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17635-21-1 127-68-4 104-15-4

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10147 - P30 BLEACH - A - ILFOCHROME CLASSIC                                                      REVISION DATE : 05/07/99




MATERIAL SAFETY DATA SHEET
P30 BLEACH - A - ILFOCHROME CLASSIC


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

P30 BLEACH - A - ILFOCHROME CLASSIC
TRADE NAME:

BL 30 Part A
SYNONYMS:

IP931111BL30A
PART No.:

2586
UN/NA (PIN) No.:

FOR MEDICAL EMERGENCY IN THE UNITED STATES AND CANADA CALL
EMERGENCY TELEPHONE:
1-800-842-9660 (PRODUCT MISUSE). FOR TRANSPORTATION EMERGENCY
CALL CHEMTREC 1-800-424-9300.

ILFORD Imaging USA Inc
SUPPLIER:
West 70 Century Road, Paramus, NJ 07653
Tel: 201-265-6000

Bryan Sammartino
CONTACT PERSON:



2. COMPOSITION, INFORMATION ON INGREDIENTS

INGREDIENT NAME: CAS No.: CONTENTS : EPA RQ: TPQ:
QUINOXALINE DERIVATIVE 7 17635-21-1 0-1 %
SODIUM 3-NITROBENZENESULFONATE 127-68-4 1-5 %
TOLUENESULFONIC ACID -para <= 5% H2- 104-15-4 5-10 %
SO4



3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:
Yellowish, slight ammonia odor, acidic, water-based, non-flammable liquid.

May cause sensitisation by skin contact.

ACUTE EFFECTS:
No specific health warnings noted.
INHALATION:

No specific health warnings noted.
INGESTION:

May cause sensitisation by skin contact. May cause allergic contact eczema.
SKIN:

Irritating to eyes.
EYES:

CHRONIC EFFECTS:
HEALTH WARNINGS:
Prolonged or repeated exposure may cause severe irritation. May cause skin irritation/eczema. May cause
sensitisation by skin contact.Liquid may irritate the skin.May cause allergy. May cause hypersensitivity.




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10147 - P30 BLEACH - A - ILFOCHROME CLASSIC REVISION DATE : 05/07/99

ROUTE OF ENTRY:
Skin and/or eye contact. Ingestion.

MEDICAL INFORMATION:
May aggravate existing: Skin disorders and allergies.



4. FIRST AID MEASURES

Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get medical attention if any
INHALATION:
discomfort continues.

DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure. Rinse mouth thoroughly.
INGESTION:
Get medical attention immediately! Immediately give a couple of glasses of water, provided the victim is fully
conscious.

Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin
SKIN:
immediately with soap and water. Get medical attention if irritation persists after washing.

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with lots of water
EYES:
while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.



5. FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for surrounding fire.


UNUSUAL FIRE & EXPLOSION HAZARDS:
May develop highly toxic or corrosive fumes if heated.

HAZARDOUS COMBUSTION PRODUCTS:
Fire creates: Corrosive gases/vapors/fumes. Sulfurous gases (SOx).



6. ACCIDENTAL RELEASE MEASURES

SPILL CLEAN-UP PROCEDURES:
Use appropriate protective clothing. Do not contaminate drainage or waterways. Neutralize with sodium
bicarbonate (baking soda), sodium carbonate (soda ash) or ILFORD BL/NE Neutralizer. Absorb spill with
non-reactive absorbent and place in non-reactive containers for disposal. Contain Spill. Use large quantities of
water to flush small spills to sanitary sewer if local regulations permit. Do not flush to septic tank. See Section
13 for disposal considerations. Flush with plenty of water to clean spillage area. Do not let washing down water
contaminate ponds or waterways. Inform Authorities if large amounts are involved.



7. HANDLING AND STORAGE

HANDLING PRECAUTIONS:
Avoid spilling, skin and eye contact. Provide good ventilation. Individuals liable to allergic reactions should not
handle the product Read and follow manufacturer's recommendations.

STORAGE PRECAUTIONS:
Keep in cool, dry, ventilated storage and closed containers. Store below 75癋. Keep in original container. Keep
containers closed tightly.

STORAGE CRITERIA:
Chemical storage.



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10147 - P30 BLEACH - A - ILFOCHROME CLASSIC REVISION DATE : 05/07/99




8. EXPOSURE CONTROLS, PERSONAL PROTECTION


PROTECTIVE EQUIPMENT:




ENGINEERING CONTROLS:
Provide eyewash station and safety shower.

Provide adequate general and local exhaust ventilation. Must not be handled in confined spaces without adequate
VENTILATION:
ventilation. General room ventilation should provide for 10 - 15 room air changes per hour.

RESPIRATORS: Respiratory protection must be used if air concentration exceeds acceptable level. An acid gas/organic vapor
cartridge should be used.

PROTECTIVE GLOVES:
Use protective gloves made of: Rubber (natural,latex). Neoprene. Polyethylene.

EYE PROTECTION:
Wear approved safety goggles.

PROTECTIVE CLOTHING:
Wear rubber apron.



9. PHYSICAL AND CHEMICAL PROPERTIES

Liquid.
APPEARANCE/PHYSICAL STATE:
Yellowish.
COLOR:
Slight. Ammonia.
ODOR:
Soluble in water.
SOLUBILITY DESCRIPTION:
212 PRESSURE: 760mmHg
BOILING POINT (癋, interval):
1.04 TEMPERATURE (癋): 68
DENSITY/SPECIFIC GRAVITY (g/ml):
<1.0
pH-VALUE, CONC. SOLUTION:


10. STABILITY AND REACTIVITY

Normally stable.
STABILITY:

CONDITIONS TO AVOID:
Avoid excessive heat for prolonged periods of time.

HAZARDOUS POLYMERIZATION:
Will not polymerize.

MATERIALS TO AVOID:
Avoid contact with other photographic solutions and/or cleaning compounds.

HAZARDOUS DECOMPOSITION PRODUCTS:
Irritating gases/vapors/fumes of: Sulfurous gases (SOx).



11. TOXICOLOGICAL INFORMATION

p-toluenesulphonic acid 1000; sodium nitrobenzenesulphonate 11000 mg/kg (oral
TOXIC DOSE - LD 50:
rat)




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10147 - P30 BLEACH - A - ILFOCHROME CLASSIC REVISION DATE : 05/07/99

TOXICOLOGICAL INFORMATION:
This chemical formulation has not been tested for health effects. Exposure effects listed are based on existing
health data for the individual components which comprise the mixture.



12. ECOLOGICAL INFORMATION

>500 p-toluenesulphonic acid
LC 50, 96 HRS, FISH, mg/l:
8665 sodium nitrobenzenesulphonate
EC 50, 48 HRS, DAPHNIA, mg/l:
ECOLOGICAL INFORMATION:
Not regarded as dangerous for the environment.



13. DISPOSAL CONSIDERATIONS

DISPOSAL METHODS:
Bleach solution, both unused and spent, are RCRA Hazardous Waste UNLESS neutralized before disposal.
Neutralized bleach solution may be allowed to be discharged to sanitary sewer by permit IF allowed by local
regulations. Consult your local authority for advice. Do not discharge to septic system. Bleach solution that
cannot be discharged to sanitary sewer can be disposed of by a licensed hazardous waste contractor.



14. TRANSPORT INFORMATION

LABEL FOR CONVEYANCE:




ARYLSULPHONIC ACID <5% SULPHURIC ACID
PROPER SHIPPING DESCRIPTION II:
LIMITED QUANTITY EXEMPTION To obtain additional information on
GENERAL:
packaging for shipment refer to the Code of Federal Regulations - CFR 49 and your
carrier.

U.S. DOT:
2586
UN/NA No.:
CORROSIVE (Black/white diam.) DOT17
U.S. DOT HAZARD LABEL:
Corrosive Material.
U.S. DOT CLASS:


SEA TRANSPORT:
2586
UN No. SEA:
8
IMDG CLASS:
8105
IMDG PAGE No.:
8-06
EmS No.:
700
MFAG TABLE No.:
No.
MARINE POLLUTANT:

AIR TRANSPORT:
8
UN No., AIR:
Ship by cargo aircraft ONLY
INFORMATION ON AIR TRANSPORT:


15. REGULATORY INFORMATION

REGULATORY STATUS OF INGREDIENTS:
NAME: CAS No: TSCA: CERCLA: SARA 302: SARA 313: DSL(CAN):
QUINOXALINE DERIVATIVE 7 17635-21-1 Yes Yes


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10147 - P30 BLEACH - A - ILFOCHROME CLASSIC REVISION DATE : 05/07/99

SODIUM 3-NITROBENZENESULFONATE 127-68-4 Yes No No No Yes
TOLUENESULFONIC ACID -para <= 5% H2- 104-15-4 Yes No No No
SO4


US FEDERAL REGULATIONS:
TSCA: The ingredients of this product are on the TSCA Inventory.
REGULATORY STATUS:


STATE REGULATIONS:
Florida Hazardous Substance List Massachusetts Right-to-Know. Pennsylvania
STATE REGULATORY STATUS:
Right-to-Know.



16. OTHER INFORMATION



ILFORD IMAGING USA INC. BELIEVES THE INFORMATION AND
USER NOTES:
RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON CORRECT
AND FACTUAL DATA. HOWEVER, NO EXPRESS OR IMPLIED GUARANTEE
OR WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THIS
INFORMATION. USE THIS INFORMATION ONLY TO SUPPLEMENT OTHER
INFORMATION YOU HAVE GATHERED AND THEN MAKE AN
INDEPENDENT DETERMINATION ABOUT THE COMPLETENESS AND
SUITABILITY OF ALL INFORMATION TO INSURE THE PROPER USE AND
DISPOSAL OF THIS PRODUCT AND THE HEALTH AND SAFETY OF
EMPLOYEES AND CUSTOMERS.

European Photographic Chemical Industry Code of Practice For Classification And
INFORMATION SOURCES:
Labelling Material Safety Data Sheet, Misc. manufacturers. Safeware Quasar Ltd
USA Regulatory Information ANSI Z400.1-1998 Material Safety Data Sheets -
Preparation


Dr D W Butcher, ILFORD IMAGING Limited, Mobberley, Knutsford, Cheshire,
PREPARED BY:
WA16 7JL. ENGLAND.

16/5/97
REVISION No./Repl. MSDS of:




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