Material Safety Data Sheet
Sodium sulfate anhydrous
ACC# 21630
Section 1 - Chemical Product and Company Identification
MSDS Name: Sodium sulfate anhydrous
Catalog Numbers: AC196640000, AC196640010, AC196640025, AC196640050,
AC196640250, AC196640251, AC218750000, AC218750250, AC219260000, AC219260010,
AC219260025, AC325600000, AC354250000, AC424410000, AC424410030, AC424410050,
21875-5000, 35425-0010, 42441-0010, BP354-500, NC9084721, NC9130094, NC9146518,
NC9260017, NC9327716, NC9369056, S415-1, S415-10, S415-10S, S415-200LB, S415-
212, S415-500, S415500LC, S415J500, S420-10, S420-3, S421-1, S421-10, S421-3, S421-
300LB, S421-50, S421-500, S42110LC, S42150LC, S429-12, S429-212, S429-250LB,
S429-500, S43112, S434-12, S78859-4
Synonyms: Bisodium sulfate; Dibasic sodium sulfate; Disodium monosulfate; Disodium
sulfate; Sodium sulphate; Sulfuric acid, disodium salt.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
7757-82-6 Sodium sulfate 99 231-820-9
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: white powder.
Caution! May cause eye, skin, and respiratory tract irritation. Hygroscopic (absorbs
moisture from the air). The toxicological properties of this material have not been fully
investigated.
Target Organs: No data found.
Potential Health Effects
Eye: May cause eye irritation. Causes redness and pain.
Skin: May cause skin irritation. May cause an allergic reaction in certain individuals.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be
harmful if swallowed.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: No information found.
Section 4 - First Aid Measures
Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15
minutes. Get medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and
shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a
fire, irritating and highly toxic gases may be generated by thermal decomposition or
combustion. Substance is noncombustible.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 1
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.
Clean up spills immediately, observing precautions in the Protective Equipment section.
Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing.
Storage: Store in a cool, dry place. Store protected from moisture.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with
an eyewash facility and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium sulfate none listed none listed none listed
OSHA Vacated PELs: Sodium sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and
ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever
workplace conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
Physical State: Powder
Appearance: white
Odor: odorless
pH: 5-8 (5% solution)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1700 deg C
Freezing/Melting Point:880 - 888 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:2.68 g/cm3
Molecular Formula:Na2SO4
Molecular Weight:142.04
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal storage
and handling conditions. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid: Dust generation, moisture, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, strong acids,
aluminum, magnesium.
Hazardous Decomposition Products: Oxides of sulfur, sodium oxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
RTECS#:
CAS# 7757-82-6: WE1650000
LD50/LC50:
CAS# 7757-82-6:
Oral, mouse: LD50 = 5989 mg/kg;
.
Carcinogenicity:
CAS# 7757-82-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No data available.
Teratogenicity: Oral, mouse: TDLo = 14 gm/kg (female 8-12 day(s) after conception)
Effects on Newborn - other neonatal measures or effects.; Parenteral, mouse: TDLo = 60
mg/kg (female 8 day(s) after conception) Effects on Embryo or Fetus - fetotoxicity (except
death, e.g., stunted fetus) and Specific Developmental Abnormalities - musculoskeletal
system.
Reproductive Effects: No information found
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information found
Other Studies:
Section 12 - Ecological Information
Ecotoxicity: Fish: Bluegill/Sunfish: LC50 = 12,750 ppm; 96 Hr; Static bioassayWater flea
Daphnia: LC50 = 4547 mg/L; 96 Hr; UnspecifiedFish: Fathead Minnow: LC50 = 13,500-
14,000 mg/L; 24 - 96 Hr; UnspecifiedFish: Mosquito Fish: LC50 = 17,500 mg/L; 96 Hr;
Unspecified This chemical is not expected to cause oxygen depletion in aquatic systems. It
has a low potential to affect aquatic organisms and is expected to have a low potential to
affect secondary waste treatment microorganisms.
Environmental: Sodium sulfate may persist indefinitely in the environment, but is not
likely to show bioaccumulation or food chain contamination effects. If diluted with water,
this chemical released directly or indirectly into the environment is not expected to have a
significant impact.
Physical: No information available.
Other: This chemical is not likely to bioconcentrate.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local hazardous waste
regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT Canada TDG
Shipping Name: Not regulated Not Regulated
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7757-82-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the
CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7757-82-6 can be found on the following state right to know lists: Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7757-82-6: 0
Canada - DSL/NDSL
CAS# 7757-82-6 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of Not controlled..
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all of the information required by those
regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
MSDS Creation Date: 7/15/1999
Revision #8 Date: 2/15/2008
The information above is believed to be accurate and represents the best information currently available to us. However,
we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and
we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if
Fisher has been advised of the possibility of such damages.
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