Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Identification of the Substance:
Trade Name: Limonene Dioxide
Chemical Name: 7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(2-methyloxiranyl)-
Use of the Substance:
Company Identification:
_______________________________________________________________________
European Headquarters
LyondellBasell Flavors & Fragrances, LLC LyondellBasell Flavors & Fragrances, LLC
P.O. Box 389 C/O SCM EUROPE
Jacksonville, FL 32201, USA Place de l'ALBERTINE 2
Telephone: 904-768-5800 B-1000 Brussels - Belgium
Fax:904-768-2200 Telephone: +32.2.289.05.10 Fax:+32.2.289.05.90
_______________________________________________________________________
Emergency Telephone: CHEMTREC: (USA, Canada): 1-800-424-9300 ;(All Others): 703-527-3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Typical
CAS Number EINECS Number Ingredient Weight %
96-08-2 202-475-1 LIMONENE DIOXIDE 95.00
6485-40-1 229-352-5 CARVONE, L- 2.00
112-30-1 203-956-9 DECANOL, N- 2.00
EU Classifications (refer to Section 16 for descriptions):
Symbol(s) Risk Phrase Code(s) Safety Phrase Code(s)
Xn R21 S2,13,24,36,46
3. HAZARDS IDENTIFICATION
This substance is classified as dangerous according to EU Directive 1999/45/EC.
Potential Health Effects
Acute Health Effects:
Irritating to skin. May cause sensitization by skin contact.
Chronic Health Effects:
Not Determined.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 1 of 6
Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
4. FIRST AID MEASURES
Inhalation:
Seek fresh air immediately. If breathing is difficult, seek medical advice.
Eye Contact:
Flush with water for at least 15 minutes. If irritation develops, get
medical attention.
Skin Contact:
Remove contaminated clothing. Wash affected areas with plenty of soap and
water. If irritation develops, seek medical advice.
Ingestion:
Drink lots of water to dilute substance. Get medical attention immediately
or contact a poison control center for advice.
5. FIRE FIGHTING MEASURES
Suitable Fire Extinguishing Media:
Carbon dioxide, dry chemical, foam.
Unsuitable Fire Extinguishing Media:
If water must be used, use as a spray only.
Special Exposure Hazards:
Combustible liquid. Avoid heat, sparks and open flames.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
Special Protective Equipment for Fire Fighters:
Standard turnout gear for combustible liquids.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Standard turnout gear for combustible liquids.
Environmental Precautions:
Not Determined
Cleanup Procedures:
Small spills should be absorbed by dirt, sand, or other absorbent. Large
spills may be pumped into containers for recovery/disposal.
7. HANDLING AND STORAGE
Handling:
Wear safety glasses or goggles, rubber gloves and apron when handling
material. If transferring to or from the container, use proper
grounding procedures.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 2 of 6
Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
Storage:
Do not store in close proximity to excessive heat, open flames, strong
acids or strong bases. To minimize product degradation, avoid prolonged
exposure of the substance to air. Keep container tightly closed when
not in use.
Ventilation:
Mechanical exhaust may be needed in confined and poorly ventilated areas.
Safety Stations:
An eyewash station and a safety shower should be readily available and
clearly marked.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits:
None found.
Exposure Controls:
Respiratory Protection:
A respirator is not normally required. If vapor concentration is suspected
to be high, use a NIOSH approved organic vapor respirator
Eye Protection:
Wear safety glasses or goggles.
Hand Protection:
Wear standard industrial type rubber gloves.
Skin Protection:
A rubber apron is recommended when handling the material for extended
periods of time.
Personal Hygiene:
Wash hands and other exposed areas of skin with soap and water after
handling the material.
Environmental Controls:
No environmental exposure controls required under Community environmental
protection laws.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information:
Property Result
Appearance: Clear liquid.
Odor: Mild, woody-floral
Important Health, Safety and Environmental Information:
Property Result
pH: ca. 3.7
Boiling Point: 462F (239C) (Thermal Analyzer)
Flash Point: 217F (103C) (Tag Closed Cup)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 3 of 6
Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
Melting Point: Not determined.
Flammability: Not determined.
Explosive Properties: Not an explosive.
Oxidizing Properties: Not determined.
Vapor Pressure: Not Determined
Solubility in Water (Weight%): Not determined
Solubility in Alcohol(Weight%): Not Determined
Fat Solubility: Not determined.
Partition Coefficient (n-Octanol/Water): Not determined.
Viscosity: Not determined.
Vapor Density (air=1): Not determined
Evaporation Rate (Butyl Acetate=1): Not determined.
Volatiles (Weight%): 99.87%
Specific Gravity: 1.0256 @ 25 C
10. STABILITY AND REACTIVITY
Stability:
Substance is stable and unreactive under conditions of normal use.
Conditions to Avoid:
Prolonged or excessive heat and/or exposure to air may cause non-hazardous
decomposition and/or oxidation of the substance.
Materials to Avoid:
Avoid contact with strong acids, bases and materials that react with
unsaturated hydrocarbons.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
11. TOXICOLOGICAL INFORMATION
Primary Target Organs: Eyes, skin.
Primary Entry Route(s): Eyes, Skin.
Medical Conditions Aggravated by Overexposure No known conditions.
Acute Toxicity:
Parameter Result
Acute Oral Toxicity: LD50 (rat): 5630 mg/kg.
Acute Inhalation Toxicity: LC50 (Rabbit) 60gm/m3/1H
Acute Dermal Toxicity: LD50 (rabbit): 1770 uL/kg
Eye Irritancy: RTECS lists LDO as a primary irritant
Dermal Irritancy: RTECS lists LDO as a primary irritant, with an open irritation test on
rabbits showing mild reaction severity.
Skin Sensitization: Not Determined
Mutagenicity: "Equivocal tumorigenic agent by RTECS criteria"
Teratogenicity: Not determined.
Acute Other: Not Determined.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 4 of 6
Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not detrmined
Mobility: Not determined.
Persistence and Degradability: Not determined
Bioaccumulation Potential: Not determined.
Ozone Depleting Substances: None.
13. DISPOSAL CONSIDERATIONS
Disposal Methods: This material, if discarded, is not considered a hazardous waste by EPA
regulations 40 CFR 261.
Safe Handling of Wastes: Refer to Section 8 for information pertaining to personal protective
equipment and exposure controls when handling this material for
disposal.
Community Provisions: Dispose of this material at a local, state or federally approved landfill,
incinerator or recovery facility.
14. TRANSPORT INFORMATION
Label Codes: None
DOT Proper Shipping Name (Bulk): Chemicals n.o.i.(Limonene dioxide)
DOT Proper Shipping Name (Non-Bulk): Chemicals n.o.i.(Limonene dioxide)
Marine Pollutant: No
15. REGULATORY INFORMATION
Chemical Inventories Status:
USA (TSCA): Compliant
European Community (EINECS): Compliant
Canada (DSL): NDSL Listed
Australia (AICS): Compliant
Japan (IEC): Compliant
Korea (KECI/ECL): Not Determined
Philippines (PICCS): Not Determined
China (SEPA/CICS): Compliant
USA: Federal:
SARA Title III Section 302/304: None.
SARA Title III Section 311/312: Yes.
SARA Title III Section 313: None.
Hazardous Air Pollutants: None.
USA: States:
None.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 5 of 6
Product Code 01F87AS
Revision Date 05/04/2010
Supersedes 05/13/2005
Material Safety Data Sheet Date Printed 05/11/2010
International:
16. OTHER INFORMATION
EU Classifications:
Symbol Code(s): Symbol Phrase(s):
Xn HARMFUL
Risk Phrase Codes: Risk Phrases:
R21 Harmful in contact with skin.
Safety Phrase Codes: Safety Phrases:
S2,13,24,36,46 Avoid contact with eyes. Avoid contact with skin.
U.S. NPCA/HMIS Hazardous Materials Information System
Health Flammability Reactivity Personal Protection*
2 1 1 C
0 - Minimal Hazard: No significant risk to health.
1 - Slight Hazard: Irritation or minor reversible injury possible.
2 - Moderate Hazard: Temporary or minor injury may occur.
3 - Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given.
4 - Severe Hazard: Life-threatening, major or permanent damage mayresult from single or repeated exposures.
* This rating will generally suffice for normal operating conditions.Please note however, that the type of personal
protection utilized may change based on specific use conditions (refer to Section 8).
Reason(s) for (Re)issue:
Legal entity change.
Technical Contact(s):
Environmental and Regulatory Affairs Dept.
References:
RIFM - Research Institute for Fragrance Materials RTECS- Registry of Toxic Effects of Chemical Substances
Acronyms: NTP(National Toxicology Program); IARC (International Agency for
Research on Cancer); OSHA (Occupational Health and Safety
Administration); DOT (U.S. Dept. of Transportation); NIOSH (National
Institute of Occupational Safety and Health)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 6 of 6
|