Engineered Chemistry?br>
HEALTH 3
BIO-CLEAR?1000 FLAMMABILITY 0
REACTIVITY 0
PERSONAL I
PROTECTION
24 hr. Emergency Contact (CHEMTREC) US Tel: 1- 800 - 424-9300 - Int'l. Tel. 703 - 527 - 3887
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SUPPLIER: CLEARWATER INTERNATIONAL L.L.C. MANUFACTURER: CLEARWATER INTERNATIONAL L.L.C.
515 POST OAK BLVD., SUITE 600 100 INDUSTRIAL DRIVE
HOUSTON, TX 77027 LEETSDALE, PA 15056
?br>
PRODUCT NAME: BIO-CLEAR 1000
PRODUCT CODE: WAT0325A
PRODUCT USE/CLASS:
MSDS REVISION DATE: 11/10/05 PREPARER: KS PHONE: 713-693-4154
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT EXPOSURE LIMITS CAS# % BY WEIGHT
2,2-DIBROMO-3-NITRILOPROPIONAMIDE NONE ESTABLISHED 10222-01-2 97.6 %
3. HAZARD IDENTIFICATION
EYE: Corrosive, contact with eyes will cause burns and permanent tissue damage.
SKIN: May cause skin irritation. Allergic reactions are possible. May cause skin sensitization, an allergic reaction which becomes
evident on re-exposure to this material.
INGESTION: This material may be harmful or fatal if swallowed. Material may be irritating to mouth, throat, and stomach. Single
dose oral toxicity is considered moderate.
INHALATION: Mist may be irritating to mucous membranes and lung tissue. Single exposure to vapors is not likely to be
hazardous.
CHRONIC INFORMATION: Excessive exposure may increase the blood and tissue levels of bromine.
PRIMARY ROUTE(S) OF ENTRY: Skin contact, Inhalation, and Eye contact.
4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical
attention, if irritation persists.
SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persist.
INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention.
Weatherford products and services are subject to the Company's standard terms and conditions, available
on request or at www.weatherford.com. For more information contact an authorized Weatherford
A Weatherford Company representative. Unless noted otherwise, trademarks and service marks herein are the property of
Weatherford. Specifications are subject to change without notice.
? ?2005. Weatherford. All rights reserved.
BIO-CLEAR 1000
Page 1 of 5
Engineered Chemistry?br>
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person. Do not give anything by mouth to an unconscious person..
5. FIRE FIGHTING MEASURES
FLASH POINT: N.D. LOWER EXPLOSIVE LIMIT: N.D.
(TAGLIABUE CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.D.
AUTOIGNITION TEMPERATURE: N.D.
EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers can build up pressure if exposed to heat (fire).
SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear a self-contained breathing apparatus pressure-demand
(MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to keep containers cool.
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep material into a pile and then place into a
chemical waste container. Use caution to avoid creating dusty conditions. (See exposure controls / personal protection section)
Spilled material should be disposed of according to applicable regulations.
7. HANDLING AND STORAGE
HANDLING: Handle all chemicals with care. Wear appropriate personnel protective equipment as outlined in section 8. Wash
thoroughly after handling.
STORAGE: Keep container closed when not in use. Store in a cool, dry, well ventilated place away from incompatible materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their
exposure limits.
RESPIRATORY PROTECTION: Use a NIOSH/MSHA approved particulate respirator when inadequate ventilation exist or when
high airborne concentrations are expected.
SKIN PROTECTION: When contact is likely wear chemical resistant gloves and boots.
EYE PROTECTION: Wear safety glasses with side shields or goggles.
OTHER PROTECTIVE EQUIPMENT: Emergency eye wash stations should b e available in the work area.
HYGIENIC PRACTICES: Wash hands before eating. Use only with adequate ventilation. Remove contaminated clothing and wash
before reuse. Avoid contact with eyes, skin, and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: White
ODOR: Disinfectant.
Weatherford products and services are subject to the Company's standard terms and conditions, available
on request or at www.weatherford.com. For more information contact an authorized Weatherford
A Weatherford Company representative. Unless noted otherwise, trademarks and service marks herein are the property of
Weatherford. Specifications are subject to change without notice.
? ?2005. Weatherford. All rights reserved.
BIO-CLEAR 1000
Page 2 of 5
Engineered Chemistry?br>
BOILING POINT (RANGE): N.A.
FREEZE POINT: N/D
VAPOR DENSITY: 0.934 G/ML
VAPOR PRESSURE: N/D
PHYSICAL STATE: Powder
SOLUBILITY IN WATER: 1.5% @ 23C
PH (AS IS): N.A.
SPECIFIC GRAVITY: N.A.
10. STABILITY AND REACTIVITY DATA
CONDITIONS TO AVOID: Avoid temperature extremes
INCOMPATIBILITY: Avoid contact with strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur under normal use and storage conditions.
CHEMICAL STABILITY: This product is stable under normal storage conditions.
11. TOXICOLOGICAL INFORMATION
ORAL: The LD50 is 201 mg/kg (rat).
DERMAL: The LD50 for skin is >2000 mg/kg (rabbit).
INHALATION: The LC50 for fine dust is 0.31 mg/L (male rats).
0.24 mg/L (female rats).
12. ECOLOGICAL INFORMATION
ECOTOXICITY: Contact a company representative for detailed information.
CHEMICAL FATE INFORMATION: No product information is available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL: Consult local, state, or federal regulatory agencies for acceptable disposal procedures and disposal
locations. Disposal in streams or sewers may be prohibited by federal, state, and local regulations.
RCRA STATUS: Not determined
14. TRANSPORTATION INFORMATION
(NON-BULK SHIPMENTS)
D.O.T. PROPER SHIPPING NAME: Toxic Solid, Organic, N.O.S.,
D.O.T. TECHNICAL NAME: (2, 2-Dibromo-3-Nitrilopropionamide)
D.O.T. HAZARD CLASS: 6.1 HAZARD SUBCLASS: N/A
D.O.T. UN NUMBER: UN2811 PACKING GROUP: III RESP. GUIDE PAGE: 154
Weatherford products and services are subject to the Company's standard terms and conditions, available
on request or at www.weatherford.com. For more information contact an authorized Weatherford
A Weatherford Company representative. Unless noted otherwise, trademarks and service marks herein are the property of
Weatherford. Specifications are subject to change without notice.
? ?2005. Weatherford. All rights reserved.
BIO-CLEAR 1000
Page 3 of 5
Engineered Chemistry?br>
(BULK SHIPMENTS)
D.O.T. PROPER SHIPPING NAME: Toxic Solid, Organic, N.O.S.,
D.O.T. TECHNICAL NAME: (2, 2-Dibromo-3-Nitrilopropionamide)
D.O.T. HAZARD CLASS: 6.1 HAZARD SUBCLASS: N/A
D.O.T. UN NUMBER: UN2811 PACKING GROUP: III RESP. GUIDE PAGE: 154
T.D.G. PROPER SHIPPING NAME: Toxic Solid, Organic, N.O.S.,
T.D.G. TECHNICAL NAME: (2, 2-Dibromo-3-Nitrilopropionamide)
T.D.G. HAZARD CLASS: 6.1 HAZARD SUBCLASS: N/A
T.D.G. UN NUMBER: UN2811 PACKING GROUP: III RESP. GUIDE PAGE: 154
IMDG PROPER SHIPPING NAME: Toxic Solid, Organic, N.O.S.,
IMDG TECHNICAL NAME: (2, 2-Dibromo-3-Nitrilopropionamide)
IMDG HAZARD CLASS: 6.1 HAZARD SUBCLASS: N/A
IMDG UN NUMBER: UN2811 PACKING GROUP: III EmS No: F-A, S-A
15. REGULATORY INFORMATION
CERCLA ?SARA HAZARD CATEGORY:
SECTION 311/312: This product has been reviewed according to the EPA `Hazard Categories' promulgated under Sections 311
and 312 of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD
SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
COMPONENT CAS# % BY WEIGHT
2,2-Dibromo-3-Nitrilopropionamide 10222-01-2 97.6 %
TSCA STATUS:
All components of this product are listed on the Toxic Substance Control Act Inventory or are excluded from the listing
requirements.
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the
16 headings.
CANADIAN WHMIS CLASS: D-1B
CANADIAN ENVIRONMENTAL PROTECTION ACT:
All components of this product are listed on the Canadian Domestic Substance List (DSL).
Weatherford products and services are subject to the Company's standard terms and conditions, available
on request or at www.weatherford.com. For more information contact an authorized Weatherford
A Weatherford Company representative. Unless noted otherwise, trademarks and service marks herein are the property of
Weatherford. Specifications are subject to change without notice.
? ?2005. Weatherford. All rights reserved.
BIO-CLEAR 1000
Page 4 of 5
Engineered Chemistry?br>
16. OTHER INFORMATION
HMIS RATING ?HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 0 PERSONAL PROTECTIVE RATING: I
VERSION NUMBER: 1
REPLACES: NONE
REVISION INFORMARTION: N.A.
LEGEND: N.A. ?NOT APPLICABLE, N.E. - NOT ESTABLISHED, N.D. ?NOT DETERMINED
THIS PRODUCT'S HEALTH AND SAFETY INFORMATION IS PROVIDED TO ASSIST OUR CUSTOMERS IN ASSESSING
COMPLIANCE WITH HEALTH, SAFETY AND ENVIRONMENTAL REGULATIONS. THE INFORMATION CONTAINED HEREIN
IS BASED ON DATA AVAILABLE TO US, AND IS BELIEVED TO BE ACCURATE, ALTHOUGH NO GUARANTEE OR
WARRANTY IS PROVIDED OR IMPLIED BY THE COMPANY IN THIS RESPECT. SINCE THE USE OF THIS PRODUCT IS
WITHIN THE EXCLUSIVE CONTROL OF THE USER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE CONDITIONS
OF SAFE USE. SUCH CONDITIONS MUST COMPLY WITH ALL GOVERNMENTAL REGULATIONS.
Weatherford products and services are subject to the Company's standard terms and conditions, available
on request or at www.weatherford.com. For more information contact an authorized Weatherford
A Weatherford Company representative. Unless noted otherwise, trademarks and service marks herein are the property of
Weatherford. Specifications are subject to change without notice.
? ?2005. Weatherford. All rights reserved.
BIO-CLEAR 1000
Page 5 of 5
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