MSDS for: LN-602 Revised: 9-JAN-2004
SECTION 1:
PRODUCT IDENTIFIER: LN-602 SUBFLOOR & DECK ADHESIVE
DATE OF PREPARATION: JANUARY 9, 2004
PRODUCT USE: ADHESIVE
MANUFACTURED BY: MACCO ADHESIVES
925 EUCLID AVENUE
CLEVELAND, OH 44115, U.S.A.
ICI PAINTS (CANADA)
8200 KEELE STREET
CONCORD, ONTARIO L4K 2A5, CANADA
EMERGENCY AND MSDS TELEPHONE NUMBER: 1-800-545-2643
MSDS PREPARED BY: PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT
ICI PAINTS NORTH AMERICA
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT WT.%
CHEMICAL NAME: 2-METHYLPENTANE 5-10
COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5
CHEMICAL NAME: BENZENE, METHYL- 5-10
COMMON NAME: TOLUENE
CAS NUMBER: 108-88-3
CHEMICAL NAME: LIMESTONE 10-20
COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3
CHEMICAL NAME: KAOLIN 20-30
COMMON NAME: CLAY
CAS NUMBER: 1332-58-7
CHEMICAL NAME: QUARTZ 0.1-1.0
COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7
CHEMICAL NAME: SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 1-5
COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8
CHEMICAL NAME: DISTILLATES (PETROLEUM), STEAM-CRACKED, POLYMERS 10-20
WITH LIGHT STEAM-CRACKED PETROLEUM NAPHTHA
COMMON NAME: AROMATIC HYDROCARBON RESIN
CAS NUMBER: 68410-16-2
CHEMICAL NAME: 2,2-DIMETHYLBUTANE 1-5
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2
CHEMICAL NAME: 2,3-DIMETHYLBUTANE 1-5
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8
CHEMICAL NAME: BENZENE, ETHENYL-, POLYMER WITH 1,3-BUTADIENE 5-10
COMMON NAME: STYRENE-BUTADIENE POLYMER
CAS NUMBER: 9003-55-8
CHEMICAL NAME: 3-METHYLPENTANE 1-5
COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0
SECTION 3: HAZARDS IDENTIFICATION
PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT,
INGESTION.
EFFECTS OF OVEREXPOSURE
INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION
MAY LEAD TO LOSS OF APPETITE, MUCOUS MEMBRANE
IRRITATION, FATIGUE, DROWSINESS, DIZZINESS AND/OR
LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA,
VOMITING, CHEST PAIN, COUGHING, DIFFICULTY WITH SPEECH,
CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION,
METALLIC TASTE, CONFUSION, ANESTHETIC EFFECT OR NARCOSIS,
DIFFICULTY OF BREATHING, NEUROTOXICITY, CONVULSIONS,
PNEUMOCONIOSIS, LOSS OF CONSCIOUSNESS, DEATH.
SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN
CAUSE DERMATITIS, DEFATTING.
EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN
CAUSE CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES,
REDNESS OF EYES, SEVERE EYE IRRITATION, CORNEAL INJURY.
INGESTION: INGESTION MAY CAUSE LUNG INFLAMMATION AND DAMAGE DUE
TO ASPIRATION OF MATERIAL INTO LUNGS, FATIGUE,
DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE,
UNCOORDINATION, NAUSEA, VOMITING, DIARRHEA, GASTRO-
INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL
NERVOUS SYSTEM DEPRESSION, INTOXICATION, DIFFICULTY OF
BREATHING, PULMONARY EDEMA, CONVULSIONS, PARALYSIS,
CARDIAC FAILURE, DEATH.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: EYE, SKIN, RESPIRATORY
DISORDERS, LUNG
DISORDERS
SECTION 4: FIRST-AID MEASURES
INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED
BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE
TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL
HELP FOR ANY BREATHING DIFFICULTY.
SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT
REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR
MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE
NEEDED. REMOVE CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER,
ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF
IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL
TREATMENT.
INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY.
SECTION 5: FIRE-FIGHTING MEASURES
FLASH POINT (SETA): 1 F./ -17 C. LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 7.0 %
FIRE EXTINGUISHING MEDIA: DRY CHEMICAL OR FOAM, WATER FOG, CARBON
DIOXIDE.
UNUSUAL FIRE AND EXPLOSION HAZARDS
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE.
VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPERATURES. VAPORS ARE HEAVIER
THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH
BACK. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPERATURES.
CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY
DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES.
FIRE FIGHTING PROCEDURES
WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS
SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED
BREATHING APPARATUS.
HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS: CARBON MONOXIDE,
CARBON DIOXIDE,
TOXIC GASES.
OXIDES OF CALCIUM
SECTION 6 ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS.
ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. VENTILATE AREA WITH
EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING TOOLS. EVACUATE ALL
UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER.
COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP.
LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO
STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS
RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF
SEWERS AND WATER COURSES.
SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.
SECTION 7 HANDLING AND STORAGE
HANDLING AND STORAGE: STORE BELOW 80F. KEEP AWAY FROM HEAT, SPARKS AND
OPEN FLAME.
OTHER PRECAUTIONS
USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF
VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING
OR SMOKING. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE.
EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN
TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5
ACGIH(TWA): 500 PPM
ACGIH(STEL): C 1000 PPM
COMMON NAME: TOLUENE
CAS NUMBER: 108-88-3
ACGIH(TWA): SKIN 50 PPM OSHA(TWA): 200 PPM
OSHA( (SKIN): CEILING: 300 PPM SUPP REC STD.: NOT AVAILABLE
COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3
ACGIH(TWA): 10 MG/M3 OSHA(TWA): 5 MG/M3
COMMON NAME: CLAY
CAS NUMBER: 1332-58-7
ACGIH(TWA): 2 MG/M3 OSHA(TWA): 5 MG/M3
COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7
ACGIH(TWA): 0.05 MG/M3 OSHA(TWA): 0.1 MG/M3
COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8
OSHA(TWA): 300 PPM
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM
COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM
SKIN - DENOTES THAT ADDITIONAL EXPOSURE, OVER AND ABOVE AIRBORNE EXPOSURE,
MAY RESULT FROM SKIN ABSORPTION.
RESPIRATORY PROTECTION - CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW
APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY
PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4)
APPROVED ELASTOMERIC SEALING-SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH
ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE
THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING.
CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4).
VENTILATION - PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING
EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT: EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR
GOGGLES. IMPERVIOUS GLOVES, IMPERVIOUS
CLOTHING.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.107
BOILING RANGE (F/C): 122-231/ 50-111 WEIGHT PER GALLON: 9.22/ 11.07IMP
%VOLATILE BY VOLUME: 52.92 PHYSICAL STATE: PASTE
APPEARANCE: TAN SOLUBILE IN WATER: NO
PH: NOT APPLICABLE
SECTION 10: STABILITY AND REACTIVITY
UNDER NORMAL CONDITIONS: STABLE (SEE SECTION 5 FIRE FIGHTING MEASURES)
MATERIALS TO AVOID: OXIDIZERS, ACIDS, NITRIC ACID, MINERAL ACIDS.
STYRENE MONOMER
CONDITIONS TO AVOID: ELEVATED TEMPERATURES, CONTACT WITH
OXIDIZING AGENT, SPARKS, OPEN FLAME, IGNITION
SOURCES
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
SECTION 11: TOXICOLOGICAL INFORMATION
COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: TOLUENE
CAS NUMBER: 108-88-3
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 14.10 ML/KG SKN RBT
LD50: 636.00 MG/KG ORL RAT
LC50: 400.00 PPM IHL MOU
COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 6450.00 MG/KG ORL RAT
COMMON NAME: CLAY
CAS NUMBER: 1332-58-7
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7
CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA NO ACGIH NO
COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
LD50: > 3.16 GM/KG SKN RBT
LD50: > 5.00 GM/KG ORL RAT
COMMON NAME: AROMATIC HYDROCARBON RESIN
CAS NUMBER: 68410-16-2
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: STYRENE-BUTADIENE POLYMER
CAS NUMBER: 9003-55-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
SUPPLEMENTAL HEALTH INFORMATION
CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH SKIN. NOTICE - REPORTS
HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE
HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO
LIVER, KIDNEY, CENTRAL NERVOUS SYSTEM, BLOOD, HEART.
CARCINOGENICITY: CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A
HAZARD BY INHALATION. IARC HAS CLASSIFIED
CRYSTALLINE SILICA AS CARCINOGENIC TO HUMANS
(GROUP 1). CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE
OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. THE
NATIONAL TOXICOLOGY PROGRAM (NTP) HAS CLASSIFIED
CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN.
REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATED
MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED
TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED
SECTION 12: ECOLOGICAL INFORMATION
NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT AS A
WHOLE.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
SECTION 14: TRANSPORT INFORMATION
DOT: ADHESIVES, 3, UN1133, PGIII
IMDG: ADHESIVES, CLASS 3, UN1133, PGIII, LIMITED QUANTITY,
ADHESIVES, CLASS 3, UN1133, PGIII
IATA: ADHESIVES, 3, UN1133, PGIII,
CONSUMER COMMODITY, 9, ID8000
TDG: NOT AVAILABLE
SECTION 15: REGULATORY INFORMATION
SARA SARA CERCLA HAZ AIR MARINE
302 313 302.4 POLLUTANT POLTNT
CAS NUMBER: 108-88-3 NO YES YES YES NO
COMMON NAME: TOLUENE
AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED
(OR ARE OTHERWISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT
HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR
(CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CPR.
SECTION 16: OTHER INFORMATION
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF
PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS
INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU
MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR
YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND
SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA
HAZARD COMMUNICATION STANDARD 29CFR1910.1200.
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