FarmSaver.com "For Chemical Emergency"
Spill, Leak, Fire, Exposure or Accident, Call:
P.O. Box 21365, Seattle, WA 98111
Chemtrec (24 Hours): (800) 424-9300
(800) 979-8994
Outside U.S., call collect: (703) 527-3887
Chemtrec (24 Hours): (800) 424-9300
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION
PRODUCT NAME: CHEMICAL NAME (FORMULA):
Armor Tech CLT 720 (Fungicide) Tetrachloroisophthalonitrile
CHEMICAL CLASS:
Chlorinated Benzonitrile Fungicide
SECTION 2 - HAZARDOUS INGREDIENT INFORMATION
Section 313 of Sara Title III: Ingredients subject to reporting are identified by asterisk (*)
CAS NO. COMPONENT % ACGIH TLV OSHA PEL OTHER
0.1 mg/m3
1897-45-6 Tetrachloroisophthalonitrile 54.0 N/D N/D
SECTION 3 - PHYSICAL PROPERTIES
BOILING POINT: MELTING POINT: SPECIFIC GRAVITY: VAPOR PRESSURE (Chlorothalonil):
5.72 x 10-7 mmHg @25癈
212癋 N/A 1.33
VAPOR DENSITY (AIR=1): % SOLUBILITY IN WATER: % VOLATILE BY WEIGHT:
N/D Dispersible in water 34
APPEARANCE: ODOR: pH:
Off white liquid Slight 6-8
SECTION 4 ?FIRE AND EXPLOSION HAZARD DATA
FLASH POINT & METHOD: FLAMMABLE LIMITS IN AIR (LFL - UFL):
Will not flash LFL: N/A UFL: N/A
EXTINGUISHING MEDIA:
Dry Chemical, water spray, foam, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES:
Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and decomposition products. Foam and/or
dry chemical are preferred to minimize environmental contamination. If water is used, dike and collect water to prevent run
off. Wear self-contained breathing apparatus and full fire-fighting turn-out gear (Bunker gear).
UNUSUAL FIRE AND EXPLOSION HAZARDS:
May decompose in fire and generate gases that may toxic and irritating.
SECTION 5 - REACTIVITY DATA
Stable
STABILITY:
Will not occur.
HAZARDOUS POLYMERIZATION:
Thermal decomposition may produce toxic carbon and nitrogen oxides, and hydrogen
HAZARDOUS DECOMPOSITION PRODUCTS:
chloride.
None known.
CONDITIONS & MATERIALS TO AVOID:
SECTION 6 - PROTECTIVE EQUIPMENT & EXPOSURE CONTROL METHODS
RESPIRATORY PROTECTION:
Not required except for applications made in enclosed areas, such as greenhouses. In enclosed areas such as greenhouses,
applicators and other handlers must wear a NIOSH-approved respirator with N, P, R or HE filter.
LOCAL EXHAUST: MECHANICAL: SPECIAL: OTHER:
VENTILATION NORMAL NORMAL NONE NONE
PROTECTIVE GLOVES AND BOOTS: EYE PROTECTION:
Chemical-resistant gloves, such as nitrile rubber, natural Protective eyewear (e.g., goggles or full-face shield)
rubber, or butyl rubber. Chemical-resistant footwear plus
socks.
PRODUCT NAME: Armor Tech CLT 720 (Fungicide)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: WORK/HYGIENIC PRACTICES:
Coveralls. Long-sleeved shirt and long pants. NIOSH- DO NOT get into eyes. Avoid contact with skin. Avoid
approved respirator with N, P, R or HE filter when working breathing spray mist. Wash hands before eating, drinking,
in enclosed areas such as greenhouses. chewing gum, using tobacco or using the toilet. Remove PPE
immediately after handling this product. Wash outside of
gloves before removing. Remove clothing immediately if
pesticide gets inside. As soon as possible, wash thoroughly and
put on clean clothing. Follow manufacturer's instructions for
cleaning maintaining PPE. If no such instructions for
washables, use detergent and hot water. Keep and wash PPE
separately from other laundry.
SECTION 7 - HEALTH HAZARDS
PRIMARY ROUTES OF ENTRY:
Eyes, skin, inhalation and ingestion.
CARCINOGEN: NTP: MUTAGENICITY: TERATOLOGY (BIRTH DEFECTS):
Chlorothalonil ?IARC-2B N/A N/A None observed
Possible human carcinogen
EYE CONTACT:
Causes eye irritation. Do not get into eyes.
SKIN CONTACT:
May cause skin irritation. May be potential skin sensitizer. Avoid prolonged contact with skin.
INHALATION:
Avoid breathing spray mist.
INGESTION:
Do not take internally.
ALLERGIC SKIN REACTIONS (Dilute Mix):
This product may produce temporary allergic side effects characterized by redness of the eyes, mild bronchial irritation and
redness or rash on exposed skin areas. Persons having allergic reactions should contact a physician.
SECTION 8 - EMERGENCY & FIRST AID PROCEDURES
EYE CONTACT:
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice.
SKIN CONTACT:
Remove contaminated clothing and shoes. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control
center or doctor immediately for treatment advice.
INHALATION:
Move person to fresh air. If person is not breathing, call 911 or an ambulance, and then give artificial respiration preferably
mouth-to-mouth if possible. Call a poison control center or doctor immediately for treatment advice.
INGESTION:
Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do
not induce vomiting unless directed to be doctor or poison control center. If vomiting occurs, keep airway clear. Never give
anything to an unconscious person.
NOTES TO PHYSICIAN:
Persons having temporary irritation may respond to treatment with antihistamines or steroid creams and/or systemic steroids.
SECTION 9 - SPILL, LEAK & DISPOSAL INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Clean up spills immediately. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.
Small Spill: Absorb small spills or sand, vermiculate or other inert absorbent. Place contaminated material in appropriate
container for disposal.
Large Spill: Dike large spills using absorbent or impervious material such as clay or sand. Recover and contain as much free
liquid as possible for reuse. Allow absorbed material to solidify, and scrape up for disposal. Pick up wash liquid with
additional absorbent and place in a disposable container. After removal, flush contaminated area thoroughly with water. This
material should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water.
PRODUCT NAME: Armor Tech CLT 720 (Fungicide)
WASTE DISPOSAL METHOD:
DO NOT contaminate water, food, or feed by disposal. Improper disposal of excess pesticide, pesticide spray or rinsate is a
violation of Federal Law. Wastes resulting from the use of this product that cannot be used according to the label instructions
or chemically reprocessed may be disposed of on site or at a landfill or water disposal facility approved for pesticide waste
disposal, or in accordance with all applicable Federal, state or local regulations. For further guidance, contact your State
Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for
guidance.
SECTION 10 ?ECOLOGICAL INFORMATION
SUMMARY OF EFFECTS:
This product is toxic to aquatic invertebrates and wildlife. Do not apply directly to water or to areas where surface water is
present or to intertidal areas below the high-water mark. Drift and runoff may be hazardous to aquatic organisms in
neighboring areas. Do not contaminate water when disposing of equipment washwater or rinsate.
The chemical is known to leach through soil into groundwater under certain conditions as a result of label use. Use of this
chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater
contamination.
Those chemical can contaminate water through spray drift. Under conditions, it may also have a high potential for runoff into
surface water for several days to weeks after application. These include poorly draining or wet soils with readily visible slopes
toward adjacent surface waters, frequently flooded areas, areas overlaying extremely shallow ground water, areas within field
canals or ditches that drain to surface water, areas not separated from adjacent surface waters with vegetated filter strips, and
areas overlaying tile drainage systems that drain to surface water.
FISH TOXICITY (Technical):
96 hour LC50, Rainbow Trout 0.04 ppm
INVERTEBRATE (Technical):
48 hour EC50, Daphnia magna 0.068 ppm
MOVEMENT & PARTITIONING:
In Soil: Low mobility in soil. Not persistent in soil.
In Water: Stable in water.
Bioaccumulation Potential: Low.
SECTION 11 - SHIPPING DATA
DOT PROPER SHIPPING NAME:
Not Regulated.
International Transportation:
By Water: Environmentally Hazardous Substance, Liquid, N.O.S. (Chlorothalonil), Marine Pollutant, 9, UN3082, PGIII
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
Health 2
Flammability 1
Reactivity 0
Additional Labeling: None
SECTION 12 - SPECIAL INSTRUCTIONS
SPECIAL INSTRUCTIONS:
Read and follow all label instructions before use. Do not contaminate water, food, or feed by storage or disposal. Do not reuse
containers.
SECTION 13 - OTHER INFORMATION/PRECAUTIONS
SARA TITLE 3: SECTION 311/312 CATEGORIZATIONS (40CFR 370):
Acute Health Hazard
Chronic Health Hazard
SARA TITLE 3: SECTION 313 INFORMATION (40CFR 372):
Chlorothalonil (54.0%) (CAS No. 1897-45-6)
CALIFORNIA PROPOSITION 65:
This material is listed as a carcinogen by the State of California under Proposition 65.
COMMON ABBREVIATIONS THAT MAY HAVE BEEN USED: N/A = NOT APPLICABLE NA = NOT AVAILABLE N/D = NOT DETERMINED
The information provided on this Material Safety Data Sheet is furnished without warranty, expressed or implied, except that
it is accurate to the best knowledge of FarmSaver.com LLC. The data on this sheet relates only to the specific material
designated herein. FarmSaver.com LLC assumes no legal responsibility for the accuracy or completeness of this data, nor for
use or reliance upon this data.
DATE: 12/20/05 / SH3
|