl]amino]-disodium salt (E)-
rescinded.
TSCA Section 5(f): This product is not subject to Section 5(f)/6(a) rule.
TSCA Section 12(b) Export Notification: This product containers the following
component(s) that are subject to a Section 12(b) Export Notification:
Components TSCA Section 12(b) Export Notification
2,2'- (1,2, ethenediyl) bis[5-[[4-(methylamino)-6-[[4- Annual Export Notification required.
[(methylamino)carbonyl]phenyl]amino]-1,3,5-triazin-2-
yl]amino]-disodium salt (E)-
State Regulations:
California Proposition 65: This product does not contain any components currently
under the California list of Known Carcinogens and Reproductive Toxins.
Pennsylvania Right-To-Know: This product contains the following components which
are subject to Pennsylvania Right-To-Know disclosure requirement.
Components CAS Number Pennsylvania Right-To-Know
Sulfuric acid disodium salt 7757-82-6 Listed. Environmental Hazard
2,2'- (1,2, ethenediyl) bis[5-[[4-(methylamino)-6-[[4- 180850-95-7 Not Listed.
[(methylamino)carbonyl]phenyl]amino]-1,3,5-triazin-2-
yl]amino]-disodium salt (E)-
Water 7732-18-5 Not Listed.
International Regulations:
Chemical Weapons Convention (CWC): This product does not contain any
components listed under the Chemical Weapons Convention Schedule of Chemicals.
Domestic Substance List (DSL) Status: Not all components are listed on the DSL.
MSDS MATERIAL SAFETY DATA SHEET
RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906
Notice to Reader
The information contained in this MSDS is based on data from sources considered
to be reliable but Rupert, Gibbon & Spider Inc. does not guarantee the accuracy or
completeness thereof. Rupert, Gibbon & Spider Inc. urges each customer or
recipient of this MSDS to study it carefully to become aware of and understand the
hazards associated with this product. The reader should consider consulting
reference works or individuals who are experts in ventilation, toxicology or fire and
understand the data in this MSDS.
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