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Section 1 - Chemical Product and Company Identification |
MSDS Name: o-Phthaloyl dichloride (pract), 97% (titr.)
Catalog Numbers:
AC417970000, AC417970030, AC417975000
Synonyms:
Phthaloyl chloride; 1,2-Benzenedicarbonyl dichloride.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 88-95-9 | 2-Phthaloyl dichloride |
95.0 | 201-869-0 |
Hazard Symbols: C
Risk Phrases: 34
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless to pale yellow liquid.
Moisture sensitive. Danger! Corrosive. Causes eye
and skin burns. May cause severe respiratory tract irritation with
possible burns. May cause severe digestive tract irritation with
possible burns.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Effects of contact may be delayed.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Effects of
inhalation may be delayed.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Discard contaminated clothing in a manner
which limits further exposure. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
Flash Point: > 230e deg F (> 110.00 deg C)
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating:
(estimated) Health: 3; Flammability: ; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Use
with adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 2-Phthaloyl dichloride | none listed |
none listed | none listed |
OSHA Vacated PELs:
2-Phthaloyl dichloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless to pale yellow
Odor: none reported
pH: Not available.
Vapor Pressure: 30 mmHg @ 47 C
Vapor Density: 7.00
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 269.0 - 271.0 deg C @ 760.00m
Freezing/Melting Point:12 deg C
Decomposition Temperature:Not available.
Solubility: decomposes in alcohol
Specific Gravity/Density:1.4090g/cm3
Molecular Formula:C8H4Cl2O2
Molecular Weight:203.02
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alcohols, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 88-95-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 88-95-9:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Neurotoxicity:
No information available.
Mutagenicity:
No information available.
Other Studies:
No data available.
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No information found.
Physical:
No information found.
Other:
No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
IATA |
RID/ADR |
IMO |
Canada TDG |
| Shipping Name: |
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. |
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CORROSIVE LIQUID ACIDIC ORGANIC (O-PHTHALOYL DICHLORIDE) |
| Hazard Class: |
8 |
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8 |
| UN Number: |
UN3265 |
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UN3265 |
| Packing Group: |
II |
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III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 88-95-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS# 88-95-9 is not present on state lists from CA, PA, MN, MA,
FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 88-95-9: No information available.
Canada - DSL/NDSL
CAS# 88-95-9 is listed on Canada's DSL List.
Canada - WHMIS
This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
Exposure Limits
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Section 16 - Additional Information
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MSDS Creation Date: 1/21/1999
Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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