IsleChem, LLC
MATERIAL SAFETY DATA SHEET
MSDS NUMBER: M104
MSDS DATE: 09/09/08
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
24 HOUR EMERGENCY PHONE: 1-800-424-9300
I. PRODUCT IDENTIFICATION
HMIS HAZARD RATINGS
HEALTH HAZARD 3 FIRE HAZARD 1 REACTIVITY 1
Based on the National Paint & Coatings Association HMIS rating system.
SARA/TITLE III HAZARD CATEGORIES (See Section X)
Immediate (ACUTE) Health: YES Reactive Hazard: NO
Delayed (Chronic) Health: NO Sudden Release of Pressure: NO
Fire Hazard: NO
MANUFACTURER'S : IsleChem, LLC
NAME AND : 2801 Long Road TELEPHONE: (716) 773-8100
ADDRESS : Grand Island, NY 14072
CHEMICAL NAME: Dimethyl acid pyrophosphate CAS NUMBER: 26644-00-8
SYNONYMS/COMMON NAMES: Pyrophosphoric acid, dimethyl ester
CHEMICAL FORMULA: C2H8O7P2
PRODUCT USE: Industrial chemical
DOT PROPER SHIPPING NAME: Corrosive Liquid Acidic Organic NOS (Dimethyl acid
pyrophosphate)
DOT HAZARD CLASS: 8
DOT IDENTIFICATION NUMBER: UN 3265
DOT PACKING GROUP: II
DOT HAZARDOUS SUBSTANCE: Not applicable
DOT MARINE POLLUTANT: Not applicable
ADDITIONAL DESCRIPTION REQUIREMENT: Not applicable
C AS = C hemical A bstract Serv ice Number ND = No relev ant information found or not av ailable
PEL = OSHA Permissible Exposur e Limit C ORP = C orporate Exposure Limit
TLV = A CGIH Threshold Limit Value, C urrent * = See C hronic Effects Information NA = Not applicab le
IMPORTA NT: The information presented herein, while not guaran teed, was prepared by competent technical p ersonnel and is true and accurate to the b est of our k nowledge. NO WA RRA NTY, EXPRESS OR IMPLIED IS MA DE REGA RDING
PERFORMA NC E, STA BILITY, OR OTHERWISE. This information is not intended to be all-inclusiv e as to th e manner and conditions of u se, handling and storage. Other factors may inv olv e other or additional safety or performance
considerations. While our technical p ersonnel will be happy to respond to question s reg arding safe handling use procedures, safe handling and u se remain s the responsibility of the custo mer. No suggestions for use are intended as, and
nothing herein shall be construed as a recommendation to infringe any existing patents or v iolate any Federal, State or local law s.
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
II. HEALTH HAZARD INFORMATION
EMERGENCY AND FIRST AID PROCEDURES
EYES:
OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION. IMMEDIATELY
flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure complete
irrigation of all eye and lid tissue. Washing eyes within one (1) minute is essential to achieve maximum
effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
SEEK MEDICAL ATTENTION IMMEDIATELY. Flush thoroughly with cool water under shower while removing
contaminated clothing and shoes. CONTINUE TO FLUSH UNTIL MEDICAL ATTENTION ARRIVES. Discard
non-rubber shoes. Wash clothing before reuse.
INHALATION:
Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops,
administer artificial resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING. This material is not soluble. DO NOT GIVE FLUIDS. If spontaneous vomiting
is inevitable, PREVENT ASPIRATION by keeping the victims head below the knees. GET IMMEDIATE
MEDICAL ATTENTION. A qualified physician can perform gastric lavage only when the airway (trachea) has
been secured to prevent aspiration.
ROUTES OF EXPOSURE
INHALATION:
Inhalation of vapors, mist or liquid may cause irritation to the mucous membranes of the nose and throat
and can produce serious chemical burns.
SKIN:
Exposure to vapor, mist or liquid may irritate skin and can produce serious burns.
EYE CONTACT:
May irritate eyes and can produce chemical burns.
INGESTION:
Can cause irritation and burning of the mouth, throat and gastrointestinal tract.
EFFECTS OF OVEREXPOSURE
ACUTE:
Irritating and corrosive to the eyes, skin, respiratory and digestive tracts.
CHRONIC:
No known chronic effects.
TOXICOLOGY DATA:
Acute Oral LD50 (rat) > 2.71 g/kg.
SYNERGISTIC MATERIALS: Not Applicable.
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
III. IMPORTANT COMPONENTS
CAS NUMBER / NAME
26644-00-8 Pyrophosphoric acid, p,p' dimethyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not established VOL
TLV: Not established WT 40-60
COMMON NAMES:
Dimethyl acid pyrophosphate
Listed On (List Legend Below):
00 22 76
CAS NUMBER / NAME
56399-35-0 Pyrophosphoric acid, monomethyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not established VOL
TLV: Not established WT 5-20
COMMON NAMES:
Monomethyl acid phopshate
Listed On (List Legend Below):
00 22
CAS NUMBER / NAME
812-00-0 Phosphoric acid, monomethyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not established VOL
TLV: Not established WT 10-15
COMMON NAMES:
Monomethyl phosphate
Listed On (List Legend Below):
00 19 22 23 51
813-78-5 Phosphoric acid, dimethyl ester
EXPOSURE LIMITS PERCENTAGE
PEL: Not Established VOL
TLV: Not Established WT 5-15
COMMON NAMES:
Dimethyl phosphate
Listed On (List Legend Below):
00 19 23 36 51
IsleChem
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
7664-38-2 Phosphoric acid
EXPOSURE LIMITS PERCENTAGE
PEL: 1 mg/m3, TWA VOL
STEL 3 mg/m3 WT 1-4
TLV: 1 mg/m3, TWA
STEL 3 mg/m3
COMMON NAMES:
Orthophosphoric acid
Listed On (List Legend Below):
00 03 12 13 21 22 24 50 51 56 57 58 60 62 64 70 71 72 75 76 77
All components of this product that are required to be on the TSCA Inventory are listed on the inventory.
Not listed as carcinogen - IARC, NTP, OSHA
LIST LEGEND
00 TSCA INVENTORY 56 OSHA PERMISSIBLE EXPOSURE LIM
03 HAS A CERCLA REPORTABLE QTY 57 ACGIH THRESHOLD LIMIT VALUES
12 PA HAZARDOUS SUBSTANCE 58 MASSACHUSETTS RIGHT TO KNOW
13 PA ENVIRONMENTAL HAZ SUBSTANCE 60 CLEAN WATER ACT, SEC 311
19 PA REQUIREMENT 23% 62 WHMIS
21 NJ SPECIAL HEALTH HAZ SUB 64 NIOSH RECOMMENDED EXPOS LIMITS
22 CANADIAN DOMESTIC SUB LIST 70 EUR AGRMT - CARRIAG DANG GOODS
NJ REQUIREMENT 1%
23 71 REGS - CARRIAGE OF GOODS/RAIL
24 NJ DISCHARGE OF HAZ SUBSTANCES 72 ANNEX I
36 CANADIAN NDSL 75 AUSTRALIAN INVENTORY (AICS)
50 PHILIPPINES INVENTORY (PICCS) 76 JAPANESE CHEMICAL INVENTORY
51 EINECS 77 KOREAN EXIST. CHEMICALS (ECL)
IV. FIRE AND EXPLOSION DATA
FLASH POINT: (COC) 204o C (399oF) AUTOIGNITION TEMPERATURE: Not Applicable
FLAMMABLE LIMITS IN AIR, % BY VOLUME - UPPER: Not Applicable
LOWER: Not Applicable
EXTINGUISHING MEDIA:
Use dry chemical, foam, carbon dioxide or water spray.
SPECIAL FIRE FIGHTING PROCEDURES:
In fire conditions wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus and full
protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARD:
Under fire conditions, will liberate toxic and corrosive oxides of phosphorus.
SENSITIVITY TO MECHANICAL IMPACT:
Not Available.
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
SENSITIVITY TO STATIC DISCHARGE:
Not Available.
V. SPECIAL PROTECTION
VENTILATION REQUIREMENTS:
Provide good general room ventilation plus local exhaust at points of emission.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY:
NIOSH/MSHA approved respirator, following manufacturer's recommendations, should be used as a
precautionary measure where airborne contaminants may occur.
EYE:
Wear chemical safety goggles plus full face shield to protect against splashing when appropriate.
GLOVES:
Wear chemical resistant gloves such as neoprene, rubber or vinyl.
OTHER CLOTHING AND EQUIPMENT:
Eyewash facility and emergency shower should be in close proximity. Impervious clothing and rubber boots
should be worn for splash protection.
VI. PHYSICAL DATA
NA; decomposition starts at 124oC (225oF)
BOILING POINT @ 760 mm Hg:
-60oF
POUR POINT:
No Data
VAPOR PRESSURE:
1.5
SPECIFIC GRAVITY (H2O=1):
Insoluble
SOLUBILITY IN H2O % BY WT:
No Data
VAPOR DENSITY (Air=1):
Clear, colorless liquid
APPEARANCE AND ODOR:
No Data
ODOR THRESHOLD (ppm):
No data
pH:
13 lb/gal
DENSITY:
No Data
EVAPORATION RATE:
COEFFICIENT WATER/OIL DISTRIBUTION: No Data
IsleChem
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
VII. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY:
Avoid exposure to heat or to most metals or plastics, especially at elevated temperatures. Thermal
degradation occurs above 255oF.
VII. REACTIVITY DATA (Continued)
INCOMPATIBILITY:
Reacts with alkalies producing heat. Reacts with many metals liberating flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal degradation occurs above 255oF, producing oxides of phosphorus.
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:
Material is not known to polymerize.
VIII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS:
Store away from heat and separate from alkalies, aluminum, zinc and other metals. Protect from
atmospheric moisture. Storage areas for drummed material should have adequate drainage. Storage tanks
should be vented and diked.
IX. ENVIRONMENTAL PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Soak up with vermiculite, sand, earth or other absorbent material and place in marked lined steel container
for disposal. Neutralize with soda ash. Flush spill area with large quantities of water.
WASTE DISPOSAL METHOD:
Product should be completely removed from container. Material that cannot be used or chemically
reprocessed should be disposed of in accordance with all local, state and federal regulations. Incinerate in
equipment designed to handle oxides of phosphorus as combustion products or send to a waste disposal
firm. Empty containers should be disposed of in a manner meeting government regulations.
X. ADDITIONAL INFORMATION
OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the
hazards of chemicals by means of a hazard communication program including labeling, material safety data
sheets, training and access to written records. We request that you, and it is your legal duty to, make all
information in this Material Safety Data Sheet available to your employees.
IsleChem
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
To aid our customers in complying with regulatory requirements, SARA Title III hazard categories for this
product are indicated in Section I. If the word "YES" appears next to any category, this product may be
reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details.
This product contains a toxic chemical or chemicals subject to the reporting requirements of SECTION 313
of TITLE III of the SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 and 40 CFR PART
372. (See Section III, List Legend 02).
XI. PREPARATION INFORMATION
For additional Non-Emergency health, safety or environmental information telephone (716) 773-8438, or
write to:
IsleChem, LLC
2801 Long Road
Grand Island, NY 14072
For Emergencies: 24 HOUR EMERGENCY PHONE: 1-800-424-9300
To request an MSDS: 716-773-8438
WARNING LABEL INFORMATION
SIGNAL WORD: DANGER
STATEMENT OF HAZARDS:
LIQUID CORROSIVE
CAUSES IRRITATION OR BURNS TO THE SKIN, EYES, RESPIRATORY AND DIGESTIVE TRACTS.
PRECAUTIONARY STATEMENTS:
Keep container closed.
Insure adequate ventilation or use an approved respirator.
Avoid breathing vapor.
Do not get in eyes, on skin, on clothing.
Wash thoroughly after handling.
Use goggles, impervious clothing and rubber shoes.
Reacts with aluminum, zinc, and other metals liberating flammable hydrogen gas.
FIRST AID:
FOR EYES:
OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION.
IMMEDIATELY flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart
to ensure complete irrigation of all eye and lid tissue. Washing eyes within one (1) minute is essential
to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.
IsleChem
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
FOR SKIN:
SEEK MEDICAL ATTENTION IMMEDIATELY. Flush thoroughly with cool water under shower while
removing contaminated clothing and shoes. CONTINUE TO FLUSH UNTIL MEDICAL ATTENTION
ARRIVES. Discard non-rubber shoes. Wash clothing before reuse.
IF INHALED:
Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration
stops, give mouth-to-mouth resuscitation. GET MEDICAL ATTENTION IMMEDIATELY.
IF SWALLOWED:
DO NOT INDUCE VOMITING. This material is not soluble. DO NOT GIVE FLUIDS. If spontaneous
vomiting is inevitable, PREVENT ASPIRATION by keeping the victims head below the knees. GET
IMMEDIATE MEDICAL ATTENTION. A qualified physician can perform gastric lavage only when the
airway (trachea) has been secured to prevent aspiration.
IN CASE OF:
SPILL OR LEAK:
Soak up with vermiculite, sand, earth or other absorbent material and place in marked metal container for
disposal. Neutralize with soda ash. Flush spill area with large quantities of water.
FIRE:
Use dry chemical, foam, carbon dioxide or water spray. Use air supplied respirator and full protection
equipment. Fire will liberate toxic gases.
HANDLING AND STORAGE:
Store in a cool, dry place separate from alkalies, aluminum, zinc and other metals.
DISPOSAL:
Product should be completely removed from container. Material that cannot be used or chemically
reprocessed should be disposed of in accordance with all local, state and federal regulations. Incinerate in
equipment designed to handle oxides of phosphorus as combustion products or send to a waste disposal
firm. Empty containers should also be disposed of in a manner meeting government regulations.
INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS:
This product contains:
CAS# NAME
26644-00-8 Pyrophosphoric acid, p,p' dimethyl ester
56399-35-0 Pyrophosphoric acid, monomethyl ester
812-00-0 Phosphoric acid, monomethyl ester
813-78-5 Phosphoric acid, dimethyl ester
7664382 Phosphoric acid
IsleChem
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MSDS NUMBER: M104
PRODUCT NAME: DIMETHYL ACID PYROPHOSPHATE
HMIS RATING SYSTEM: HEALTH 3 FLAMMABILITY 1 REACTIVITY 1
FOR INDUSTRIAL USE ONLY
For additional information, see Material Safety Data Sheet (MSDS) for this product.
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