www.Titebond.comFranklin International
MATERIAL SAFETY DATA SHEET
MSDS Name: Titebond Multi-Purpose 100% Silicone White
MSDS Number: 2601
Revision Date: 8/11/05
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Titebond Multi-Purpose 100% Silicone
White
CAS Number: none
HMIS Hazard Rating: Health: 1 Fire: 1 Reactivity: 0
Company Identification: Franklin International
2020 Bruck Street
Columbus OH 43207
Contact: Franklin Technical Services
Telephone/Fax: (800) 877-4583 (614) 445-1493
Emergency Phone (24 Hour): Franklin Security
(614) 445-1300
Chemtrec (24 Hour): (800) 424-9300
Chemtrec International: (703) 527-3887
Product Class silicone elastomer
Product Use: caulk sealant
Product Code: Not applicable
Division: Construction Adhesives & Sealants
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS Number Percent
methyltriacetoxysilane 4253-34-3 2.00
ethyltriacetoxsilane 17689-77-9 2.00
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.
SECTION 3 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
CAUTION: IRRITANT. Direct contact with uncured caulk irritates eyes
and skin. Overexposure to vapor may irritate eyes, nose and throat.
Caulk may release acetic acid vapor (vinegar-like odor) during cure.
Fully cured caulk is nonhazardous. KEEP OUT OF THE REACH OF CHILDREN.
Material is a paste-like material that can be of various colors.
ROUTES OF ENTRY:
Inhalation: yes
Ingestion: yes
Skin: no
Eye: yes
INHALATION:
May be irritating to upper respiratory tract.
INGESTION:
Ingestion is not a probable route of exposure. Single dose oral
toxicity is considered to be extremely low. No hazard expected from
swallowing small amounts incidental to normal handling operations.
Ingestion may cause gastrointestinal irritation.
SKIN:
Prolonged or repeated skin contact may cause moderate irritation.
EYE:
Substance may cause moderate eye irritation.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
None identified.
CARCINOGENICITY:
IARC: No
NTP: No
OSHA: No
REPRODUCTIVE TOXICITY:
None currently known.
TARGET ORGANS:
Eyes, skin, and respiratory tract.
SECTION 4 - FIRST AID MEASURES
INHALATION:
Remove to fresh air. If difficulty persists, seek medical attention.
INGESTION:
Call poison control center immediately. Follow their specific
instructions.
SKIN:
Wash with soap and water or waterless cleaner. Contact a physician if
irritation develops or persist.
EYE:
Hold eyelids apart and flush with plenty of water for at least 15
minutes. Seek medical attention.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability Class (OSHA) IIIB
Flash Point: > 200.疐
Tag Closed Cup
Explosive Range: Not applicable
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, water spray, or ABC dry chemical
when fighting fires involving this product.
FIRE FIGHTING PROCEDURES:
Wear a NIOSH approved self contained breathing apparatus. Wear
appropriate personal protective equipment.
Product will not burn but may spatter if temperature exceeds boiling
point of water. After water evaporates, remaining material will burn.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES:
Use inert absorbent to dike the spill. Keep away from drains.
CLEAN-UP:
Spread absorbent over material and scrape up material/absorbent and
place in an approved container. If product has dried scrape up and
place in an approved container.
SECTION 7 - HANDLING AND STORAGE
HANDLING:
Wash thoroughly after handling.
Do not get material in eyes.
Avoid breathing vapors.
Avoid prolonged or repeated contact with the skin.
STORAGE:
Store in a cool, dry place. Avoid contact with moist air.
PRECAUTIONARY STATEMENT:
Keep out of the reach of children.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
methyltriacetoxysilane
N/est N/est N/est N/est N/est
ethyltriacetoxsilane
N/est N/est N/est N/est N/est
Note: Product evolves acetic acid (CAS# 64-19-7) when exposed to
moisture or humid air. The ACGIH TLV for acetic acid is 10.00 ppm with
a 15-minute STEL of 15 ppm. The OSHA PEL for acetic acid is 10.00 ppm.
ENGINEERING CONTROLS:
Use appropriate ventilation as needed to maintain occupational
exposure limits.
OTHER:
Facilities storing or utilizing any chemical should be equipped with
an eyewash facility and a safety shower.
RESPIRATORY PROTECTION:
Respiratory protection is not expected to be necessary under normal
use. Follow requirements for respiratory protection in OSHA 1910.134.
EYE PROTECTION:
Chemical splash goggles (ANSI Z87.1 or approved equivalent).
SKIN PROTECTION:
Where skin contact can occur, wear impervious gloves.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: Paste
Appearance/Color: White
Odor: Acetic acid
Solubility (in water): Nil
pH Value: Not Available
Boiling Range/Point: Not Available
Evaporation Rate: Slower than n-Butyl Acetate
% Volatile: < 5
Specific Gravity: 1.03
VOC: 32.0 g/l
SECTION 10 - STABILITY AND REACTIVITY
Stability: This product is stable
Hazardous Polymerization: Hazardous polymerization will not occur
CONDITIONS TO AVOID:
None known.
INCOMPATIBLITY:
Water or damp air; product cures in the presence of moisture. Avoid
oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS:
Acetic acid is released on hydrolysis.
SECTION 11 - TOXICOLOGICAL INFORMATION
Inhalation of Acetic Acid vapor is irritating to the eyes and
respiratory system. Direct and prolonged contact with the skin is
irritating.
SECTION 12 - ECOLOGICAL INFORMATION
This formulation has not been tested for environmental effects.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal of this product must comply with all applicable federal,
state and local regulations.
CONTAINER DISPOSAL:
Disposal of this container should comply with all applicable federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
UN Number None
UN Pack Group N/A
UN Class Nonhaz
ICAO/IATA Class Nonhazardous
IMDG Class Nonhazardous
Shipping Name Nonhazardous
Packaging may not be approved for shipping by air. Please contact
Franklin International for further information.
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic Substances Control Act Inventory):
All components of this product are listed on the TSCA inventory except
as exempted.
PENNSYLVANIA:
Nonhazardous components required to be listed at 3% or more:
amorphous silica 7631-86-9; polydimethylsiloxane 63148-62-9
NEW JERSEY:
fumed amorphous silica 7631-86-9; methyltriacetoxysilane 4153-34-3;
ethyltriacetoxysilane 17689-77-9; polydimethylsiloxane 63148-62-9;
dimethyl siloxane, hydroxy-terminated 70131-67-8
SECTION 16 - OTHER INFORMATION
DISCLAIMER:
While the information and recommendations set forth herein are
believed to be accurate as of the data hereof, Franklin International
makes no warranty, express or implied, with respect thereto and
disclaims all liability from reliance thereon.
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