Material Safety Data Sheet
WHMIS (Classification)
WHMIS (Pictograms) Protective Clothing
Not controlled under WHMIS
(Canada).
Section 1. Chemical Product and Company Identification
Product Name
USED MOTOR OIL File # W384
Code
On the DSL list.
DSL
PETRO-CANADA
Supplier
Print Date: 8/11/2004.
P.O. Box 2844
Calgary, Alberta
T2P 3E3
Used crank case oil.
Synonym
Petro-Canada Emergency
In case of
Emergency Number: (403) 296-3000
Not applicable.
Chemical Name
Canutec Transportation
Emergency: (613)
Not available.
Chemical Family
996-6666
Poison Control Centre
Not applicable.
Chemical Formula
Numbers: Consult local
telephone directory for
emergency number(s).
PETRO-CANADA An oil from industrial and non-industrial sources, which
Manufacturer Material Uses
P.O. Box 2844, Petro-Canada has been acquired for lubricating or other purposes
Centre and has become unsuitable for its original purpose due
Calgary, Alberta to the presence of impurities or the loss of original
T2P 3E3 properties. Crank case oil drainings from oil filters,
cars or trucks are included in this waste category.
Section 2. Composition/Information on Ingredients
Exposure Limits (ACGIH)
Name CAS # TLV-TWA(8 STEL CEILING % (V/V)
h)
Unburnt gasoline fractions varies Not Not Not 3-10
applicable applicable applicable
Ethylene glycol 107-21-1 Not Not 50 ppm will vary
applicable applicable
PNAs ( various Not Not Not will vary
applicable applicable applicable
Barium 7440-39-3 0.5 mg/m3 Not Not will vary
applicable applicable
7782-50-5 1.5 mg/m3 Not Not will vary
Chlorine
applicable applicable
Oxides of nitrogen varies Not Not Not will vary
applicable applicable applicable
Not Not Not will vary
various
Heavy (trace) metals - may include AS, Cd,
applicable applicable applicable
Cr, Co, Cu, Fe, Pb, Hg, Mn, Mo, Ni, Se, V,
Zn, or their inorganic compounds.
The following components may have been
found in this waste at concentrations that
may meet WHMIS ingredient disclosure
criteria or other legislative requirements.
Continued on Next Page
Page Number: 2
USED MOTOR OIL
Section 3. Hazards Identification.
Low toxicity on ingestion. Has laxative effect. Mildly irritating to eyes. Negligible breathing
Potential Acute Health
hazard at normal temperatures (up to 38 deg C) or recommended blending temperatures.
Effects
Elevated temperatures or mechanical action may form vapours, mists, or fumes. Inhalation of oil
mists or vapours from hot oil may cause irritation of the upper respiratory tract.
Prolonged or repeated contact with skin may cause irritation and possibly dermatitis.
Potential Chronic Health
Effects
Section 4. First Aid Measures
Check for and remove any contact lenses. DO NOT use an eye ointment. Copious warm water
Eye Contact
flush - 15 minutes. Physician assessment if eyes inflamed.
Remove contaminated clothing - launder before reuse. Soap and water wash. Discard saturated
Skin Contact
leather articles.
Evacuate the victim to a safe area as soon as possible. Allow the victim to rest in a well
Inhalation
ventilated area. Seek immediate medical attention.
Not applicable
Hazardous Inhalation
DO NOT induce vomiting. Force fluids. Activated charcoal tablets.
Ingestion
No additional remark.
Hazardous Ingestion
Section 5. Fire-fighting Measures
Low fire hazard.
The Product is:
Auto-Ignition Temperature Not available.
Not available.
Flash Points
Not available.
Flammable Limits
Smoke on combustion.
Products of Combustion
Avoid contact with strong oxidizing agents, including peroxides, chlorine and strong acids.
Fire Hazards in Presence
Addition of water or foam may cause frothing.
of Various Substances
Do not cut, drill or weld empty containers.
Explosion Hazards in
Presence of Various
Substances
Respiratory and eye protection required for fire fighting personnel. A self contained breathing
Fire Fighting Media
apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small
and Instructions
outdoor fires, which may be easily extinquished with a portable fire extinquisher, use of a SCBA
may not be required. SMALL FIRE: Use DRY chemicals, CO2, water spray or foam. LARGE
FIRE: Use water spray, fog or foam.
No additional remark.
Special Remarks on
Fire Hazards
No additional remark.
Special Remarks on
Explosion Hazards
Continued on Next Page
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USED MOTOR OIL
Section 6. Accidental Release Measures
Contain spill. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth,
Small Spill
commericial sorbents. Do not use combustible material such as sawdust. Scoop up used
absorbent and rags into drums. For water spills, try to contain floating material and remove
material by skimming or with suitable absorbent. Check with applicable jurisdictions for specific
disposal requirements of material and empty containers.
No additional remark.
Large Spill
Section 7. Handling and Storage
Wash hands after handling and before eating. Launder work clothes frequently. Discard
Handling
saturated leather goods. Avoid inhalation and skin contact especially when handling used oil.
An API study has indicated that prolonged or repeated skin exposure to used motor oils can
cause cancer in mice.
Store in cool, well-ventilated area. May be stored in steel tanks or drums.
Storage
Section 8. Exposure Controls/Personal Protection - The selection of personal protective
equipment varies, depending upon conditions of use.
Provide exhaust ventilation or other engeneering controls to keep the airborne concentrations of
Engineering Controls
vapors below their respective threshold limit value. Ensure that eyewash station and safety
shower is proximal to the work-station location.
Splash goggles. Gloves (impervious). For direct contact of more than 2 hours -- VITON or
Personal Protection
NITRILE gloves are needed, otherwise, PVC gloves may be used. Wear long sleeved clothing to
minimize skin contact. Respirator normally not necessary. If mist generated by heating,
spraying, etc. wear approved organic vapour respirator suitable for oil mist in areas with
sufficient oxygen.
No additional remarks
Personal Protection in
Case of a Large Spill
Various
Exposure Limits
Section 9. Physical and Chemical Properties
Liquid. (Viscous liquid.) Burnt hydrocarbon.
Physical State and Odor
Appearance
Not available.
Taste
Not available.
Dropping Point
Black. (Dark.)
Color
Not available.
Penetration (@ 25癈)
230癈 (446癋)
Boiling Point
Not available.
Melting Point
0.8 (Water = 1)
Specific Gravity
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Oil / Water Dist. Coeff.
Not available.
Viscosity (@ 40 癈)
Insoluble in cold water.
Solubility
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Page Number: 4
USED MOTOR OIL
Section 10. Stability and Reactivity
The product is stable.
Stability
Not available.
Instability Temperature
Avoid excessive heat. Formation of oil mist.
Conditions to Avoid
None known.
Incompatibility with Decomposition
Highly reactive with oxidizing
Various Substances products:
agents.
Not applicable
Corrosivity
Peroxides, chlorine, strong acids, etc.
Special Remarks on
Reactivity
No additional remark.
Special Remarks on
Corrosivity
Section 11. Toxicological Information
Inhalation. Skin contact.
Routes of Entry
Prolonged and/or repeated contact with used motor oil has caused skin cancer in experimental
Toxicity to Animals
animals. The relationship of these results to humans has not been fully established.
Prolonged or repeated contact with skin may cause irritation and possibly dermatitis.
Chronic Effects on
Humans
Low toxicity on ingestion. Has laxative effect. Mildly irritating to eyes. Negligible breathing
Other Toxic Effects
hazard at normal temperatures (up to 38 deg C) or recommended blending temperatures.
on Humans
Elevated temperatures or mechanical action may form vapours, mists, or fumes. Inhalation of oil
mists or vapours from hot oil may cause irritation of the upper respiratory tract.
No additional remark.
Special Remarks on
Toxicity to Animals
No additional remark.
Special Remarks on
Chronic Effects on
Humans
Special Remarks on Other No additional remark.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Products of Biodegradation Not available.
Not available.
Toxicity of the Products
of Biodegradation
No additional remark.
Special Remarks on the
Products of Biodegradation
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Page Number: 5
USED MOTOR OIL
Section 13. Disposal Considerations
Consult your local or regional authorities. Preferred waste management priorities are: (1) recycle
Waste Disposal
or reprocess; (2) incineration with energy recovery; (3) disposal at licensed waste disposal
facility. Ensure that disposal or reprocessing is in compliance with government requirements and
local disposal regulations.
Section 14. Transport Information
Not available
TDG Classification
Not available
Special Provisions for
Transport
Section 15. Regulatory Information and Pictograms
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): This product is on the Domestic
Other Regulations
Substances List (DSL), and is acceptable for use under the provisions of CEPA.
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
Not classified under the Dangerous Substances or Dangerous Preparations
DSD/DPD (EEC)
Directives.
WHMIS (Canada)
(Pictograms)
0
HMIS (U.S.A.) NFPA (U.S.A.)
Health Hazard
Fire Hazard
1
1
Fire Hazard
0 0
Health Reactivity
0
Reactivity
Specific hazard
a
Personal Protection
DSD/DPD (Europe)
(Pictograms)
TDG (Canada)
Not evaluated for transport
(pictograms)
Non 関alu?pour le transport
DOT (U.S.A)
(Pictograms)
Protective Clothing
(Pictograms)
Continued on Next Page
Page Number: 6
USED MOTOR OIL
Section 16. Other Information
Available upon request.
References
Note 1: This product is exempted from WHMIS legislation. Regulations do require appropriate
Other Special
identification of the waste and worker education in its handling.
Considerations
Note 2: The components of this product may have been found in this waste at concentrations that may
meet WHMIS ingredient disclosure criteria or other legislative requirements.
Prepared by Administrator on 5/20/1998. Data entry by Administrator.
Print Date: 8/11/2004.
Information Contact
For Product Safety Information: (905) 804-4752
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of
its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards
that exist.
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