LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Loctite(R) 680 Retaining Compound High Strength
68005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Loctite(R) 680 Retaining Compound High Strength
Item No.: 68005
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Aromatic dimethacrylate ester 24448-20-2 40-45
Hydroxyalkyl methacrylate 27813-02-1 30-35
Bisphenol A fumarate resin 39382-25-7 15-20
CUMENE HYDROPEROXIDE* 80-15-9 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
N,N-Dialkyltoluidines 613-48-9 0.1-1
MALEIC ACID 110-16-7 0.1-1
SACCHARIN 81-07-2 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Hydroxyalkyl methacrylate None None 3 ppm ceiling
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Severe eye irritant. Moderate skin irritant.
Possible inhalation irritant. May be harmful if
swallowed. May cause kidney or liver damage.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: May cause severe dermatitis on prolonged contact
in sensitive individuals.
Existing Conditions
Aggravated by Exposure: None known
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Loctite(R) 680 Retaining Compound High Strength
Item No.: 68005
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Aromatic dimethacrylate ester ALG IRR NO NO NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Bisphenol A fumarate resin ALG IRR NO NO NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
N,N-Dialkyltoluidines No Data NO NO NO
MALEIC ACID IRR NO NO NO
SACCHARIN No Data YES 2B NO
-------------------------------------------------------------------------------
Abbreviations
2B Possibly carcinogenic to humans ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant MUT Mutagen
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep indivudual calm.
Obtain medical attention.
Inhalation: Does not apply
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Loctite(R) 680 Retaining Compound High Strength
Item No.: 68005
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Maintain adequate ventilation.
Soak up in an inert absorbent. Store in partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100癋
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
Do not breath vapors.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Green Liquid
Odor: Mild
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.11 at 80癋
Volatile Organic Compound
(EPA Method 24) 38.4%; 426 grams per liter
Vapor Pressure: Less than 5mm at 80癋
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Loctite(R) 680 Retaining Compound High Strength
Item No.: 68005
11. TOXICOLOGICAL INFORMATION
Oral LD50 more than 10000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer
and birth defects or other reproductive
harm.
Propylene oxide
(ppb levels of Arsenic, Cd, Pb, Ni),
This product contains Saccharin. No Prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Loctite(R) 680 Retaining Compound High Strength
Item No.: 68005
16. OTHER INFORMATION (continued)
Estimated HMIS(R) Code:
Health Hazard: 1*
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: May 02, 1996 Revision: 0027
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