MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
MATERIAL SAFETY DATA SHEET
Acryloyl Chloride, Stabilized with 0.1% Phenothiazine, 98%
96666
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: Acryloyl Chloride, Stabilized with 0.1% Phenothiazine, 98%
Acrylic Acid Chloride, Propenoyl Chloride.
Company Identification: Acros Organics N.V.
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 92-84-2 |Phenothiazine | 0.1% | 202-196-5 |
|----------------|--------------------------------------|----------|-----------|
| 814-68-6 |Acryloyl chloride | 98 | 212-399-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Appearance: clear, colorless. Flash Point: 16 deg C.
Danger! Flammable liquid. Corrosive. Moisture sensitive. Causes eye
and skin burns. Causes digestive and respiratory tract burns.
Target Organs: None.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Vapors may cause
dizziness or suffocation.
Chronic:
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MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately. Do NOT allow victim to rub or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Do NOT induce vomiting. Allow the victim
to rinse his mouth and then to drink 2-4 cupfuls of water, and seek
medical advice.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable Liquid.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Do NOT use water directly on fire. Use water
spray to cool fire-exposed containers. Do NOT use straight streams of
water.
Autoignition Temperature: Not available.
Flash Point: 16 deg C ( 60.80 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower: N/A
Upper: N/A
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove
all sources of ignition. Use a spark-proof tool. A vapor suppressing
foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Avoid contact with heat, sparks and flame. Do not ingest or
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MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Flammables-area. Refrigerator (approx
4狢).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
+--------------------+-------------------+-------------------+-----------------+
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|--------------------|-------------------|-------------------|-----------------|
| Phenothiazine |5 mg/m3; skin - |5 mg/m3 TWA |none listed |
| |potential for | | |
| |cutaneous | | |
| |absorption | | |
|--------------------|-------------------|-------------------|-----------------|
| Acryloyl chloride |none listed |none listed |none listed |
+--------------------+-------------------+-------------------+-----------------+
OSHA Vacated PELs:
Phenothiazine:
5 mg/m3 TWA
Acryloyl chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ?910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use. Wear a
NIOSH/MSHA or European Standard EN 149 approved
full-facepiece airline respirator in the positive
pressure mode with emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear, colorless
Odor: None reported
pH: Not available.
Vapor Pressure: Not available.
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MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 76 deg C
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: 1.1136 @ 20C
Molecular Formula: C3H3ClO
Molecular Weight: 90.4734
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, hydrogen fluoride.
Hazardous Polymerization:
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 92-84-2: SN5075000
CAS# 814-68-6: AT7350000
LD50/LC50:
CAS# 92-84-2: Oral, mouse: LD50 = 5 gm/kg; Oral, rabbit: LD50 = 4
gm/kg.
CAS# 814-68-6: Inhalation, mouse: LC50 =92 mg/m3/2H.
Carcinogenicity:
Phenothiazine -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acryloyl chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Neurotoxicity:
No information available.
Mutagenicity:
No information available.
Other Studies:
No data available.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Not available.
Environmental Fate:
Not available.
Physical/Chemical:
Not available.
Other:
Not available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
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MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
Dispose of in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants:
None listed.
RCRA D-Series Chronic Toxicity Reference Levels: None
listed.
RCRA F-Series: None listed.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Not listed as a material banned from land disposal
according to RCRA.
**** SECTION 14 - TRANSPORT INFORMATION ****
US DOT
Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
(ACRYLOYL CHLORIDE)
Hazard Class: 3
UN Number: UN2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.2
UN Number: 2924
Packing Group: II
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Dangerous Goods Code: 3(26B)
UN Number: 2924
Canadian TDG
Shipping Name: FLAMMABLE LIQUID CORROSIVE NOS (ACRYLOYL CHLORIDE)
Hazard Class: 3(8)
UN Number: UN2924
Other Information: FP 16 C
**** SECTION 15 - REGULATORY INFORMATION ****
US FEDERAL
TSCA
CAS# 92-84-2 is listed on the TSCA inventory.
CAS# 814-68-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 92-84-2: Effective Date: June 1, 1987; Sunset Date: June 1, 1997
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
CAS# 814-68-6: TPQ = 100 pounds; RQ = 100 pounds (revised TPQ based on
new or re-evaluated toxi city data)
SARA Codes
CAS # 92-84-2: acute, chronic.
Section 313
No chemicals are reportable under Section 313.
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MATERIAL SAFETY DATA SHEET http://www.fisher1.com/fb/itv?16..f97.1.msa0001.287..1.9.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
CAS# 814-68-6 is considered highly hazardous by OSHA.
STATE
Phenothiazine can be found on the following state right to know
lists: California, New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
Acryloyl chloride can be found on the following state right to know
lists: New Jersey, Florida, Pennsylvania, Massachusetts.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 30 Never add water to this product.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident of if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 92-84-2: 2
CAS# 814-68-6: 2
Canada
CAS# 92-84-2 is listed on Canada's DSL/NDSL List.
This product does not have a WHMIS classification.
CAS# 92-84-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 814-68-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 92-84-2:. OEL-AUSTRALIA:TWA 5 mg/m3;Skin. OEL-BELGIUM:TWA 5 mg/m
3;Skin. OEL-DENMARK:TWA 5 mg/m3;Skin. OEL-FINLAND:TWA 5 mg/m3;STEL 10
mg/m3;Skin. OEL-FRANCE:TWA 5 mg/m3;Skin. OEL-THE NETHERLANDS:TWA 5 mg/
m3;Skin. OEL-THE PHILIPPINES:TWA 5 mg/m3;Skin. OEL-SWITZERLAND:TWA 5 m
g/m3;Skin. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. O
EL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 814-68-6:. OEL-RUSSIA:STEL 0.3 mg/m3;Skin
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/01/1996 Revision #3 Date: 12/19/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
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for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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