MSDS Number: MI030H
View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: SOCKETLOCK CATALYST HMIS
MSDS Manufacturer MI030H
Health Hazard 3*
Number:
Manufacturer Name: ITW Polymer Technologies Fire Hazard 1
Address: 130 Commerce Drive
Montgomeryville, PA 18936 REACTIVITY 3
General Phone Number: (215) 855-8450 Personal
X
Emergency Phone Number: (215) 855-8450 Protection
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300 * Chronic Health
Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) Effects:
MSDS Revision Date: 10/10/2006
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS# Ingredient Percent
Dimethylphthalate 131-11-3 30 - 60 by weight
Methyl ethyl ketone peroxide 1338-23-4 30 - 60 by weight
Non-hazardous ingredients. N/A 1 - 5 by weight
Trade secret. N/A 10 - 30 by weight
Dipropylene glycol 25265-71-8 1 - 5 by weight
Hydrogen peroxide 7722-84-1 1 - 5 by weight
Methyl ethyl ketone 78-93-3 1 - 5 by weight
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: DANGER! Reactive. Irritant.
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye: Can cause moderate irritation, burning sensation, tearing, redness, and swelling.
Overexposure may cause lacrimation, conjunctivitis, corneal damage and
permanent injury.
Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache,
and anesthetic effects.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Kidney. Liver. Central
nervous system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
SECTION 4 - FIRST AID MEASURES
Page 1 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030H
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes.
Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes.
Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: 151癋 (66.1癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: Not determined.
Lower Flammable/Explosive Limit: Not determined.
Upper Flammable/Explosive Limit: Not determined.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH
(approved or equivalent) and full protective gear.
Unusual Fire Hazards: Organic peroxides can decompose violently if heated strongly while confined.
Sudden reaction and fire may result if product is mixed with an oxidizing agent.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a
chemical waste container. Provide ventilation. Clean up spills immediately
observing precautions in the protective equipment section. After removal, flush
spill area with soap and water to remove trace residue.
Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper
personal protective equipment as listed in section 8.
Other Precautions: Pump or shovel to storage/salvage vessels.
SECTION 7 - HANDLING and STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Storage: Store in a cool, dry, well ventilated area away from sources of heat and
incompatible materials. Keep container tightly closed when not in use. Do not
store in temperatures above 100 癋. Storage above 109癈 may cause explosive
decomposition.
Hygiene Practices: Wash thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
Page 2 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030H
contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
EXPOSURE GUIDELINES
Dimethylphthalate :
Guideline ACGIH: ACGIH TLV-TWA 5 mg/m3
Guideline OSHA: OSHA PEL-TWA 5 mg/m3
Methyl ethyl ketone peroxide :
Guideline ACGIH: ACGIH TLV-STEL 0.2 ppm Ceiling
Hydrogen peroxide :
Guideline ACGIH: ACGIH TLV-TWA 1 ppm
Guideline OSHA: OSHA PEL-TWA 1 ppm
Methyl ethyl ketone :
Guideline ACGIH: ACGIH TLV-STEL 300 ppm
Guideline OSHA: OSHA PEL-TWA 200 ppm
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance: Liquid..
Color: Red
Odor: ketone
Boiling Point: Not determined.
Melting Point: Not determined.
Specific Gravity: 1.1
Solubility: negligible
Vapor Density: Not determined.
Vapor Pressure: Not determined.
Percent Volatile: Approximately 3
Evaporation Rate: n/e
pH: Neutral
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 151癋 (66.1癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: Not determined.
VOC Content: 0.27 g/L
Percent Solids by Weight Approx. 96
SECTION 10 - STABILITY and REACTIVITY
Chemical Stability: Unstable.
Hazardous Polymerization: Not reported.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Contamination, direct sunlight, friction and prolonged
storage above 100癋 (38癈).
Incompatible Materials: Oxidizing agents. Strong acids and alkalis.
SECTION 11 - TOXICOLOGICAL INFORMATION
Dimethylphthalate :
Page 3 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030H
Eye: Eye - Rabbit Standard Draize Test. : 119 mg(RTECS)
Skin: Skin - Guinea pig LD50: >10 mL/kg - [Details of toxic effects not reported other
than lethal dose value. ](RTECS)
Skin - Rat LD50: >4800 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ](RTECS)
Skin - Rabbit LD50: >20 mL/kg - [Details of toxic effects not reported other than
lethal dose value. ](RTECS)
Inhalation: Inhalation. - Mammal cat LCLo - Lowest published lethal concentration: 9300
mg/m3/6.5H - [Details of toxic effects not reported other than lethal dose
value.] (RTECS)
Ingestion: Oral - Rat LD50: 6800 mg/kg - [oral - somnolence (general depressed activity)
oral - withdrawal Nutritional and Gross Metabolic - weight loss or decreased
weight gain ] (RTECS)
Oral - Mouse LD50: 6800 mg/kg - [oral - somnolence (general depressed
activity) oral - withdrawal Nutritional and Gross Metabolic - weight loss or
decreased weight gain ] (RTECS)
Methyl ethyl ketone peroxide :
Eye: Eye - Rabbit Standard Draize Test.: 40 %(RTECS)
Skin: Skin - Rabbit Standard Draize Test.: 500 mg(RTECS)
Skin - Rabbit TDLo: 2000 mg/kg - [Skin and Appendages - primary irritation
(after topical exposure) ](RTECS)
Inhalation: Inhalation. - Rat LC50: 3600 mg/m3/4H - [Sense Organs and Special Senses
(Eye) - conjunctive irritation Lungs, Thorax, or Respiration - cough ] (RTECS)
Inhalation. - Mouse LC50: 170 ppm/4H - [Lungs, Thorax, or Respiration -
dyspnea ] (RTECS)
Inhalation. - Mouse LC50: 2500 mg/m3/4H - [Sense Organs and Special Senses
(Eye) - conjunctive irritation Lungs, Thorax, or Respiration - cough ] (RTECS)
Ingestion: Oral - Rat LD50: 470 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Oral - Mouse LD50: 250 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Dipropylene glycol :
Skin: Skin - Rabbit LD50: >20 mL/kg - [Details of toxic effects not reported other than
lethal dose value.](RTECS)
Ingestion: Oral - Rat LD50: 14850 mg/kg - [Details of toxic effects not reported other than
lethal dose value.] (RTECS)
Hydrogen peroxide :
Eye: Eye - Rabbit Standard Draize Test. : 1 mg - [severe ](RTECS)
Skin: Skin - Rat LD50: 4060 mg/kg - [Lungs, Thorax, or Respiration - pulmonary
emboli ](RTECS)
Skin - Rabbit LDLo: 500 mg/kg - [Behavioral - convulsions or effect on seizure
threshold ](RTECS)
Skin - Mammal pig LDLo: 2 gm/kg - [Behavioral - convulsions or effect on
seizure threshold ](RTECS)
Skin - Mouse TCLo - Lowest published toxic concentration: 10 pph - [Vascular -
other changes ](RTECS)
Skin - Mouse LD50: 1072 mg/kg - [Details of toxic effects not reported other
than lethal dose value. ](RTECS)
Skin - Rat LC50 - Lethal concentration, 50 percent kill: 4060 mg/m3 - [Lungs,
Thorax, or Respiration - other changes Biochemical - Effect on specific coenzyme
- disturbed regulation ](RTECS)
Skin - Mammal species unspecified TCLo - Lowest published toxic concentration:
110 mg/m3 - [Cardiac - pulse rate increase, without fall in BP Behavioral -
tetany Lungs, Thorax, or Respiration - dyspnea ](RTECS)
Skin - Rabbit LCLo - Lowest published lethal concentration: 15 pph - [Sense
Organs and Special Senses (Eye) - lacrimation Behavioral - headache Lungs,
Thorax, or Respiration - cough ](RTECS)
Inhalation: Inhalation. - Rat LC50: 2000 mg/m3 - [Details of toxic effects not reported other
than lethal dose value.] (RTECS)
Ingestion: Oral - Rat LD50: 4050 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Oral - Mouse LD50: 2000 mg/kg - [Details of toxic effects not reported other
than lethal dose value. ] (RTECS)
Methyl ethyl ketone :
Eye: Eye - Human Standard Draize Test. : 350 ppm(RTECS)
Skin: Skin - Rabbit Open irritation test: 14 mg/24H - [mild ](RTECS)
Skin - Rabbit LD50: 6480 mg/kg - [Details of toxic effects not reported other
than lethal dose value. ](RTECS)
Inhalation: Inhalation. - Rat LC50: 23500 mg/m3/8H - [Details of toxic effects not reported
other than lethal dose value.] (RTECS)
Inhalation. - Mouse LC50: 32 gm/m3/4H - [Details of toxic effects not reported
other than lethal dose value.] (RTECS)
Ingestion: Oral - Rat LD50: 2737 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Oral - Mouse LD50: 3000 mg/kg - [Details of toxic effects not reported other
than lethal dose value. ] (RTECS)
Page 4 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030H
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number: D003
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: Organic peroxide Type D, liquid - methyl ethyl ketone peroxide, <45%
DOT UN Number: 3105
DOT Hazard Class: 5.2
DOT Packing Group: II
SECTION 15 - REGULATORY INFORMATION
Dimethylphthalate :
TSCA Inventory Status: Listed
SARA: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
Methyl ethyl ketone peroxide :
TSCA Inventory Status: Listed
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
Dipropylene glycol :
TSCA Inventory Status: Listed
State Regulations: Listed in the Pennsylvania State Hazardous Substances List.
Hydrogen peroxide :
TSCA Inventory Status: Listed
Section 302 EHS: EPCRA (SARA Title III) Section 302 (40 CFR Part 355) Extremely Hazardous
Substances (EHS) Threshold Planning Quantity (TPQ) in pounds: 1,000 Lbs.
Section 302 RQ: EPCRA (SARA Title III) Section 302 Extremely Hazardous Substances (EHS)
Reportable Quantities (RQ) in pounds: 1,000 Lbs.
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
Methyl ethyl ketone :
TSCA Inventory Status: Listed
SARA: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
Canadian Regulations. WHMIS Hazard Class(es): D2B; C
All components of this product are on the Canadian Domestic Substances List.
SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard: 1
HMIS Health Hazard: 3*
HMIS Reactivity: 3
Page 5 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030H
HMIS Personal Protection: X
MSDS Revision Date: 10/10/2006
MSDS Author: Actio Corporation
Disclaimer: This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment.
Copyright?1996-2008 Actio Software Corporation. All Rights Reserved.
Page 6 of 6 (Revision Date: 10/10/2006)
MSDS Number: MI030R
View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: SOCKETLOCK RESIN HMIS
MSDS Manufacturer MI030R
Health Hazard 2*
Number:
Manufacturer Name: ITW Polymer Technologies Fire Hazard 3
Address: 130 Commerce Drive
Montgomeryville, PA 18936 REACTIVITY 2
General Phone Number: (215) 855-8450 Personal
X
Emergency Phone Number: (215) 855-8450 Protection
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300 * Chronic Health
Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) Effects:
MSDS Revision Date: 10/10/2006
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS# Ingredient Percent
Styrene 100-42-5 10 - 30 by weight
Crystalline silica 14808-60-7 30 - 60 by weight
Polyester Resin 26098-37-3 10 - 30 by weight
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Reactive. Suspect Carcinogen. Irritant.
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye: Can cause moderate irritation, burning sensation, tearing, redness, and swelling.
Overexposure may cause lacrimation, conjunctivitis, corneal damage and
permanent injury.
Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache,
and anesthetic effects.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Central nervous system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
SECTION 4 - FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes.
Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes.
Get medical attention if irritation develops or persists.
Page 1 of 5 (Revision Date: 10/10/2006)
MSDS Number: MI030R
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.
SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties: Flammable.
Flammable liquid.
Flash Point: 90癋 (32.2癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: 914癋
Lower Flammable/Explosive Limit: 1.1%
Upper Flammable/Explosive Limit: 6.1%
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH
(approved or equivalent) and full protective gear.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a
chemical waste container. Provide ventilation. Collect spill with a non-sparking
tool. Place into a suitable container for disposal. Clean up spills immediately
observing precautions in the protective equipment section. After removal, flush
spill area with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture
with air. . Vapors can flow along surfaces to distant ignition sources and flash
back. Ventilate area. Use proper personal protective equipment as listed in
section 8.
Other Precautions: Pump or shovel to storage/salvage vessels.
SECTION 7 - HANDLING and STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material
will accumulate static charges which may cause an electrical spark (ignition
source). Use proper grounding procedures. Do not reuse containers without
proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, direct sunlight, and incompatible substances. Keep container tightly
closed when not in use.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product. Hazardous liquid or vapor
residue may remain in emptied container. Do not reuse, heat, burn, pressurize,
cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources
of empty containers without proper commercial cleaning or reconditioning.
Hygiene Practices: Wash thoroughly after handling.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
Page 2 of 5 (Revision Date: 10/10/2006)
MSDS Number: MI030R
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
EXPOSURE GUIDELINES
Styrene :
Guideline ACGIH: ACGIH TLV-STEL 40 ppm
Guideline OSHA: OSHA PEL-STEL 600 ppm Ceiling/Peak
Crystalline silica :
Guideline ACGIH: ACGIH TLV-TWA 0.025 mg/m3
Guideline OSHA: OSHA PEL-TWA [10 mg/m3]/[{% SiO2} + 2]
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance: Liquid..
Color: Thick white.
Odor: Pungent.
Boiling Point: 295癋 (146.1癈)
Melting Point: Not determined.
Specific Gravity: 1.1-1.5
Solubility: negligible
Vapor Density: > 1 (air = 1)
Vapor Pressure: 4.5 mmHg @68癋
Percent Volatile: <30
Evaporation Rate: Not determined.
pH: Not applicable.
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 90癋 (32.2癈)
Flash Point Method: Tag closed cup (TCC)
Auto Ignition Temperature: 914癋
VOC Content: Not determined.
Percent Solids by Weight >70
SECTION 10 - STABILITY and REACTIVITY
Chemical Stability: Unstable.
Hazardous Polymerization: Polymerization may occur under certain conditions.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions.
Incompatible Materials: Oxidizing agents. Strong acids and alkalis.
SECTION 11 - TOXICOLOGICAL INFORMATION
Styrene :
Page 3 of 5 (Revision Date: 10/10/2006)
MSDS Number: MI030R
Eye: Eye - Rabbit Standard Draize Test. : 100 mg/24H - [Moderate](RTECS)
Skin: Skin - Rabbit Standard Draize Test. : 100% - [Moderate](RTECS)
Inhalation: Inhalation. - Rat LC50: 11800 mg/m3/4H - [Details of toxic effects not reported
other than lethal dose value.] (RTECS)
Inhalation. - Mouse LC50: 21000 mg/m3/2H - [Details of toxic effects not
reported other than lethal dose value.] (RTECS)
Inhalation. - Mouse LC50: 9500 mg/m3/4H - [Details of toxic effects not
reported other than lethal dose value.] (RTECS)
Ingestion: Oral - Rat LD50: 5000 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Oral - Mouse LD50: 316 mg/kg - [Details of toxic effects not reported other than
lethal dose value. ] (RTECS)
Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans.
Crystalline silica :
Inhalation: Inhalation. - Rat TCLo - Lowest published toxic concentration: 1 mg/kg - [Lungs,
Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary)
- effect on inflammation or mediation of inflammation ] (RTECS)
Ingestion: Oral - Rat TDLo - Lowest published toxic dose: 120 gm/kg - [Gastrointestinal -
hypermotility, diarrhea Gastrointestinal - other changes ] (RTECS)
Carcinogenicity: IARC: Group 1: Carcinogenic to humans.
NTP: Reasonably anticipated to be a human carcinogen.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number: D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal container.
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: Resin solution
DOT UN Number: 1866
DOT Hazard Class: 3
DOT Packing Group: III
SECTION 15 - REGULATORY INFORMATION
Styrene :
TSCA Inventory Status: Listed
SARA: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
Crystalline silica :
TSCA Inventory Status: Listed
State Regulations: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
Polyester Resin :
TSCA Inventory Status: Listed
Canadian Regulations. WHMIS Hazard Class(es): B2; D2A; D2B;
Page 4 of 5 (Revision Date: 10/10/2006)
MSDS Number: MI030R
WHMIS Pictograms
SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard: 3
HMIS Health Hazard: 2*
HMIS Reactivity: 2
HMIS Personal Protection: X
MSDS Revision Date: 10/10/2006
MSDS Author: Actio Corporation
Disclaimer: This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment.
Copyright?1996-2008 Actio Software Corporation. All Rights Reserved.
Page 5 of 5 (Revision Date: 10/10/2006)
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