DOLIUM(R) GREASE R
71604 08/13/93
SHELL MATERIAL SAFETY DATA SHEET
BE SAFE. READ OUR PRODUCT SAFETY INFORMATION ... AND PASS IT ON.
PRODUCT LIABILITY LAW REQUIRES IT!
******************** MATERIAL SAFETY DATA SHEET 56476 - 00 ********************
DOLIUM(R) GREASE R SH MSDS: 56476 - 00 08/13/93
MANUFACTURER'S NAME AND ADDRESS
SHELL OIL COMPANY
PRODUCT SAFETY & COMPLIANCE
P.O. BOX 4320
HOUSTON, TX 77210
TELEPHONE NUMBERS:
24 HOUR EMERGENCY ASSISTANCE
SHELL: 713-473-9461 CHEMTREC: 800-424-9300
GENERAL MSDS ASSISTANCE
SHELL: 713-241-4819
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SECTION I | NAME
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PRODUCT: DOLIUM(R) GREASE R
CHEM NAME: MIXTURE, (SEE SECTION II-A) ACUTE HEALTH HAZARD: 1
CHEM FAMILY: PETROLEUM HYDROCARBON; LUBRICATING FIRE HAZARD: 1
GREASE
SHELL CODE: 71604 REACTIVITY: 0
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SECTION II-A | PRODUCT/INGREDIENT
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NO. COMPOSITION CAS PERCENT
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P DOLIUM GREASE R MIXTURE 100
1 SOLVENT REFINED; HYDROTREATED 64742-54-7 82.0
HEAVY PARAFFINIC DISTILLATES
2 POLYUREA THICKENERS MIXTURE 14.0
3 OTHER COMPONENT CONTAINING: MIXTURE 4.0
3A SODIUM NITRITE 7632-00-0 0.5
3B ZINC NAPHTHENATE 12001-85-3 2.5
NFPA HAZARD RATING: HEALTH 0 FIRE 1 REACTIVITY 0
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SECTION II-B | ACUTE TOXICITY DATA
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NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
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P NOT AVAILABLE
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SECTION III | HEALTH INFORMATION
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THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT:
MAY BE MILDLY IRRITATING TO THE EYES.
SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE VARIOUS SKIN DISORDERS SUCH AS
DERMATITIS, FOLLICULITIS OR OIL ACNE. RELEASE DURING HIGH PRESSURE USAGE
MAY RESULT IN INJECTION OF OIL INTO THE SKIN CAUSING LOCAL NECROSIS.
INHALATION:
NO SPECIFIC INFORMATION IDENTIFIED.
INGESTION:
NO SPECIFIC INFORMATION IDENTIFIED.
SIGNS AND SYMPTOMS:
IRRITATION AS NOTED ABOVE. LOCAL NECROSIS IS EVIDENCED BY DELAYED ONSET OF
PAIN AND TISSUE DAMAGE A FEW HOURS FOLLOWING INJECTION.
AGGRAVATED MEDICAL CONDITIONS:
PREEXISTING SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
OTHER HEALTH EFFECTS:
THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), NATIONAL TOXOCOLOGY
PROGRAM (NTP) OR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA).
THIS SPECIFIC PRODUCT HAS NOT BEEN TESTED IN LONG-TERM, CHRONIC EXPOSURE
TESTS. LUBRICATING GREASES ARE GENERALLY CONSIDERED TO BE OF A LOW ORDER
OF ACUTE TOXICITY TO HUMANS AND EXPERIMENTAL ANIMALS. HOWEVER, THE
HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE
FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE.
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SECTION IV | OCCUPATIONAL EXPOSURE LIMITS
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OSHA ACGIH
NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER
================================================================================
NO OSHA/PEL OR ACGIH/TLV HAS BEEN ESTABLISHED.
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SECTION V | EMERGENCY AND FIRST AID PROCEDURES
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EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET
MEDICAL ATTENTION.
SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WIPE EXCESS OFF. WASH WITH SOAP
AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER.
DO NOT REUSE CLOTHING UNTIL THOROUGHLY CLEANED. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. IF MATERIAL IS INJECTED UNDER
THE SKIN, GET MEDICAL ATTENTION PROMPTLY TO PREVENT SERIOUS
DAMAGE; DO NOT WAIT FOR SYMPTOMS TO DEVELOP.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. IN GENERAL, NO TREATMENT IS NECESSARY
UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. HOWEVER, GET
MEDICAL ADVICE.*
NOTE TO PHYSICIAN: *NOTE TO THE PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS
UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS,
I.E., MOST OILS AND GREASES.
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SECTION VI | SUPPLEMENTAL HEALTH INFORMATION
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NORMAL USE OF THIS PRODUCT SHOULD NOT RESULT IN OVEREXPOSURE TO COMPONENT 3,
SODIUM NITRITE. HOWEVER, IN CASE OF ACCIDENTAL INGESTION, SODIUM NITRITE MAY
ALTER THE BLOOD (HEMOGLOBIN) TO REDUCE OXYGEN CARRYING CAPACITY; CYANOSIS
(BLUISH SKIN), SHORTNESS OF BREATH, PALPITATIONS, COMA AND/OR DEATH MAY OCCUR.
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SECTION VII | PHYSICAL DATA
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BOILING POINT (DEG F): SPECIFIC GRAVITY (H20=1): VAPOR PRESSURE (MM HG):
NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
MELTING POINT (DEG F): SOLUBILITY (IN WATER): VAPOR DENSITY (AIR=1):
426 (DROP POINT) INSOLUBLE NOT AVAILABLE
EVAPORATION RATE (NORMAL BUTYL ACETATE = 1): NOT AVAILABLE
APPEARANCE AND ODOR: AMBER, SMOOTH, SLIGHT ODOR.
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SECTION VIII | FIRE AND EXPLOSION HAZARDS
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FLASH POINT AND METHOD: FLAMMABLE LIMITS/% VOLUME IN AIR:
465 DEG F. PMCC (BASE OIL) LOWER: N/AV UPPER: N/AV
EXTINGUISHING MEDIA:
USE WATER FOG, DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF WATER.
PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
DO NOT ENTER CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT
INCLUDING A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE
EXPOSED CONTAINERS SURROUNDING EQUIPMENT AND STRUCTURES WITH WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
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SECTION IX | REACTIVITY
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID:
AVOID HEAT, OPEN FLAME AND CONTACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION
CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID PARTICULATES AND
GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION.
CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON
COMBUSTION.
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SECTION X | EMPLOYEE PROTECTION
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RESPIRATORY PROTECTION:
NOT ORDINARILY REQUIRED.
PROTECTIVE CLOTHING:
USE OIL RESISTANT GLOVES AND OTHER CLOTHING AS NEEDED TO MINIMIZE SKIN
CONTACT.
ADDITIONAL PROTECTIVE MEASURES:
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SECTION XI | ENVIRONMENTAL PROTECTION
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SPILL OR LEAK PROCEDURES:
SCOOP UP EXCESS GREASE. CLEAN AREA WITH APPROPRIATE CLEANER.
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SECTION XII | SPECIAL PRECAUTIONS
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STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN
FLAMES AND HIGH TEMPERATURES.
MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES,
THAT CANNOT BE DECONTAMINATED.
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SECTION XIII | TRANSPORTATION REQUIREMENTS
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DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
NOT HAZARDOUS BY D.0.T. REGULATIONS
D.O.T. PROPER SHIPPING NAME:
OTHER REQUIREMENTS:
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SECTION XIV | OTHER REGULATORY CONTROLS
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THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES EXCEPT THOSE WHICH ARE SPECIFICALLY NOT SUBJECT TO NOTIFICATION
REQUIREMENTS IN 40 CFR 720.30.
PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR
WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING
SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA
SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
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SECTION XV | STATE REGULATORY INFORMATION
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THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER
PRODUCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO
BE APPLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY
REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT CAS NUMBER PERCENT STATE CODE
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SODIUM NITRITE 7632-00-0 0.5 CA, MA, PA
CA = CALIFORNIA HAZ. SUBST. LIST; CA65C, CA65R, CA65C/R = CALIFORNIA SAFE
DRINKING WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST; CT =
CONNECTICUT TOXIC. SUBST. LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX.
SUBST. LIST; LA = LOUISIANA HAZ. SUBST. LIST; MA = MASSACHUSETTS SUBST.
LIST; ME = MAINE HAZ. SUBST. LIST; MN = MINNESOTA HAZ. SUBST. LIST; NJ =
NEW JERSEY HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE
ISLAND HAZ. SUBST. LIST.
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SECTION XVI | SPECIAL NOTES
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MSDS CREATED FOR THIS PRODUCT CODE, 71604.
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THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS
BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE
THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE
PRODUCT DESCRIBED HEREIN.
WE ARE PROVIDING OUR MOST RECENT MATERIAL SAFETY DATA SHEET AND/OR
ENVIRONMENTAL DATA SHEET. IF YOU WISH TO RECEIVE UPDATES TO THIS INFORMATION,
PLEASE CALL SHELL'S GENERAL MSDS ASSISTANCE LINE (713-241-4819) TO ENSURE THAT
YOU ARE ADDED TO SHELL'S REGULAR MSDS DISTRIBUTION SYSTEM.
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BE SAFE. READ OUR PRODUCT SHELL OIL COMPANY
SAFETY INFORMATION...AND PRODUCT SAFETY AND COMPLIANCE
PASS IT ON. (PRODUCT P. O. BOX 4320
LIABILITY LAW REQUIRES IT) HOUSTON, TX. 77210
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********************** ENVIRONMENTAL DATA SHEET 56476 - 00 ********************
EDS: 56476 - 00 08/13/93
PRODUCT NAME: DOLIUM(R) GREASE R
PRODUCT CODE: 71604
MANUFACTURER'S NAME AND ADDRESS
SHELL OIL COMPANY
P.O. BOX 4320
HOUSTON, TX 77210
TELEPHONE NUMBERS:
24 HOUR EMERGENCY ASSISTANCE
SHELL: 713-473-9461 CHEMTREC: 800-424-9300
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE
CALL 713-241-2252
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SECTION I | PRODUCT COMPOSITION
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NO. COMPOSITION CAS PERCENT
================================================================================
P DOLIUM GREASE R MIXTURE 100
1 SOLVENT REFINED; HYDROTREATED HEAVY 64742-54-7 82.0
PARAFFINIC DISTILLATE
2 POLYUREA THICKENERS MIXTURE 14.0
3 OTHER COMPONENT CONTAINING: MIXTURE 4.0
3A SODIUM NITRITE 7632-00-0 0.5
3B ZINC NAPHTHENATE 12001-85-3 2.5
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SECTION II | SARA TITLE III INFORMATION
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NO. EHS RQ* EHS TPQ* SEC-313 313 CATEGORY 311/312 CATEGORY
(*1) (*2) (*3) (*4) (*5)
================================================================================
3A H-1
3B YES ZINC COMPOUNDS
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*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.42), MUST BE USED ON TOXIC
RELEASE INVENTORY FORM
*5 = HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING
HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL: P-3 = FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD
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SECTION III | ENVIRONMENTAL RELEASE INFORMATION
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THIS PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE
RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA
("SUPERFUND"). HOWEVER UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA),
THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH , SPILLS INTO OR LEADING TO
SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 800-424-8802.
THIS PRODUCT IS AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED BY RAIL OR
HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT IS SUBJECT TO
THE REQUIREMENTS OF PART 130. MIXTURE SOLUTIONS IN WHICH THIS PRODUCT IS
PRESENT AT 10% OR MORE MAY ALSO BE SUBJECT TO THIS RULE.
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SECTION IV | RCRA INFORMATION
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IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA
CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
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WE ARE PROVIDING OUR MOST RECENT MATERIAL SAFETY DATA SHEET AND/OR
ENVIRONMENTAL DATA SHEET. IF YOU WISH TO RECEIVE UPDATES TO THIS INFORMATION,
PLEASE CALL SHELL'S GENERAL MSDS ASSISTANCE LINE (713-241-4819) TO ENSURE THAT
YOU ARE ADDED TO SHELL'S REGULAR MSDS DISTRIBUTION SYSTEM.
--------------------------------------------------------------------------------
SHELL OIL COMPANY
P.O. BOX 4320
HOUSTON, TX 77210
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL
(713) 241-2252
FOR EMERGENCY ASSISTANCE PLEASE CALL
SHELL: (713) 473-9461
CHEMTREC: (800) 424-9300
********************************************************************************
THIS MSDS HAS BEEN PROVIDED IN AN ELECTRONIC FORMAT FOR USE IN THE CHEMTREC
EMERGENCY RESPONSE PROGRAM AND/OR OTHER APPROVED PROGRAMS. THIS FORMAT MAY
CONTAIN BLANKS WHERE INFORMATION WAS NOT AVAILABLE OR NOT APPLICABLE AND
THEREFORE MAY NOT BE FULLY COMPLIANT WITH THE OSHA HAZARD COMMUNICATION
STANDARD. IF YOU PURCHASE OR USE THIS SHELL PRODUCT AND HAVE NOT RECEIVED
A MSDS FROM SHELL PLEASE CONTACT US AND WE WILL PROVIDE ONE. THIS WILL ENSURE
THAT YOU RECEIVE UPDATES OF THIS INFORMATION.
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