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CAS

68476-85-7 64741-65-7 123-86-4 103-09-3 109-60-4 64742-52-5 110-19-0

File Name: 68476-85-7_64741-65-7_123-86-4_103-09-3_109-60-4_64742-52.asp

                                                                       Material Safety Data Sheet

Revision Date 25-Aug-2008


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product code DA7101
Product name Engage
Recommended Use Lubricant

Supplier Drummond American Corporation
600 Corporate Woods Parkway
Vernon Hills, IL 60061

(847) 913-9313


Emergency telephone number (888) 426-4851

2. HAZARDS IDENTIFICATION

Emergency Overview
Flammable. Irritant. May be harmful if swallowed.

Color Colorless Odor Solvent Form Aerosol

Aggravated Medical Conditions None Known

Principal Routes of Exposure Eyes. Ingestion. Inhalation. Skin absorption. Skin contact.

Potential health effects

Eyes Contact with eyes may cause irritation. Extreme overexposure may cause. Chemical
burns. Irreversible damage to eyes.

Skin May cause skin irritation and/or dermatitis. Extreme overexposure may cause.
Chemical burns.

Inhalation Exposure to vapors may cause the following effects. Shortness of breath. Dizziness.
Light headedness. Extreme overexposure may cause. Possible asphyxiation.
Chemical pneumonitis. Central nervous system effects. Harmful by inhalation.

Ingestion May cause chemical pneumonitis if aspirated into lungs. Extreme overexposure may
cause. Gastrointestinal irritation. Kidney damage. Liver abnormalities. Central
nervous system effects.




Page 1 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________


3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight %
L.P.G. (liquified petroleum gas) 68476-85-7 10-30
Naphtha (petroleum), heavy alkylate 64741-65-7 7-13
n-Butyl acetate 123-86-4 1-5
2-Ethylhexyl Acetate 103-09-3 3-7
n-Propyl acetate 109-60-4 1-5
Hydraulic Oil Antiwear Additive Mixture 0.5-1.5
Petroleum distillates, hydrotreated heavy 64742-52-5 40-70
naphthenic
Isobutyl acetate 110-19-0 1-5

4. FIRST AID MEASURES

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 20
minutes. Seek medical attention.

Skin contact Wash area thoroughly with soap and water. Remove and wash contaminated
clothing before re-use.

Ingestion Drink 1 or 2 glasses of water. Do not induce vomiting. Never give anything by mouth
to an unconscious person. Seek medical attention.

Inhalation Remove to fresh air. Provide oxygen if breathing is difficult. If not breathing, give
artificial respiration. Keep warm and quiet. Seek medical attention.

5. FIRE FIGHTING MEASURES

Flash point 癈 No data available
Flash point 癋 No data available
Method No information available

Autoignition temperature 癈 No data available
Autoignition temperature 癋 No data available

Flammability Limits (% in Air)
Upper 9.5%
Lower 0.8%

Specific Information for Aerosol Products

Flame extension >18 inches
Flashback None

Suitable extinguishing media
Water fog. Water spray. Carbon dioxide (CO2). Dry chemical. Foam. Alcohol foam.

Special protective equipment for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.




Page 2 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________

Special Fire-Fighting Procedures
Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when
exposed to extreme heat.

Fire and Explosion Hazards
Material is highly volatile and readily gives off vapors. Vapors are heavier than air and may travel along the ground to an
ignition source distant from material handling area. Possible ignition sources include pilot lights, flames, lighted
cigarettes, heating elements, electric motors, sparks from electrical switches. Evacuate area of unprotected and
unnecessary personnel. Do not use direct water stream.

Sensitivity to shock Sensitivity to static discharge
No information available. No information available.


6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Keep people away from and upwind of spill/leak. Ensure adequate ventilation. Remove all sources of ignition.

Clean-up methods - small spill
Absorb with fire resistant absorbent. Dispose of absorbent in accordance with local, state and federal regulations.

Clean-up methods - large spill
Dike or dam large spills. Do not allow product to reach sewage system, soil, surface or ground water, or any water
course. Notify proper authorities if entry occurs. Dispose of absorbent in accordance with local, state and federal
regulations.

7. HANDLING AND STORAGE

Handling
Keep container closed when not in use. Keep away from open flames, hot surfaces and sources of ignition. Intentional
misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Do not smoke while using.

Storage
Keep container tightly closed. Keep away from direct sunlight. Keep away from open flames, hot surfaces and sources of
ignition.




Page 3 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits


Chemical Name OSHA PEL (TWA) OSHA PEL (Ceiling) ACGIH OEL (TWA) ACGIH OEL (STEL)
Petroleum distillates, - - - -
hydrotreated heavy
naphthenic
L.P.G. (liquified 1000 ppm - 1000 ppm 2500 ppm
1800 mg/m3
petroleum gas)
Naphtha (petroleum), - - - -
heavy alkylate
2-Ethylhexyl Acetate - - - -
n-Propyl acetate 200 ppm - 200 ppm 250 ppm
840 mg/m3
Isobutyl acetate 150 ppm - 150 ppm -
700 mg/m3
n-Butyl acetate 150 ppm - 150 ppm 200 ppm
710 mg/m3
Hydraulic Oil Antiwear - - - -
Additive

Ventilation and Environmental Controls
Sufficient ventilation in volume and in pattern, should be provided to keep air contamination below current applicable
OSHA PEL or ACGIH OEL limits.

Hygiene measures
General industrial hygiene practice. Wash hands before eating or using the washroom.

Personal protective equipment

Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Wear a NIOSH approved respirator with chemical/mechanical filters for chemicals listed in Section 3 when
ventilation is restricted.

Hand Protection
Gloves are recommended to prevent prolonged or repeated contact. Chemical resistant gloves. Polyvinyl alcohol
gloves.

Eye protection
ANSI approved safety glasses or splash goggles with face shield are recommended.

Skin and body protection
Wear appropriate clothing to minimize skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form Aerosol Color Colorless
Odor Solvent Odor Threshold No information available
pH Not Applicable Specific Gravity 0.797
Vapor pressure No data available Vapor density No data available
Evaporation Rate Slower than Ether (ether = 1) VOC Content 42.77
Water solubility Insoluble in water

Page 4 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________


9. PHYSICAL AND CHEMICAL PROPERTIES
Partition Coefficient Not Applicable
(n-octanol/water)

Boiling point/range 癈 -53.2 Boiling point/range 癋 -43.7
Melting point/range 癈 Not Applicable Melting point/range 癋 Not Applicable
Flash point 癈 No data available Flash point 癋 No data available



10. STABILITY AND REACTIVITY

Stability
Stable under normal conditions.

Conditions to avoid
Heat, flames and sparks.

Incompatability
Strong oxidizing agents. Strong mineral acids. Alkalis.

Hazardous Decomposition Products
May produce forms of. Carbon monoxide. Carbon dioxide. phosgene.

Polymerization
Hazardous polymerization does not occur.



11. TOXICOLOGICAL INFORMATION
Component Information

Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat)
Petroleum distillates, 2.18 mg/L 2.18 mg/L 2.18 mg/L
hydrotreated heavy 2000 mg/kg 2000 mg/kg 2000 mg/kg
naphthenic 5000 mg/kg 5000 mg/kg 5000 mg/kg
64742-52-5
L.P.G. (liquified petroleum - - -
gas)
68476-85-7
Naphtha (petroleum), heavy 2000 mg/kg 2000 mg/kg 2000 mg/kg
alkylate 3000 mg/kg 3000 mg/kg 3000 mg/kg
64741-65-7 5.04 mg/L 5.04 mg/L 5.04 mg/L
7000 mg/kg 7000 mg/kg 7000 mg/kg
2-Ethylhexyl Acetate 3 g/kg 3 g/kg 3 g/kg
103-09-3
n-Propyl acetate 9370 mg/kg 9370 mg/kg 9370 mg/kg
109-60-4 17760 mg/kg 17760 mg/kg 17760 mg/kg
Isobutyl acetate 13400 mg/kg 13400 mg/kg 13400 mg/kg
110-19-0 5000 mg/kg 5000 mg/kg 5000 mg/kg
n-Butyl acetate 10768 mg/kg 10768 mg/kg 10768 mg/kg
123-86-4 390 ppm 390 ppm 390 ppm
17600 mg/kg 17600 mg/kg 17600 mg/kg


Page 5 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________

Chemical Name LD50 (oral,rat) LD50 (dermal,rat/rabbit) LC50 (inhalation,rat)
Hydraulic Oil Antiwear - - -
Additive
Mixture

Synergistic Products
None known

Potential health effects

Sensitization Chronic toxicity
None known . See Section 2 .

Mutagenic effects Teratogenic effects
None known . None known .

Reproductive toxicity Target Organ Effects
None known . Kidney. Liver. Cardiovascular system.

Carcinogenic effects
See Table Below.

Chemical Name ACGIH OEL - IARC NTP - Known NTP - Suspected OSHA RTK
Carcinogens Carcinogens Human Carcinogens
Carcinogens
Petroleum distillates, Not Listed Group 1 Not Listed Not Listed Listed
hydrotreated heavy
naphthenic
L.P.G. (liquified petroleum Not Listed Not Listed Not Listed Not Listed Not Listed
gas)
Naphtha (petroleum), heavy Not Listed Not Listed Not Listed Not Listed Not Listed
alkylate
2-Ethylhexyl Acetate Not Listed Not Listed Not Listed Not Listed Not Listed
n-Propyl acetate Not Listed Not Listed Not Listed Not Listed Not Listed
Isobutyl acetate Not Listed Not Listed Not Listed Not Listed Not Listed
n-Butyl acetate Not Listed Not Listed Not Listed Not Listed Not Listed
Hydraulic Oil Antiwear Not Listed Not Listed Not Listed Not Listed Not Listed
Additive




12. ECOLOGICAL INFORMATION
Petroleum distillates, hydrotreated heavy naphthenic
Water Flea Data
Daphnia magna EC50>1000 mg/L (48 h)
Naphtha (petroleum), heavy alkylate
Water Flea Data
Mysidopsis bahia LC50=2 mg/L (48 h)
n-Propyl acetate
Water Flea Data
Daphnia magna EC50=318 mg/L (24 h)
Isobutyl acetate


Page 6 / 8
Product code DA7101 Product name Engage
______________________________________________________________________________________

Water Flea Data
Daphnia magna EC50=168 mg/L (24 h)
n-Butyl acetate
Microtox Data
Photobacterium phosphoreum EC50=70.0 mg/L (5 min)
Photobacterium phosphoreum EC50=82.2 mg/L (15 min)
Pseudomonas putida EC50=959 mg/L (18 h)
Photobacterium phosphoreum EC50=98.9 mg/L (30 min)
Water Flea Data
water flea EC50=44 mg/L (48 h)



13. DISPOSAL CONSIDERATIONS

Disposal Information
Full or partially full containers are considered hazardous waste. Do not puncture or incinerate.

Waste from residues / unused products
Dispose of all product, residues and clean-up materials in accordance with local, state, and federal regulations. Do not
puncture or incinerate.

14. TRANSPORT INFORMATION


DOT
UN1950 Aerosols, flammable, 2.1
Exception: (Compressed Gas not more than 1.0L) Consumer Commodity ORM-D

TDG
UN1950 AEROSOLS, flammable, 2.1

IMDG/IMO
UN1950 Aerosols, flammable, 2.1

IATA
UN1950 Aerosols, flammable, 2.1

MEX
UN1950 Aerosols, flammable, 2.1

15. REGULATORY INFORMATION




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Product code DA7101 Product name Engage
______________________________________________________________________________________


15. REGULATORY INFORMATION
Chemical Name New Jersey - RTK Pennsylvania - RTK California Prop. 65
Petroleum distillates, Not Listed Not Listed Not Listed
hydrotreated heavy
naphthenic
L.P.G. (liquified petroleum Listed Listed Not Listed
gas)
Naphtha (petroleum), heavy Not Listed Not Listed Not Listed
alkylate
2-Ethylhexyl Acetate Not Listed Listed Not Listed
n-Propyl acetate Listed Listed Not Listed
Isobutyl acetate Listed Listed Not Listed
n-Butyl acetate Listed Listed Not Listed
Hydraulic Oil Antiwear Not Listed Not Listed Not Listed
Additive



Chemical Name EINECS DSL NDSL TSCA
Petroleum distillates, hydrotreated heavy X X - X
naphthenic
L.P.G. (liquified petroleum gas) X X - X
Naphtha (petroleum), heavy alkylate X X - X
2-Ethylhexyl Acetate X X - X
n-Propyl acetate X X - X
Isobutyl acetate X X - X
n-Butyl acetate X X - X
Hydraulic Oil Antiwear Additive - - - -

CPRC This product has been classified in accordance with the hazard criteria of the
Controlled Product Regulations and the MSDS contains all of the information
required by the Controlled Product Regulations




16. OTHER INFORMATION


NFPA HMIS
Health 2 Health 2
Flammability 4 Flammability 4
Reactivity 0 Physical Hazard 0

Prepared By Michael Katz, Regulatory Affairs Specialist

The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the
company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and
suitable to their circumstances.




Page 8 / 8

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