Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMPRO 656 WHITE - 30 CTG
Product code : 656806 323
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Non-sag gunnable paste. May cause slight irritation to the respiratory system. Leave area to breathe
fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Slightly irritating.
:
Ingestion May cause irritation to the mouth, throat and stomach.
:
Skin Irritant effect may be delayed.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Long term overexposure to propylene glycol caused liver abnormalities, kidney damage in laboratory animals.
Repeated excessive ingestion may cause central nervous system effects. Fillers are encapsulated and not
expected to be released from product under normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Acrylic polymer NJ TSRN# 51721300-5277P 40.0 - 70.0
Water 7732-18-5 30.0 - 60.0
White mineral oil 8042-47-5 7.0 - 13.0
Amorphous silica 7631-86-9 1.0 - 5.0
Propylene glycol 57-55-6 1.0 - 5.0
Titanium dioxide 13463-67-7 1.0 - 5.0
Ammonium hydroxide 1336-21-6 - <1.0
Zinc oxide 1314-13-2 - <1.0
Chlorothalonil 1897-45-6 - <1.0
Formaldehyde 50-00-0 - <0.1
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Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash with water. If irritation, rash or other disorders develop, get medical attention
immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : This product is not expected to burn under normal conditions of use.Use
that which is appropriate to the surroundings.
Hazardous combustion : Smoke, fumes.
products
Protective equipment for : Not applicable. Product is not expected to burn.
firefighters
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate
container for disposal. Keep out of water courses.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not use in confined or poorly ventilated areas.
Store in sealed containers in a dry, ventilated warehouse location above freezing.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
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Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
Respiratory protection : Not required under normal conditions of use.
Hand protection : Protect hands with impervious gloves.
Eye protection : Use safety glasses if eye contact is likely.
Protective measures : Use professional judgment in the selection, care, and use.Other equipment
not normally required.
Engineering measures : General ventilation is sufficient.Use local exhaust when the general
ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Amorphous silica 7631-86-9 ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 0.8 mg/m3
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Ammonium hydroxide 1336-21-6 ACGIH TWA: 25 ppm
ACGIH STEL: 35 ppm
OSHA PEL: 35 mg/m3
Zinc oxide 1314-13-2 ACGIH TWA: 2 mg/m3 Respirable fraction.
ACGIH STEL: 10 mg/m3 Respirable fraction.
OSHA PEL: 5 mg/m3 Fume.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Non-sag gunnable paste
Color : White
Odor : Acrylate
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : < 32 ?< 90 ?br>
C, F
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Miscible
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Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
Specific Gravity : 1.0931
% Volatile Weight : 35 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Strong acids.Strong bases.
SECTION 11 - TOXICOLOGICAL INFORMATION
Amorphous silica, CAS-No.: 7631-86-9
Acute oral toxicity (LD-50 oral) 22,500 mg/kg ( Rat ) 22,500 mg/kg ( Rat ) 15,000 mg/kg (
Mouse ) 15,000 mg/kg ( Mouse )
Propylene glycol, CAS-No.: 57-55-6
Acute oral toxicity (LD-50 oral) 30,000 mg/kg ( Rat ) 18,000 mg/kg ( Rabbit ) 19,000 mg/kg
( Dog ) 23,900 - 31,800 mg/kg ( Mouse ) 18,400 - 196,000
mg/kg ( Guinea pig )
Ammonium hydroxide, CAS-No.: 1336-21-6
Acute oral toxicity (LD-50 oral) 350 mg/kg ( Rat )
Zinc oxide, CAS-No.: 1314-13-2
Acute oral toxicity (LD-50 oral) 7,950 mg/kg ( Mouse ) 7,950 mg/kg ( Mouse )
Chlorothalonil, CAS-No.: 1897-45-6
Acute oral toxicity (LD-50 oral) 10,000 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 10,000 mg/kg ( Albino rat )
Formaldehyde, CAS-No.: 50-00-0
Acute oral toxicity (LD-50 oral) 800 mg/kg ( Rat ) 260 mg/kg ( Guinea pig ) 100 mg/kg ( Rat
) 42 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 0.82 mg/l for 30 min ( Rat ) 0.48 mg/l for 4 h ( Rat ) 0.414
mg/l for 4 h ( Mouse ) 0.4 mg/l for 2 h ( Mouse )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose of
waste in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
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Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Chlorothalonil 1897-45-6
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components :
Amorphous silica 7631-86-9
Titanium dioxide 13463-67-7
Ammonium hydroxide 1336-21-6
Zinc oxide 1314-13-2
Chlorothalonil 1897-45-6
Formaldehyde 50-00-0
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 36 g/l
exempt solvent)
VOC Method 310 : 1%
U.S. State Regulations:
MASS RTK Components : Amorphous silica 7631-86-9
Titanium dioxide 13463-67-7
Formaldehyde 50-00-0
Penn RTK Components : Acrylic polymer NJ TSRN# 51721300-5277P
Water 7732-18-5
White mineral oil 8042-47-5
Amorphous silica 7631-86-9
Propylene glycol 57-55-6
Titanium dioxide 13463-67-7
NJ RTK Components : Acrylic polymer NJ TSRN# 51721300-5277P
Water 7732-18-5
White mineral oil 8042-47-5
Amorphous silica 7631-86-9
Propylene glycol 57-55-6
Titanium dioxide 13463-67-7
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm:
1897-45-6 Chlorothalonil
50-00-0 Formaldehyde
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Material Safety Data Sheet
TREMPRO 656 WHITE - 30 CTG
Version 1.3 Print Date 05/02/2008
REVISION DATE: 12/21/2007
140-88-5 Ethyl Acrylate
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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