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MSDS Material Safety Data Sheet
CAS

10380-28-6 107-21-1 7664-38-2

File Name: 10380-28-6_107-21-1_7664-38-2.asp

                             MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 1 of 6
March 2005




1.0 Introduction

Statement of Hazardous Nature: Hazardous according to the criteria of NZS 5433:1999.
Triggers the HSNO Act 1996 thresholds for acute
toxicity (6.1D), contact sensitiser (6.5A), target organ
systemic effects (6.9A), corrosivity (to metals 8.1A,
dermal 8.2B and ocular 8.3A), aquatic toxicity (9.1A)
and harmful to terrestrial vertebrates (9.3C).
Company Details:
Company: Osmose New Zealand
Street Address: 14 Mayo Road, Wiri, Auckland, New Zealand
Postal Address: PO Box 88-048, Clendon Town, Auckland,
New Zealand
Telephone No: (09) 277-7770
Emergency Telephone No: 0800 200 162


2.0 Product Identification

Product Name: Cutrol 375
Other Names: Cutrol
UN Number: 2586
Dangerous Goods Class: 8
Hazchem Code: 2X
Subsidiary Risk: Not applicable
Ethylene Glycol is 3rd Schedule poison
Toxic Substances Schedule:
NFPA: (Health: 3) - (Flammability: 0) - (Reactivity: 1)
Packaging Group: III
IMDG: Page 8105 (amendment 27-94)
Manufacturer: Osmose New Zealand
Use: Antisapstain treatment for freshly sawn timber or logs
being seasoned.
MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 2 of 6
March 2005




Physical Description/Properties:
Appearance: Clear green liquid.
Form: Liquid
Boiling Point: 100癈
Melting Point: < 0癈
Vapour pressure: Not available
Vapour density: Not available
Volatile Component: Not applicable
Specific gravity: 1.06 g/mL
Flash Point: Not applicable
Autoignition Temp: Not applicable
Solubility in water: Miscible
pH: ~ 2.0


Ingredients:

Chemical Entity CAS. no. Proportion
Copper 8 hydroxyquinolate 10380-28-6 2-5 %w/v
Aryl Sulphonic Acid Proprietary 20-40 %w/v
1, 2 Ethanediol (Ethylene Glycol) 107-21-1 10-30 %w/v
Phosphoric acid 7664-38-2 <1 %w/v
Water Balance



3.0 Health Hazard Information

Acute Effects:
Swallowed: Causes gastrointestinal irritation, nausea, vomiting, and diarrhoea.
Eye: Corrosive. Causes irreversible damage.
Skin: Corrosive. Causes skin burns on repeated or prolonged contact.
Inhaled: Respiratory sensitiser. Causes drowsiness, nausea and vomiting.
MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 3 of 6
March 2005




Chronic Effects:
Increased risk with Wilson's Disease. Toxicity caused by accumulation of copper in
sensitive individuals.


First Aid:
Swallowed: Never give anything by mouth to an unconscious person. Give water or milk
to drink.
DO NOT induce vomiting. Seek medical assistance immediately. For advice
contact the National Poisons Centre (0800 764 766) or a doctor immediately.
Eye: Immediately irrigate with copious amounts of water for a minimum of 15
minutes with eyelids held open. Seek medical assistance immediately.
Skin: Immediately flush body and clothes with large amounts of water. Remove
contaminated clothing and footwear. Wash affected areas with soap and water
for 15 minutes. Seek medical assistance if a large area is involved or if
irritation persists.
Inhaled: Remove victim to fresh air. Lay patient down and keep warm and rested. If
breathing shallow or has stopped ensure airway is clear and apply
resuscitation. Seek medical assistance.


First Aid Facilities:
Ensure an eyewash and safety showers are available and ready for use.


Advice to Doctor:
Give fluids. DO NOT induce emesis. No data on treatment, however chelation treatment
would seem appropriate. Give calcium EDTA orally and IV 2% solution in 5% dextrose
25mg/kg over a one to two hour period twice a day. The maximum dose should not
exceed 50mg/kg/day. The drug should be given in 5 day courses with a rest period of at
least two days between courses. Daily urine analyses should be done during the treatment
period. The dosage should be reduced if any unusual urinary findings appear. Watch for
anuria and/or liver damage.
MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 4 of 6
March 2005




4.0 Precautions For Use

Exposure Standards:

Workplace exposure standards: TWA WES-C:
None established for Cutrol or copper oxine
1mg/m3
Copper dust and mist as Cu -
50ppm (127mg/m3)
Ethylene glycol -


Engineering Controls:
Ensure good ventilation. Local mechanical ventilation may be required.


Personal Protection:
Avoid all skin and eye contact. Wear PVC or nitrile gloves, safety goggles or face
mask, PVC, nitrile or rubber apron, boots when handling.
An approved air supplied respirator should be worn during spraying applications.


Flammability:
Non flammable.


Environment:
Dispose of empty container safely. Triple rinse container and add residue to storage tank.
Crush or bury container in suitable landfill. Avoid contamination of any water supply with
chemical or empty container.
MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 5 of 6
March 2005




5.0 Safe Handling Information

Storage and Transport:
Road Transport: Aryl sulphonic acid
UN2586 Hazchem 2X
DG Class 8 Packaging Group III
Sea Transport: IMDG page 8105 (amendment 27-94)
Location: Store in a dry area
Bunding: Store in a bunded area
Security: Should be stored in a secure and safe area
Ventilation: Good ventilation is adequate
Temperature conditions: Store away from direct heat sources. Under extreme heat
may decompose emitting toxic fumes.
Protection from weather: Keep away from direct sunlight and from rain.
Storage: Store in a dry place away from foodstuffs. Avoid contact
with strong oxidising agents.
Dangerous Goods
Class/Subsidiary Risk: DG Class 8. No subsidiary risk


Spills and Disposal:
Wear gloves and breathing apparatus.
Contain spill by absorbing with sand, earth or other absorbent material.
Prevent from entering drains, waterways and sewers.
If spill may enter waterways contact emergency services and regional authority.
Neutralise small spills with lime, sodium carbonate or sodium bicarbonate. Absorb with
sand, earth or other absorbent material and collect for disposal.
Dispose of by liaising with a waste disposal company or by dumping at a site approved by
local authorities.


Reactivity Data:
Stable under most conditions.
Can react with oxidising materials and alkalis.
Avoid contact with metallic iron and zinc.
This product is not suitable for transport or storage in metal containers.
MATERIAL SAFETY DATA SHEET FOR


CUTROL 375
Page 6 of 6
March 2005




Fire/Explosion Hazard:
Non flammable.
Emits toxic fumes of oxides of carbon, nitrogen and sulphur when heated to
decomposition.
Full protective clothing required including self-contained breathing apparatus.
No skin surface should be exposed.



6.0 Additional Information

Toxicity Data:
Copper 8 hydroxyquinolate: Oral-mouse LD50: 10000mg/kg
Ethylene Glycol: Oral-rat LD50: 4700mg/kg

Environment:
Very ecotoxic to aquatic organisms and may cause long-term adverse effects in the
aquatic environment. CUTROL is harmful to terrestrial vertebrates.




CONTACT POINTS:
OSMOSE HEAD OFFICE NORMAL HOURS: (09) 277-7770
OSMOSE 24 HOUR EMERGENCY NUMBER: 0800 200 162




IN AN EMERGENCY, DIAL 111 - FIRE OR POLICE
24 hr Emergency No: National Poisons Centre Phone: 0800 764 766

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