Safety Data Sheet
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
552-97143 INTERGRAIN MAXIPROOF GLOSS
Product Name:
Recommended Use: Floor coating. Applied by brush, roller or pad.
Supplier: Orica Woodcare New Zealand
Street Address: 150 Hutt Park Road
Lower Hutt, New Zealand
Telephone Number: +64 4 576 6400
Facsimile: + 64 4 576 6496
Emergency Telephone: 0 800 734 607 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as a Dangerous Good according to NZS 5433:1999 Transport of Dangerous Goods on Land.
Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001.
Subclasses: Subclass 3.1 Category C (medium hazard) - Flammable Liquids.
Subclass 6.1 Category D - Substances which are acutely toxic.
Subclass 6.3 Category B - Substances that are mildly irritating to the skin.
Subclass 6.4 Category A - Substances that are irritating to the eye.
Subclass 6.5 Category A - Substances that are respiratory sensitisers.
Subclass 6.5 Category B - Substances that are contact sensitisers.
Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment.
Surface Coatings and Colourants (Flammable) Group Standard 2006
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components / CAS Number Proportion Risk Phrases
Isocyanate prepolymer 30-60% -
-
Solvent naphtha (petroleum), 30-60% R65
light arom.
64742-95-6
Propylene glycol monomethyl 1-<10% R10, R36
ether acetate
108-65-6
1-methoxy-2-propyl 1-<10% -
propionate
148462-57-1
Hexamethylene diisocyanate <0.15% R23 R36/37/38 R42/43
822-06-0
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor.
Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing
and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm.
Keep at rest until fully recovered. If patient finds breathing difficult and develops a bluish
discolouration of the skin (which suggests a lack of oxygen in the blood - cyanosis), ensure airways
are clear of any obstruction and have a qualified person give oxygen through a face mask. Apply
artificial respiration if patient is not breathing. Seek immediate medical advice.
Skin Contact: If skin contact occurs, remove contaminated clothing and wash skin with running water. If irritation
occurs seek medical advice.
Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a sensible
precaution to seek medical advice.
Ingestion: Immediately rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water.
Seek immediate medical assistance.
Medical attention Treat symptomatically.
and special
treatment:
5. FIRE FIGHTING MEASURES
Hazards from combustion Flammable liquid. On burning will emit toxic fumes, including those of oxides of carbon
products: and oxides of nitrogen .
Precautions for fire fighters and Keep containers cool with water spray. Fire fighters to wear self-contained breathing
special protective equipment: apparatus and suitable protective clothing if risk of exposure to vapour or products of
combustion.
Suitable Extinguishing Media: Normal foam, dry agent (carbon dioxide, dry chemical powder).
Hazchem Code: 3Y
6. ACCIDENTAL RELEASE MEASURES
Emergency procedures: If contamination of sewers or waterways has occurred advise local emergency services.
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
Methods and materials for Shut off all possible sources of ignition. Slippery when spilt. Avoid accidents, clean up
containment and clean up: immediately. Wear protective equipment to prevent skin and eye contact and breathing in
vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and
waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly
labelled containers or drums for disposal.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid skin and eye contact and breathing in vapour. May form flammable vapour
mixtures with air. All potential sources of ignition (open flames, pilot lights, furnaces,
spark producing switches and electrical equipment etc) must be eliminated both in and
near the work area. Do NOT smoke. Vapour may travel a considerable distance to
source of ignition and flash back.
Conditions for safe storage: Store in cool place and out of direct sunlight. Store away from sources of heat or
ignition. Store away from foodstuffs. Store away from incompatible materials described
in Section 10. Keep containers closed when not in use - check regularly for leaks.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:
No value assigned for this specific material by the New Zealand Occupational Safety and Health Service (OSH).
However, Workplace Exposure Standard(s) for constituent(s):
Isocyanates, all, (as -NCO): WES-TWA 0.02 mg/m3; WES-STEL 0.07 mg/m3, sen
As published by the New Zealand Occupational Safety and Health Service (OSH).
WES - TWA (Workplace Exposure Standard - Time Weighted Average) - The eight-hour, time-weighted average
exposure standard is designed to protect the worker from the effects of long-term exposure.
WES - STEL (Workplace Exposure Standard - Short Term Exposure Limits) - The 15 minute average exposure standard.
Applies to any 15 minute period in the working day and is designed to protect the worker against adverse effects of
irritation, chronic or irreversible tissue change, or narcosis that may increase the likelihood of accidents. The WES-STEL
is not an alternative to the WES-TWA; both short-term and eight-hour, time-weighted average exposures should be
determined.
`Sen' Notice - sensitiser. The substance can cause a specific immune response in some people. An affected individual
may subsequently react to exposure to minute levels of that substance.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine
dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
Engineering controls:
Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Exposure
Standards. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter confined spaces where
vapour may have collected. Keep containers closed when not in use.
Personal Protective Equipment:
The selection of PPE is dependant on a detailed risk assessment. The risk assessment should consider the work
situation, the physical form of the chemical, the handling methods, and environmental factors.
Orica Personal Protection Guide No. 1, 1998: G - OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES,
RESPIRATOR.
Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation. If inhalation risk exists wear organic
vapour respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. Always wash hands before smoking,
eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Viscous liquid
Colour: Pale Yellow
Odour: Solvent
Solubility: Insoluble in water. Soluble in organic solvents.
Specific Gravity: 0.97-0.99 @20癈
Relative Vapour Density (air=1): >1
Vapour Pressure (20 癈): N Av
Flash Point (癈): 45癈
Flammability Limits (%): 0.8-6
Autoignition Temperature (癈): N Av
% Volatile by Weight: N Av
Solubility in water (g/L): Insoluble
Melting Point/Range (癈): N App
Boiling Point/Range (癈): 155-174
pH: N App
Viscosity: N Av
Evaporation Rate: N Av
10. STABILITY AND REACTIVITY
Chemical stability: Stable under normal conditions of use.
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
Conditions to avoid: Avoid contact with foodstuffs. Avoid exposure to heat, sources of ignition, and open
flame. Avoid exposure to moisture.
Incompatible materials: Incompatible with oxidising agents.
Hazardous decomposition Isocyanates. Oxides of carbon. Oxides of nitrogen.
products:
Hazardous reactions: Reacts with moisture liberating carbon dioxide.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Ingestion: Swallowing can result in nausea, vomiting and central nervous system depression. If the victim is
showing signs of central system depression (like those of drunkeness) there is greater likelihood of the
patient breathing in vomit and causing damage to the lungs.
Eye contact: May be an eye irritant.
Skin contact: Contact with skin may result in irritation. Will have a degreasing action on the skin. Repeated or
prolonged skin contact may lead to irritant contact dermatitis. Component/s of this material can be
absorbed through the skin with resultant adverse effects.
Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways). Breathing in vapour
can result in headaches, dizziness, drowsiness, and possible nausea. Breathing in high concentrations
can produce central nervous system depression, which can lead to loss of co-ordination, impaired
judgement and if exposure is prolonged, unconsciousness. May cause respiratory sensitisation in
sensitive individuals, producing asthma-like symptoms.
Long Term Effects:
No information available for the product. For the major solvent (1) : Evidence indicates that repeated or prolonged
exposure to this chemical could result in central nervous system disorders.
Toxicological Data:
No LD50 data available for the product. The toxicity of the product may be attributed to the solvents it contains. Additive
effects may occur with mixtures of solvents. Similar effects can occur where the consumption of alcohol is also involved.
However, for constituent(s) Solvent naphtha (petroleum), light arom. (1):
Oral LD50 (rat): >2000 mg/kg
Dermal LD50 (rabbit): >2000 mg/kg
12. ECOLOGICAL INFORMATION
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
Ecotoxicity Avoid contaminating waterways.
13. DISPOSAL CONSIDERATIONS
Disposal methods: Refer to Waste Management Authority. Advise flammable nature. Dispose of material
through a licensed waste contractor. Normally suitable for incineration by an approved
agent.
14. TRANSPORT INFORMATION
Road and Rail Transport
Classified as a Dangerous Good according to NZS 5433:1999 Transport of Dangerous Goods on Land.
UN No: 1263
Class-primary 3 Flammable Liquid
Packing Group: III
Proper Shipping Name: PAINT
Hazchem Code: 3Y
Marine Transport
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for
transport by sea; DANGEROUS GOODS.
UN No: 1263
Class-primary: 3 Flammable Liquid
Packing Group: III
Proper Shipping Name: PAINT
Air Transport
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods
Regulations for transport by air; DANGEROUS GOODS.
UN No: 1263
Class-primary: 3 Flammable Liquid
Packing Group: III
Proper Shipping Name: PAINT
15. REGULATORY INFORMATION
Classification: Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations
2001.
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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Safety Data Sheet
Subclasses: Subclass 3.1 Category C (medium hazard) - Flammable Liquids.
Subclass 6.1 Category D - Substances which are acutely toxic.
Subclass 6.3 Category B - Substances that are mildly irritating to the skin.
Subclass 6.4 Category A - Substances that are irritating to the eye.
Subclass 6.5 Category A - Substances that are respiratory sensitisers.
Subclass 6.5 Category B - Substances that are contact sensitisers.
Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment.
Surface Coatings and Colourants (Flammable) Group Standard 2006
16. OTHER INFORMATION
(1) Supplier Material Safety Data Sheet; 12/ 2003.
This material safety data sheet has been prepared by SH&E Shared Services, Orica.
Reason(s) for Issue:
Format change
Change in Formulation
Alignment to HSNO requirements
This MSDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the
material and general guidance on how to safely handle the material in the workplace. Since Orica Limited cannot
anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and
control the risks arising from its use of the material.
If clarification or further information is needed, the user should contact their Orica representative or Orica Limited at the
contact details on page 1.
Orica Limited's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is
available upon request.
Product Name: 552-97143 INTERGRAIN MAXIPROOF GLOSS
Substance No: 000000010817 Issued: 23/06/2006 Version: 2
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