Material Safety Data Sheet
5-Chloro-2-nitrobenzotrifluoride, 99%
ACC# 16725 Section 1 - Chemical Product and Company Identification
MSDS Name: 5-Chloro-2-nitrobenzotrifluoride, 99%
Catalog Numbers: AC109710000, AC109710050, AC109710250
Synonyms: 5-Chloro-2-nitro-alpha1,alpha1,alpha1-trifluorotoluene
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS#Chemical NamePercentEINECS/ELINCS
118-79-62,4,6-Tribromophenol98.0 204-278-6
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: clear brown liquid.
Caution! Harmful. The toxicological properties of this material have not been
fully investigated.
Target Organs: None known.
Potential Health Effects
Eye: May cause eye irritation.
Skin: Harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. The toxicological properties of this substance
have not been fully investigated.
Inhalation: Harmful if inhaled. The toxicological properties of this substance
have not been fully investigated.
Chronic: Not available.
Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids.
Skin: Flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Will burn if involved in a fire.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical
foam.
Flash Point: 102 deg C ( 215.60 deg F)
Autoignition Temperature: > 450 deg C (> 842.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or
earth), then place in suitable container.
Section 7 - Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and
eyes. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower.
Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs
2,4,6-Tribromophenol none listed none listed none listed
OSHA Vacated PELs: 2,4,6-Tribromophenol: No OSHA Vacated PELs are listed for
this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear a chemical apron.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if irritation or other symptoms
are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Appearance: clear brown
Odor: Not available.
pH: Not available.
Vapor Pressure: 1.3 hPa @ 60 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 222 - 224 deg C @ 760.00mm Hg
Freezing/Melting Point:21 deg C
Decomposition Temperature:> 300 deg C
Solubility: IN WATER: 168 MG/L (20癈)
Specific Gravity/Density:1.5260g/cm3
Molecular Formula:C7H3ClF3NO2
Molecular Weight:225.55
Section 10 - Stability and Reactivity
Chemical Stability: Not available.
Conditions to Avoid: Not available.
Incompatibilities with Other Materials: Strong bases, strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon
monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 118-79-6: SN1225000
LD50/LC50:
CAS# 118-79-6:
Draize test, rabbit, eye: 100 mg Mild;
Inhalation, rat: LC50 = >1630 mg/m3/4H;
Oral, rat: LD50 = 200 mg/kg;
.
Carcinogenicity:
CAS# 118-79-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is
classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators
must consult state and local hazardous waste regulations to ensure complete and
accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOTCanada TDG
Shipping Name:DOT regulated - small quantity provisions apply (see
49CFR173.4)No information available.
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 118-79-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 118-79-6: Effective 1/11/90, Sunset 6/30/98
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 118-79-6: Section 4 (see 40 CFR 707.72)
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 118-79-6: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances
under the CWA.
None of the chemicals in this product are listed as Priority Pollutants
under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under
the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by
OSHA.
STATE
CAS# 118-79-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are
listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and gloves.
WGK (Water Danger/Protection)
CAS# 118-79-6: No information available.
Canada - DSL/NDSL
CAS# 118-79-6 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
MSDS Creation Date: 9/02/1997
Revision #4 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should
make their own investigations to determine the suitability of the information
for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if Fisher has been advised of the possibility of such damages.
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