230102-00 COMMERCIAL PROPANE
MATERIAL SAFETY DATA BULLETIN
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1. PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: COMMERCIAL PROPANE
SUPPLIER: EXXONMOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA 22037
24 - Hour Health and Safety Emergency (call collect): 609-737-4411
24 - Hour Transportation Emergency:
CHEMTREC: 800-424-9300 202-483-7616
LUBES AND FUELS: 281-834-3296
Product and Technical Information:
Lubricants and Specialties: 800-662-4525 800-443-9966
Fuels Products: 800-947-9147
MSDS Fax on Demand: 613-228-1467
MSDS Internet Website: http://emmsds.ihssolutions.com/
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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CHEMICAL NAMES AND SYNONYMS: PROPANE
GLOBALLY REPORTABLE MSDS INGREDIENTS:
Substance Name Approx. Wt%
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PROPANE (74-98-6) 85-95
PROPYLENE (115-07-1) 1-5
BUTANE (106-97-8) 1-5
See Section 8 for exposure limits (if applicable).
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3. HAZARDS IDENTIFICATION
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This product is considered hazardous according to regulatory guidelines
(See Section 15).
EMERGENCY OVERVIEW: Colorless Liquified Gas. Extremely flammable.
Vapor accumulation could flash and/or explode if in contact with
open flame. Pressurized containers may explode if exposed to
open flames or high temperatures. DOT ERG No. : 115
POTENTIAL HEALTH EFFECTS: Can cause irritation or freeze burns if
contact with compressed liquid occurs. ***** This product is an
asphyxiant. Symptoms include respiratory irritation, dizziness,
nausea and loss of consciousness. In addition, exposure to
concentrations above 2% may cause a general central nervous
system (CNS) depression typical of anesthetic gases or
intoxicants. Continued exposure to odorized gas may reduce or
eliminate ability to smell the odorant. People with impaired
ability to detect odor due to colds, allergies, injuries, etc.
must be especially cautious. Odor must not be used exclusively
as a safety measure. Proper respiratory protection and
fire/explosion precautions should be utilized when odor is first
detected.
For further health effects/toxicological data, see Section 11.
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4. FIRST AID MEASURES
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EYE CONTACT: Flush thoroughly with water. If irritation occurs, call
a physician.
SKIN CONTACT: If frostbite occurs, immerse involved area in warm water
(between 100F/38C and 110F/43C, not exceeding 112F/44C). Keep
immersed for 20 to 40 minutes. Seek medical assistance. (See
Section 16 - Injection Injury)
INHALATION: Immediately remove from further exposure. Get immediate
medical assistance. For those providing assistance, avoid
exposure to yourself or others. Use adequate respiratory
protection. Give supplemental oxygen, if available. If
breathing has stopped, assist ventilation with a mechanical
device or use mouth-to-mouth resuscitation.
INGESTION: Not expected to occur in normal industrial use.
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5. FIRE-FIGHTING MEASURES
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EXTINGUISHING MEDIA: Carbon dioxide, dry chemical and water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Let fire burn; shut off gas supply.
Water should be used to keep fire-exposed containers cool. Stop
flow of material. Use water to keep fire exposed containers cool
and to protect personnel effecting shutoff. If a leak or spill
has not ignited, use water spray to disperse the vapors and to
protect personnel attempting to stop leak. Prevent runoff from
fire control or dilution from entering streams, sewers, or
drinking water supply.
SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire
fighters must use self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Vapor
accumulation could flash and/or explode if in contact with open
flame. Pressurized containers may explode if exposed to open
flames or high temperatures.
Flash Point C(F): -104(-156) (ASTM D-93).
Flammable Limits (approx.% vol.in air) - LEL: 2.0%, UEL: 9.5%
NFPA HAZARD ID: Health: 1, Flammability: 4, Reactivity: 0
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6. ACCIDENTAL RELEASE MEASURES
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NOTIFICATION PROCEDURES: Report spills/releases as required to
appropriate authorities. U.S. Coast Guard and EPA regulations
require immediate reporting of spills/releases that could reach
any waterway including intermittent dry creeks. Report
spill/release to Coast Guard National Response Center toll free
number (800)424-8802. In case of accident or road spill notify
CHEMTREC (800) 424-9300.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:
LAND SPILL: Eliminate sources of ignition. Warn occupants in
downwind areas of fire and explosion hazard. Shut off source taking
normal safety precautions.
WATER SPILL: Eliminate sources of ignition. Advise occupants and
ships in the vicinity in downwind areas of fire and explosion hazard
and warn them to stay clear. Notify port and other relevant
authorities. Do not confine in area of leakage.
ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers,
water sources or low lying areas; advise the relevant authorities
if it has, or if it contaminates soil/vegetation.
PERSONAL PRECAUTIONS: See Section 8
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7. HANDLING AND STORAGE
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HANDLING: Avoid all personal contact. Can cause irritation or freeze
burns if contact with compressed liquid occurs. Ethyl mercaptan
is added to gas as an odorant to aid in the detection of the gas
in case of leak or accidental discharge. Since ethyl mercaptan
is reactive, a reduction in its effectiveness may occur during
shipping and storage of the odorized gas. Therefore, odor must
not be used exclusively as a safety measure. Handle gas with
strict adherence to established safety procedures. See Section 8
for additional personal protection advice when handling this
product.
STORAGE: Store away from all ignition sources in a cool area equipped
with an automatic sprinkling system. Outside or detached storage
preferred. Storage containers should be grounded and bonded.
SPECIAL PRECAUTIONS: To prevent and minimize fire or explosion risk
from static accumulation and discharge, effectively bond and/or
ground product transfer system. Electrical equipment and
fittings must comply with local fire prevention regulations for
this class of product. Use the correct grounding procedures.
Refer to national or local regulations covering safety at
petroleum handling and storage areas for this product.
EMPTY CONTAINER WARNING: Empty containers retain residue (liquid
and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to
refill or clean container since residue is difficult to remove.
Empty drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner. All containers should
be disposed of in an environmentally safe manner and in
accordance with governmental regulations.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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---TWA--- ----STEL--- NOTE
Substance Name (CAS-No.) Source ppm mg/m3 ppm mg/m3
------ --- ----- --- ----- ----
PROPANE (74-98-6)
OSHA 1000 1800
ACGIH 2500 4508
XOM 1000 1500
PROPYLENE (115-07-1)
Simple asphyxiant ACGIH
XOM 1000 3000
BUTANE (106-97-8)
OSHA 800 1900
ACGIH 800 1900
XOM 1000 1500
NOTE: Limits shown for guidance only. Follow applicable regulations.
VENTILATION: Ventilation equipment must be explosion proof.
RESPIRATORY PROTECTION: Use supplied air breathing apparatus in oxygen
deficient atmospheres, or if petroleum gas concentration exceeds
rating or capacity of air purifying respirator cartridge/filter.
EYE PROTECTION: If eye contact is likely, safety glasses with side
shields or chemical type goggles should be worn.
SKIN PROTECTION: No special requirements under ordinary conditions of
use. Thermally protective gloves and long sleeves must be worn
when handling liquid. Good personal hygiene practices should
always be followed.
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9. PHYSICAL AND CHEMICAL PROPERTIES
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Typical physical properties are given below. Consult Product Data Sheet
for specific details.
APPEARANCE: Liquified Gas
COLOR: Colorless
ODOR: Sulfur
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): -42(-44)
MELTING POINT C(F): -187(-305)
FLASH POINT C(F): -104(-156) (ASTM D-93)
FLAMMABILITY (solids): NE
AUTO FLAMMABILITY C(F): 410(770)
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: > 1000.0
VAPOR DENSITY: 1.6
EVAPORATION RATE: NE
RELATIVE DENSITY, 15/4 C: 0.5
SOLUBILITY IN WATER: Negligible
PARTITION COEFFICIENT: NE
VISCOSITY AT 40 C, cSt: NA
VISCOSITY AT 100 C, cSt: NA
POUR POINT C(F): NA
FREEZING POINT C(F): NE
VOLATILE ORGANIC COMPOUND: NE
NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE
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10. STABILITY AND REACTIVITY
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STABILITY (THERMAL, LIGHT, ETC.): Stable.
CONDITIONS TO AVOID: Heat, sparks, flame and build up of static
electricity.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at
ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
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11. TOXICOLOGICAL DATA
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---ACUTE TOXICOLOGY---
ORAL TOXICITY (RATS): Not applicable
DERMAL TOXICITY (RABBITS): Not applicable
INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater
than 5 mg/l). ---Based on testing of similar products and/or the
components.
EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score:
0 or greater but 6 or less). ---Based on testing of similar
products and/or the components.
SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary
Irritation Index: 0.5 or less). ---Based on testing of similar
products and/or the components.
OTHER ACUTE TOXICITY DATA: This product is an asphyxiant. Simple
asphyxiants act by displacing oxygen in the lungs thereby
diminishing the supply of oxygen available to the blood and
tissues. Continued lack of oxygen may result in convulsions,
loss of consciousness and death. Since exercise increases the
tissue need for oxygen, symptoms will occur more quickly during
exertion in an oxygen-deficient environment. Oxygen in enclosed
spaces should be maintained at 21% by volume. In addition,
exposure to this product may cause a general central nervous
system (CNS) depression typical of anesthetic gases or
intoxicants.
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12. ECOLOGICAL INFORMATION
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ENVIRONMENTAL FATE AND EFFECTS:
ECOTOXICITY: This material is not expected to be harmful to aquatic
organisms.
MOBILITY: Highly volatile, will partition rapidly to air. In air,
these hydrocarbons are photodegraded.
PERSISTENCE AND DEGRADABILITY: Expected to degrade at a moderate rate
in air.
BIOACCUMULATIVE POTENTIAL: Not expected to bioconcentrate.
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13. DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL: Product is suitable for burning in an enclosed,
controlled burner for fuel value. Such burning may be limited
pursuant to the Resource Conservation and Recovery Act. In
addition, the product is suitable for processing by an approved
recycling facility or can be disposed of at an appropriate
government waste disposal facility. Use of these methods is
subject to user compliance with applicable laws and regulations
and consideration of product characteristics at time of disposal.
RCRA INFORMATION: Disposal of unused product may be subject to RCRA
regulations (40 CFR 261). Disposal of the used product may also
be regulated due to ignitability, corrosivity, reactivity, or
toxicity as determined by the Toxicity Characteristic Leaching
Procedure (TCLP).
FLASH: -104(-156) C(F)
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14. TRANSPORT INFORMATION
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USA DOT:
SHIPPING NAME: Petroleum Gases, Liquefied
HAZARD CLASS & DIV: 2.1
ID NUMBER: UN1075
ERG NUMBER: 115
PACKING GROUP: NA
STCC: 4905752
DANGEROUS WHEN WET: No
POISON: No
LABEL(s): Flammable Gas
PLACARD(s): Flammable Gas
PRODUCT RQ: NA
MARPOL III STATUS: NA
RID/ADR:
HAZARD CLASS: 2
PACKING GROUP: NA
LABEL: 3
DANGER NUMBER: 23
UN NUMBER: 1075
SHIPPING NAME: Petroleum Gases, Liquefied
REMARKS: NA
IMO:
HAZARD CLASS & DIV: 2.1
UN NUMBER: 1075
PACKING GROUP: NA
SHIPPING NAME: Petroleum Gases, Liquefied
LABEL(s): Flammable Gas
MARPOL III STATUS: NA
ICAO/IATA:
HAZARD CLASS & DIV: 2.1
ID/UN Number: 1075
PACKING GROUP: NA
SHIPPING NAME: Petroleum Gases, Liquefied
SUBSIDIARY RISK: NA
LABEL(s): Flammable Gas, Cargo Aircraft Only
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15. REGULATORY INFORMATION
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US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance
with OSHA 29 CFR 1910.1200 and determined to be hazardous.
EU Labeling: Product is dangerous as defined by the European Union
Dangerous Substances/Preparations Directives.
Symbol: F+ Extremely flammable.
Risk Phrase(s): R12.
Extremely flammable.
Safety Phrase(s): S9-16-33.
Keep container in a well-ventilated place. Keep away from sources
of ignition - No smoking. Take precautionary measures against
static discharges.
Governmental Inventory Status: All components comply with TSCA,
EINECS/ELINCS, and DSL.
U.S. Superfund Amendments and Reauthorization Act (SARA) Title III:
This product contains no "EXTREMELY HAZARDOUS SUBSTANCES".
SARA (311/312) REPORTABLE HAZARD CATEGORIES:
PRESSURE FIRE
This product contains the following SARA (313) Toxic Release
Chemicals:
CHEMICAL NAME CAS NUMBER CONC.
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PROPYLENE 115-07-1 <5%
The following product ingredients are cited on the lists below:
CHEMICAL NAME CAS NUMBER LIST CITATIONS
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PROPANE 74-98-6 1, 10, 19, 20, 21,
23, 24, 25, 26
BUTANE 106-97-8 1, 10, 18, 19, 20,
21, 23, 24, 25, 26
PROPYLENE 115-07-1 1, 18, 19, 20, 21,
23, 24, 25, 26
--- REGULATORY LISTS SEARCHED ---
1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK
2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293
3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK
4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK
5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK
26=RI RTK
Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive
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16. OTHER INFORMATION
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USE: FUEL
NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES
ARE NOT FORMULATED TO CONTAIN PCBS.
Health studies have shown that many hydrocarbons pose potential human
health risks which may vary from person to person. Information provided
on this MSDS reflects intended use. This product should not be used for
other applications. In any case, the following advice should be
considered:
INJECTION INJURY WARNING: If product is injected into or under the skin,
or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a
physician as a surgical emergency. Even though initial symptoms from
high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the
ultimate extent of injury.
Precautionary Label Text:
DANGER!
EXTREMELY FLAMMABLE LIQUID AND GAS UNDER PRESSURE. MAY CAUSE FLASH FIRE.
CONTACT WITH LIQUID CAN CAUSE FREEZE BURNS. EXPOSURE TO SUFFICIENTLY
HIGH CONCENTRATIONS MAY CAUSE GENERAL CENTRAL NERVOUS SYSTEM DEPRESSION
AND SUFFOCATION.
Keep away from heat, sparks, and flame. Avoid all personal contact.
Avoid breathing gas. Keep container closed. Use only with adequate
ventilation. Do not depend on odor to detect presence of gas.
FIRST AID: If inhaled, immediately remove from further exposure. Get
immediate medical assistance. Give supplemental oxygen, if available.
If breathing has stopped, assist ventilation with a mechanical device or
use mouth-to-mouth resuscitation. If frostbite occurs, immerse involved
area in warm water (between 100F/38C and 110F/43C) for 20 to 40 minutes.
Get medical attention.
Chemicals known to the State of California to cause cancer, birth
defects, or other reproductive harm are created by the combustion of this
product. Refer to product Material Safety Data Sheet for further safety
and health information.
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For Internal Use Only: MHC: NA NA 0* 0* 0*, MPPEC: DF, TRN:
230102-00, CMCS97: 97G421, REQ: HOUSTON GAS LIQUIDS, SAFE USE: F
EHS Approval Date: 23MAY2003
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SYNONYM TRADE NAMES:
COMMERCIAL GRADE PROPANE (COLORADO REFINING)
COMMERCIAL GRADE PROPANE (COLORADO REFINING)
PROPANE
PROPANE (VARIOUS)
PROPANE HD-5
PROPANE, HIGH PURITY
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Information given herein is offered in good faith as accurate, but
without guarantee. Conditions of use and suitability of the product for
particular uses are beyond our control; all risks of use of the product
are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL
WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE
USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a
recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling
procedures should be provided to handlers and users. Alteration of this
document is strictly prohibited. Except to the extent required by law,
republication or retransmission of this document, in whole or in part, is
not permitted. Exxon Mobil Corporation and its affiliated companies
assume no responsibility for accuracy of information unless the document
is the most current available from an official ExxonMobil distribution
system. Exxon Mobil Corporation and its affiliated companies neither
represent nor warrant that the format, content or product formulas
contained in this document comply with the laws of any other country
except the United States of America.
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Copyright 2001 Exxon Mobil Corporation, All rights reserved
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