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The Procter & Gamble Company
P & G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
CT#FH/H/2007/MOMJ-6YNMUS Issue Date: 07/12/07
FH/H/2005/LHLA-6HAMFT
FH/H/2005/LHLA-6C3HLV(S)
FH/H/2005/LHLA-6C9JGL
FH/H/2004/MSMM-63XHAH
SECTION I - CHEMICAL PRODUCT
Identity: Instant Stain Remover
Brands: Tide To Go StainPen
Emergency Telephone Number: 24 hour P&G Operator: 1-800-879-8433 or local Poison Control Center.
This MSDS applies to all uses/handling of this product in a retail package for consumer home use.
SECTION II - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: Low order of toxicity.
Eye Contact: May cause slight irritation.
Skin: May cause slight irritation following prolonged skin contact.
Inhalation: Low order of toxicity.
Signs and Symptoms of Exposure:
Ingestion: If ingested, it may cause slight gastrointestinal irritation. May be emetic due to Hydrogen
Peroxide content.
Eye Contact: Eye contact may result in transient stinging and/or slight irritation.
Skin: Prolonged exposure my cause slight irritation and temporary whitening of skin. Contact with
irritated or damaged skin may aggravate existing conditions.
Inhalation: None.
TIDE TO GO StainPen MSDS (continued) Page 2 of 5
SECTION III - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Contains biodegradable cleaning agents.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Chemical Name Common CAS No. Recommended Limits Composition LD50/LC50
Name Range
ACGIH TWA: 1880 mg/m3
Ethyl alcohol Ethanol 64-17-5 0.5 ?1.5% 7.06 g/kg
OSHA PEL & TWA: 1900 mg/m3 (oral, rat)
7722-84-1 ACGIH TWA: 1.4 mg/m3
Hydrogen 1 ?5% N/A
Hydrogen
Peroxide OSHA PEL/TWA: 1.4 mg/m3
Peroxide
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Drink a glassful of water.
Eye contact: In case of accidental eye contact, flush thoroughly with water.
Skin: For skin irritation, rinse exposed area with water.
Inhalation: Move to an open area away from the site of exposure.
If symptoms persist or reoccur, seek medical attention.
Other: N/A
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): > 170 F Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: N/A
Special Fire Fighting Procedures:. N/A
Unusual Fire Hazards: N/A
Conditions to Avoid: Temperatures >100CF (43CC)
Stability Unstable:
Stable: X
Incompatibility (Materials to Avoid): transition metals
Hazardous Decomposition/By Products: None known
Conditions to Avoid: None known.
Hazardous Polymerization: May Occur:
Will Not Occur: X
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE AND LOCAL REGULATIONS. Small or household quantities may be disposed of in refuse or in sewer.
First check with your local water treatment plant. For larger quantities, incineration is preferred. Do not landfill.
Steps To Be Taken in Case Material is Released or Spilled: Use water spray to dilute and/or wash away spills.
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TIDE TO GO StainPen MSDS (continued) Page 3 of 5
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store in a cool, dry place.
Other Precautions: None
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type):
Ventilation Local Exhaust: None required with normal use. Special: None
Mechanical (General): Acceptable Other: None
Eye Protection: None required with normal consumer use.
Industrial Setting: If a splash is likely, chemical goggles may be needed.
Protective Gloves: None required with normal consumer use.
Industrial Setting: Protective gloves may be used to prevent temporary skin whitening that may result from skin
contact with the Tide To Go solution.
Other Protective Equipment: None required with normal use.
SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling point 癋: ~200 F | Specific Gravity (H2O=1): 1.0055
Vapor Pr. (mm Hg): unknown | Percent Volatile by Volume (%): ~99.5
pH: 4.2 ?4.6 | Evaporation Rate (nBuOAc=1): unknown
Solubility in Water: complete | Appearance: Clear
Vapor Dens.(Air=1): unknown | Odor: Product contains fragrance.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: Open flame, high temperature (>90F), prolonged exposure to UV light
Materials to Avoid: Dust, prolonged contact with metallic or organic materials
Hazardous Decomposition Products: None known
Other Recommendations: None
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TIDE TO GO StainPen MSDS (continued) Page 4 of 5
SECTION XI - TOXICOLOGICAL INFORMATION
Tide to Go has a low order of toxicity. If ingested, it may cause slight gastrointestinal irritation. Tide to Go may be
emetic due to its Hydrogen Peroxide content.
Estimated Oral LD50 > 5 g/kg
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No
IARC: No
OSHA: No
SECTION XII - ECOLOGICAL INFORMATION
Based on ecotoxicity and fate data for the individual ingredients in this specific formulation and for related
consumer household cleaning product formulations, it is expected that this product would exhibit a non-hazardous
order of toxicity at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Products covered by this MSDS, in their original form, when disposed as waste, are
considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in
accordance with all Federal, state/provincial and local regulations.
Household Use: Consumer produced household solutions may be disposed of down the drain with running water.
Consumer may discard empty container in trash, or recycle where facilities exist.
SECTION XIV - TRANSPORT INFORMATION
U.S. D.O.T.: These products are not regulated when transported by ground.
IATA: These products are not regulated when transported by air.
IMDG: These products are not regulated when transported by vessel.
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TIDE TO GO StainPen MSDS (continued) Page 5 of 5
SECTION XV - REGULATORY INFORMATION
United States
All intentionally-added components of these products are listed on the US TSCA Inventory.
EPA Registration Number: NA
SARA 313/302/304/311/312 chemicals:
Hydrogen Peroxide (CAS#7722-84-1) EPCRA (SARA Title III) Section 302: RQ= 1000 lbs
California: These products have been evaluated and do not require warning labeling under California Proposition
65.
California Hazardous Waste: Yes
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state worker
exposure lists:
Ingredient CAS # Level CERCLA State
RQ IL MA NJ PA RI
Ethanol 64-17-5 0.5? 100 lbs X X X X X
1.5%
Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in
accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS
contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION
Perfumes contained within these products covered by this MSDS comply with appropriate IFRA guidance.
P&G Hazard Rating: 1 Health: 1 4=EXTREME
Flammability: 1 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
0=NOT SIGINIFICANT
*N/A. - Not Applicable *N/K. ?Not Known
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the
use of this material. The information contained here has been compiled from sources considered by Procter &
Gamble to be dependable and is accurate to the best of the Company's knowledge. It is not meant to be an all-
inclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and
design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the
environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any
damage to any property resulting from misuse of the product.
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