MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 1999, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: INDUSTRIAL TAPE AND SPECIALTIES DIVISION
TRADE NAME:
3M BRAND SUPER 77 SPRAY ADHESIVE
ISSUED: August 10, 1999
SUPERSEDES: August 11, 1998
DOCUMENT: 08-7157-4
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1. INGREDIENT C.A.S. NO. PERCENT
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NON-VOLATILE COMPONENTS (SYNTHETIC
RUBBER, ROSIN DERIVATIVE, HYDROCARBON
RESIN). TRADE SECRET.................. None 25.0 - 30.0
N-HEXANE................................ 110-54-3 15.0 - 20.0
CYCLOHEXANE............................. 110-82-7 10.0 - 15.0
ISOBUTANE............................... 75-28-5 10.0
DIMETHYL ETHER.......................... 115-10-6 10.0
3-METHYLPENTANE......................... 96-14-0 5.0 - 10.0
PROPANE................................. 74-98-6 10.0
METHYLCYCLOPENTANE...................... 96-37-7 1.0 - 5.0
2-METHYLPENTANE......................... 107-83-5 1.0 - 5.0
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
N-HEXANE
CYCLOHEXANE
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2. PHYSICAL DATA
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BOILING POINT:................. N/A
VAPOR PRESSURE:................ N/A
VAPOR DENSITY:................. N/A
EVAPORATION RATE:.............. N/A
SOLUBILITY IN WATER:........... N/A
SPECIFIC GRAVITY:.............. 0.780 Water=1
PERCENT VOLATILE:.............. 78.00 %
pH:............................ N/A
VISCOSITY:..................... N/A
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SUPER 77 SPRAY ADHESIVE
August 10, 1999 PAGE 2
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2. PHYSICAL DATA (continued)
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MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Liquid in aerosol container
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... -46.00 C
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/A
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head. Water may not
effectively extinguish fire; however, it should be used to keep fire-
exposed containers and surfaces cool and prevent explosive rupture.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 4 REACTIVITY: 1
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Aldehydes, Ketones, Hydrocarbons.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SUPER 77 SPRAY ADHESIVE
August 10, 1999 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Extinguish
all ignition sources. Cover with absorbent material. Collect using
non-sparking tools. Place in an approved metal container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Facility must be capable of handling
aerosol cans. Dispose of empty cans in a sanitary landfill. Dispose
of completely absorbed waste product in a facility permitted to
accept chemical wastes.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 748 gms/liter.
VOC Less H2O & Exempt Solvents: 748 gms/liter.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SUPER 77 SPRAY ADHESIVE
August 10, 1999 PAGE 4
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
Wear safety glasses with side shields.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material. A pair of gloves made from the
following material(s) are recommended: nitrile rubber,
polyethylene/ethylene vinyl alcohol, polyvinyl alcohol,
polytetrafluoroethylene (Teflon), fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep out
of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Keep away
from heat, sparks, open flame, and other sources of ignition.
Extremely flammable liquid and vapor. Do not pierce or burn
container, even after use. Avoid static discharge.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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NON-VOLATILE COMPONENTS (SYNTHETIC
RUBBER, ROSIN DERIVATIVE,
HYDROCARBON RESIN). TRADE SECRET... NONE NONE NONE NONE
N-HEXANE............................. 50 PPM TWA ACGIH Y
N-HEXANE............................. 50 PPM TWA OSHA
CYCLOHEXANE.......................... 300 PPM TWA ACGIH
CYCLOHEXANE.......................... 300 PPM TWA OSHA
ISOBUTANE............................ NONE NONE NONE NONE
DIMETHYL ETHER....................... 1000 PPM TWA CMRG
DIMETHYL ETHER....................... 500 PPM TWA AIHA
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SUPER 77 SPRAY ADHESIVE
August 10, 1999 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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DIMETHYL ETHER....................... 942 MG/M3 TWA AIHA
3-METHYLPENTANE...................... 500 PPM TWA ACGIH
3-METHYLPENTANE...................... 1000 PPM STEL ACGIH
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. 2500 PPM TWA ACGIH
METHYLCYCLOPENTANE................... 500 PPM TWA ACGIH
METHYLCYCLOPENTANE................... 1000 PPM STEL ACGIH
2-METHYLPENTANE...................... 500 PPM TWA ACGIH
2-METHYLPENTANE...................... 1000 PPM STEL ACGIH
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
May be absorbed through the skin in harmful amounts.
INHALATION:
Intentional concentration and inhalation may be harmful or fatal.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SUPER 77 SPRAY ADHESIVE
August 10, 1999 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Peripheral Neuropathy: signs/symptoms can include tingling of
extremities, incoordination, numbness, weakness and tremors.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE August 11, 1998 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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