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17557-23-2 68609-97-2 38-43-5 15625-89-5

File Name: 17557-23-2_68609-97-2_38-43-5_15625-89-5.asp

Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoKwick Resin
Article number: 20-812x
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 1 / 5
1 Identification of the substance / preparation and of the company
Product: Buehler EpoKwick Resin
Article number: 20-812x
Registration number: not applicable
Use: Epoxy resin
Identified use: none
Method of operation: See product information.
Company: Buehler GmbH
In der Steele 2
D-40599 D黶seldorf (Germany/Allemagne)
Phone: 0800 707 6273
Fax: 0800 707 6274
Homepage: www.buehler-met.de/en/
E-mail: sales@buehler.co.uk
Emergency phone: 0800 707 6273 (Only valid if dialled within the UK)
Responsible: Simonavicius@chemiebuero.de
2 Hazards identification
Physico-chemical hazards: See chapter 10.
Human health dangers: See R-phrases.
Environmental hazards: See R-phrases.
Other hazards: none
Hazard symbols:


Irritant Dangerous for the
environment
R-phrases: R 36/38: Irritating to eyes and skin.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
3 Composition / Information on ingredients
1,3-Bis(2,3-epoxypropoxy)-2,2-dimethylpropane 5 - < 20%
Xi, R38-43 CAS: 17557-23-2, EINECS/ELINCS: 241-536-7, EU-INDEX: 603-094-00-7, ECBnr:
Oxirane, mono[(C12-14-alkyloxy)methyl] derivs. 10 - < 20%
Xi, R38-43 CAS: 68609-97-2, EINECS/ELINCS: 271-846-8, EU-INDEX: 603-103-00-4, ECBnr:
Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight 60 - < 80%
Xi-N, R36/38-43-51/53 CAS: 25068-38-6, EINECS/ELINCS: 500-033-5, EU-INDEX: 603-074-00-8, ECBnr:
Trimethylolpropan triacrylate 5 - < 20%
Xi, R36/38-43 CAS: 15625-89-5, EINECS/ELINCS: 239-701-3, EU-INDEX: 607-111-00-9, ECBnr:
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
General information: Change soaked clothing.
Inhalation: Ensure supply of fresh air.
In the event of symptoms seek for medical treatment.
Skin contact: In case of contact with skin wash off immediately with soap and water.
Consult a doctor if skin irritation persists.
Eye contact: In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
Ingestion: Consult a doctor immediately.
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Advice to doctor: Treat symptomatically.




http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00005 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoKwick Resin
Article number: 20-812x
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 2 / 5
5 Fire-fighting measures
Suitable extinguishing media: Foam.
Dry powder.
Water spray jet.
Carbon dioxide.
Extinguishing media that must not Full water jet.
be used:
Special exposure hazards arising Unknown risk of formation of toxic pyrolysis products.
from the substance or preparation
itself or combustion products:
Special protective equipment for Use self-contained breathing apparatus.
firefighters:
Additional information: Fire residues and contaminated firefighting water must be disposed of in accordance within the local
regulations.
6 Accidental release measures
Personal precautions: High risk of slipping due to leakage/spillage of product.
Environmental precautions: Prevent spread over a wide area (e.g. by containment or oil barriers).
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up: Pick up with absorbent material (e.g. sand, sawdust, universal absorbent, diatomaceous earth).
Dispose of absorbed material in accordance within the regulations.
7 Handling and storage
Advice on safe handling: No special measures necessary if used correctly.
Advice on protection against fire No special measures necessary.
and explosion:
Requirements for storage rooms Keep only in original container.
and vessels:
Advice on storage compatibility: Do not store together with oxidizing agents.
Further information on storage Keep container tightly closed.
conditions:
Keep container in a well-ventilated place.
8 Exposure controls / personal protection
Additional advice on system Ensure adequate ventilation on workstation.
design:
Ingredients with occupational exposure limits to be monitored: (GB)
( not applicable )
Respiratory protection: not applicable
Hand protection: Butyl rubber, >120 min (EN 374).
Eye protection: Safety glasses.
Skin protection: Light protective clothing of plastic material.
General protective measures: Avoid contact with eyes and skin.
Do not inhale vapours.
Hygiene measures: Remove soiled or soaked clothing immediately.
Do not eat, drink, smoke or take drugs at work.
Wash hands before breaks and after work.
Use barrier skin cream.
Delimitation and monitoring of the not applicable
environmental exposition:




http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00005 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoKwick Resin
Article number: 20-812x
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 3 / 5
9 Physical and chemical properties
Form: liquid
Color: yellow
Odor: characteristic
pH-value: not applicable
pH-value [1%]: not applicable
Boiling point [癈]: 205-304
Flash point [癈]: 93
Flammability [癈]: not determinated
Lower explosion limit: not applicable
Upper explosion limit: not applicable
Oxidizing properties: no
Vapour pressure [kPa]: not determinated
Density [g/ml]: 1,10
Density at [癈]: 20癈
Bulk density [kg/m砞: not applicable
Solubility in water: immiscible
Partition coefficient [n- not determinated
octanol/water]:
Viscosity: not applicable
Relative vapour density not determinated
determined in air:
Evaporation speed: not determinated
Melting point [癈]: not determinated
Autoignition temperature [癈]: not applicable
Decomposition temperature [癈]: not determinated
10 Stability and reactivity
Hazardous reactions: Reactions with amines.
Reactions with strong alkalies.
Hazardous decomposition No hazardous decomposition products known.
products:
11 Toxicological information
Acute oral toxicity: not determinated
Acute dermal toxicity: not determinated
Acute inhalational toxicity: not determinated
Irritant effect on eye: not determinated
Irritant effect on skin: not determinated
Sensitization: not determinated
Subacute toxicity: not determinated
Chronic toxicity: not determinated
Mutagenicity: not determinated
Reproduction toxicity: not determinated
Carcinogenicity: not determinated
Experiences made in practice: none
General remarks: Toxicological data are not available.
The product was classified on the basis of the calculation procedure of the preparation directive.




http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00005 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoKwick Resin
Article number: 20-812x
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 4 / 5
12 Ecological information
Fish toxicity: not determinated
Daphnia toxicity: not determinated
Behaviour in environment not determinated
compartments:
Behaviour in sewage plant: not determinated
Bacteria toxicity: not determinated
Biological degradability: not determinated
COD: not determinated
BOD 5: not determinated
AOX-advice: The product contains organically bound halogen in accordance with the formulation.
2006/11/EC: yes
General information: The product was classified on the basis of the calculation procedure of the preparation directive.
13 Disposal considerations
Disposal / Product: Disposal in an incineration plant in accordance with the regulations of the local authorities.
Dispose of as hazardous waste.
Disposal / Contaminated Packaging that cannot be cleaned should be disposed of as for product.
packaging:
Uncontaminated packaging may be taken for recycling.
Waste no. (recommended): 080409*
14 Transport information
Classification according to ADR: UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol A Epoxy resin) 9, III
- Classification Code: M6
- ADR Limited Quantities: LQ7: 5l
- Label:


Classification according to IMDG: UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol A Epoxy resin) 9 III
- IMDG Limited Quantities: LQ: 5 l
- EMS: F-A, S-F
- Label:


Classification according to IATA: UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol A Epoxy resin-mixture) 9 III
- Label:




http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00005 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoKwick Resin
Article number: 20-812x
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 5 / 5
15 Regulatory information
Exposure scenario: not applicable
Chemical safety report: not applicable
Labelling: The product is classified and labelled in accordance within EC-directives.
Hazard symbols:


Irritant Dangerous for the
environment
Contains: - 1,3-Bis(2,3-epoxypropoxy)-2,2-dimethylpropane
- Trimethylolpropan triacrylate
- Oxirane, mono[(C12-14-alkyloxy)methyl] derivs.
- Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight
700
R-phrases: R 36/38: Irritating to eyes and skin.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrases: S 24/25: Avoid contact with skin and eyes.
S 28.2: After contact with skin, wash immediately with water and soap.
S 37/39: Wear suitable gloves and eye/face protection.
S 61: Avoid release to the environment. Refer to special instructions, safety data sheets.
Special labelling: Contains epoxy-containing compounds. Observe manufacturer's instructions.
Authorisation, TITEL VII: not applicable
Restrictions, TITEL VIII: not applicable
EEC-REGULATIONS: 1967/548 (2004/73, 29. ATP); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004; 1907/2006.
TRANSPORT-REGULATIONS: ADR (2007); IMDG-Code (33. Amdt.); IATA-DGR (2008).
NATIONAL REGULATIONS (GB) EH40/2005 Workplace exposure limits with amendments October 2007.
16 Other informations
R-phrases (Chapter 03): R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 43: May cause sensitisation by skin contact.
R 38: Irritating to skin.
R 36/38: Irritating to eyes and skin.
Modified position: none
Observe employment restrictions yes
for people:
VOC (1999/13/CE): not determinated
Customs Tariff: not determinated




This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall
not establish a legally valid contractual relationship.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00005 GB

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