Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1
Page 1 of 7
SDS no. : 153595
V002.0
3106 Adhesive
Revision: 14.03.2008
printing date: 06.12.2008
1. Identification of the substance/preparation and of the company/undertaking
Trade name:
3106 Adhesive
Intended use:
Ultraviolet adhesive
Company name:
Henkel Limited
Technologies House
Wood Lane End
HP2 4RQ Hemel Hempstead
Great Britain
Phone: +44 (0)1442 278000
Fax-no.: +44 (0)1442 278071
E-mail address of person responsible for Safety Data Sheet:
ua-productsafety.uk@uk.henkel.com
Emergency information:
24 Hours Emergency Tel: +44(0)8701906777
2. Hazards identification
Care should be taken during the cure of these products by UV radiation to avoid exposure of the skin and especially of the eyes to
direct or reflected UV radiation as longterm effects could be harmful.
R20/21 Harmful by inhalation and in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R68 Possible risk of irreversible effects.
3. Composition / information on ingredients
Declaration of ingredients according to EC/1907/2006:
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Hazardous components EINECS content Classification
CAS-No. ELINCS
Isobornyl acrylate 227-561-6 30 - 40 % Xi - Irritant; R36/37/38
5888-33-5 N - Dangerous for the environment; R51, R53
2-Propenamide, N,N-dimethyl- 220-237-5 10 - 20 % T - Toxic; R21/22, R23
2680-03-7
Ethanone, 2,2-dimethoxy-1,2-diphenyl- 246-386-6 1- 5% N - Dangerous for the environment; R50/53
24650-42-8
Diphenyl-2,4,6-trimethylbenzoyl 278-355-8 1-< 5 % N - Dangerous for the environment; R51/53
phosphine oxide Toxic for reproduction - category 3.; Xn - Harmful;
75980-60-8 R62
2-Hydroxyethyl acrylate 212-454-9 0,1 - < 0,2 % T - Toxic; R24
818-61-1 C - Corrosive; R34
R43
N - Dangerous for the environment; R50
[3-(2,3- 219-784-2 1- 3% Xn - Harmful; R22, R68
Epoxypropoxy)propyl]trimethoxysilane Xi - Irritant; R36
2530-83-8
For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.
4. First aid measures
Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.
Consideration should be given to the possible effects of a faulty UV source (Stray radiation, ozone).
Skin contact:
Rinse with running water and soap.
In case of adverse health effects seek medical advice.
Eye contact:
Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary.
Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.
5. Fire fighting measures
Suitable extinguishing media:
carbon dioxide, foam, powder
Special protection equipment for firefighters:
Wear self-contained breathing apparatus.
Wear protective equipment.
Hazardous combustion products:
Oxides of carbon, oxides of nitrogen, irritating organic vapors.
6. Accidental release measures
Personal precautions:
Avoid skin and eye contact.
Ensure adequate ventilation.
Wear protective equipment.
Environmental precautions:
Do not let product enter drains.
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Clean-up methods:
For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for disposal.
Wash spillage site thoroughly with soap and water or detergent solution.
7. Handling and storage
Handling:
Ventilation will remove any ozone that may be produced by the ultra violet lamp
Avoid skin and eye contact.
Storage:
Store in original containers at 8-21癈 (46.4-69.8癋) and do not return residual materials to containers as contamination may
reduce the shelf life of the bulk product.
8. Exposure controls / personal protection
Engineering controls:
UV lamp should be designed, installed and operated in such a way as to eliminate exposure of the skin and eyes to stray
radiation
Respiratory protection:
Use only in well-ventilated areas.
Ensure adequate ventilation.
Hand protection:
Avoid skin-contact.
The use of chemical resistant gloves such as Nitrile are recommended
Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many
influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and
tear are noticed then the gloves should be replaced.
Eye protection:
Tightly fitting safety goggles
General protection and hygiene measures:
Good industrial hygiene practices should be observed
9. Physical and chemical properties
General characteristics:
Appearance liquid
Clear
Odor: Mild
Phys./chem. properties:
Flash point 77,8 癈 (172.04 癋)
Vapor pressure < 6,6600000 mbar
(20 癈 (68 癋))
Density 1,078 g/cm3
()
Solubility (qualitative) Slight
(Solvent: Water)
VOC content < 3,00 % (As defined in the Council Directive 2004/42/EC)
(1999/13/EC)
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10. Stability and reactivity
Conditions to avoid:
Protect from direct sunlight.
Avoid contact with acids and oxidizing agents.
Materials to avoid:
Reaction with strong bases
Reaction with strong acids.
Hazardous decomposition products:
Sulphur oxides
nitrogen oxides
Irritating organic vapours
Dimethylamine.
carbon oxides
11. Toxicological information
General toxicological information:
Possible risk of irreversible effects.
Oral toxicity:
May cause irritation to the digestive tract.
Ingestion of large quantities may cause liver or kidney damage.
Inhalative toxicity:
Harmful by inhalation.
Irritating to respiratory system
Dermal toxicity:
Harmful in contact with skin.
Skin irritation:
Irritating to the skin
Eye irritation:
Irritating to eyes.
12. Ecological information
Mobility:
Cured adhesives are immobile.
General ecological information:
Toxic to aquatic organisms
May cause long-term adverse effects in the aquatic environment.
13. Disposal considerations
Product disposal:
Dispose of in accordance with local and national regulations.
Waste code(EWC ):
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances
Disposal of uncleaned packages:
Dispose of in authorised landfill site or incinerate.
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14. Transport information
Road transport ADR:
Class: 9
Packaging group: III
Classification code: M6
Hazard ident. number: 90
UN no.: 3082
Label: 9
Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (2,2-Dimethoxy-1,2-diphenylethan-1-one,Isobornyl acrylate)
Railroad transport RID:
Class: 9
Packaging group: III
Classification code: M6
Hazard ident. number: 90
UN no.: 3082
Label: 9
Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (2,2-Dimethoxy-1,2-diphenylethan-1-one,Isobornyl acrylate)
Inland water transport ADN:
Class: 9
Packaging group: III
Classification code: M6
Hazard ident. number:
UN no.: 3082
Label: 9
Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (2,2-Dimethoxy-1,2-diphenylethan-1-one,Isobornyl acrylate)
Marine transport IMDG:
Class: 9
Packaging group: III
UN no.: 3082
Label: 9
EmS: F-A ,S-F
Seawater pollutant: -
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (2,2-Dimethoxy-1,2-diphenylethan-1-one,Isobornyl acrylate)
Air transport IATA:
Class: 9
Packaging group: III
Packaging instructions (passenger) 914
Packaging instructions (cargo) 914
UN no.: 3082
Label: 9
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (2,2-Dimethoxy-
1,2-diphenylethan-1-one,Isobornyl acrylate)
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15. Regulations - classification and identification
Indication of danger:
Xn - Harmful N - Dangerous for the
environment
Contains
2-Propenamide, N,N-dimethyl-,
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane
Risk phrases:
R20/21 Harmful by inhalation and in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R68 Possible risk of irreversible effects.
Safety phrases:
S23 Do not breathe vapour.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of water and soap.
S37 Wear suitable gloves.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
Contains 2-Hydroxyethyl acrylate. May produce an allergic reaction.
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16. Other information
The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet
are as follows:
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R34 Causes burns.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51 Toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
R68 Possible risk of irreversible effects.
Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.
This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and
Commission Directive 1999/45/EC.
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