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1 - PRODUCT IDENTIFICATION
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PRODUCT NAME: ANILINE
FORMULA: C6H5NH2
FORMULA WT: 93.13
CAS NO.: 00062-53-3
NIOSH/RTECS NO.: BW6650000
COMMON SYNONYMS: BENZAMINE; ANILINE OIL, PHENYLAMINE; AMINOBENZENE;
BENZENAMINE
PRODUCT CODES: 9110,9112
EFFECTIVE: 08/27/86
REVISION #02
PRECAUTIONARY LABELLING
BAKER SAF-T-DATA(TM) SYSTEM
HEALTH - 3 SEVERE (POISON)
FLAMMABILITY - 2 MODERATE
REACTIVITY - 2 MODERATE
CONTACT - 3 SEVERE (LIFE)
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
LABORATORY PROTECTIVE EQUIPMENT
STOP SIGN - SEE SECTION VIII FOR PRECAUTIONS
PRECAUTIONARY LABEL STATEMENTS
POISON DANGER
COMBUSTIBLE
VAPOR EXTREMELY IRRITATING
MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN
EXCEPTIONAL CONTACT HAZARD - READ MATERIAL SAFETY DATA SHEET
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY,
ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER
SPRAY.
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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2 - HAZARDOUS COMPONENTS
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COMPONENT % CAS NO.
ANILINE 90-100 62-53-3
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3 - PHYSICAL DATA
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BOILING POINT: 184 C ( 363 F) VAPOR PRESSURE(MM HG): 0.6
MELTING POINT: -6 C ( 21 F) VAPOR DENSITY(AIR=1): 3.22
SPECIFIC GRAVITY: 1.02 EVAPORATION RATE: <1
(H2O=1) (BUTYL ACETATE=1)
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: N/A
APPEARANCE & ODOR: OILY LIQUID, COLORLESS UNLESS EXPOSED TO AIR OR LIGHT.
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4 - FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT (CLOSED CUP: 70 C ( 158 F) NFPA 704M RATING: 3-2-0
FLAMMABLE LIMITS: UPPER - N/A % LOWER - 1.3 %
FIRE EXTINGUISHING MEDIA
USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM.
SPECIAL FIRE-FIGHTING PROCEDURES
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS
GIVES OFF FLAMMABLE VAPORS. VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
OXIDIZERS MAY CAUSE FIRE.
TOXIC GASES PRODUCED
AMMONIA, NITROGEN OXIDES, CARBON MONOXIDE, CARBON DIOXIDE
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5 - HEALTH HAZARD DATA
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TLV AND PEL LISTED DENOTE (SKIN).
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( 2 PPM)
PERMISSIBLE EXPOSURE LIMIT (PEL): 19 MG/M3 ( 5 PPM)
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 250
LD50 (SKN-RAT) (MG/KG) - 1400
LD50 (IPR-RAT)(MG/KG) - 420
LC50 (INHL-MOUSE-7H) (PPM) - 175
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
EFFECTS OF OVEREXPOSURE
ACUTE POISONING VIA ALL ROUTES OF EXPOSURE MAY BE SEVERE ENOUGH TO BE
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FATAL.
ANILINE POISONING IS CHARACTERIZED BY METHEMOGLOBIN FORMATION IN THE
BLOOD, RESULTING IN CYANOSIS. OTHER SYMPTOMS THAT MAY OCCUR BECAUSE OF
INHALATION OF VAPORS, SKIN ABSORPTION, OR INGESTION ARE HEADACHE, NAUSEA,
VOMITING, CONFUSION, DIZZINESS, DROWSINESS, AND LOSS OF CONSCIOUSNESS.
LIQUID MAY BE IRRITATING TO SKIN AND EYES.
LIQUID MAY CAUSE PERMANENT EYE DAMAGE.
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE ANEMIA, ANOREXIA, AND SKIN
LESIONS.
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
TARGET ORGANS
BLOOD, CARDIOVASCULAR SYSTEM, LIVER, KIDNEYS
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
NONE IDENTIFIED
ROUTES OF ENTRY
INHALATION, ABSORPTION, INGESTION, EYE CONTACT, SKIN CONTACT
EMERGENCY AND FIRST AID PROCEDURES
CALL A PHYSICIAN.
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
THOROUGH CLEANSING OF THE ENTIRE CONTAMINATED AREA OF THE BODY INCLUDING
SCALP AND NAILS IS OF THE UTMOST IMPORTANCE.
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6 - REACTIVITY DATA
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, AIR, LIGHT
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS,
ALKALIES, ZINC, ALUMINUM, RUBBER, LEATHER,
SOLUTIONS CONTAINING IRON SALTS
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN, AMMONIA,
CARBON MONOXIDE, CARBON DIOXIDE
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7 - SPILL AND DISPOSAL PROCEDURES
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
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CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
FOR SPILLS OF THIS PRODUCT.
DISPOSAL PROCEDURE
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER: U012 (TOXIC WASTE)
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8 - PROTECTIVE EQUIPMENT
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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
TLV REQUIREMENTS.
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
TO 100 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE
THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS
IS RECOMMENDED.
EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM,
PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.
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9 - STORAGE AND HANDLING PRECAUTIONS
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
SPECIAL PRECAUTIONS
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED,
FLAMMABLE LIQUID STORAGE AREA OR CABINET.
KEEP PRODUCT OUT OF LIGHT.
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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DOMESTIC (D.O.T.)
PROPER SHIPPING NAME ANILINE
HAZARD CLASS POISON B
UN/NA UN1547
LABELS POISON
REPORTABLE QUANTITY 5000 LBS.
INTERNATIONAL (I.M.O.)
PROPER SHIPPING NAME ANILINE
HAZARD CLASS 6.1
UN/NA UN1547
LABELS POISON
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