Section 1 - Chemical Product and Company Identification |
MSDS Name: Sudan IV Solution Alcoholic
Catalog Numbers:
S80211-1
Synonyms:
Oil red
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
67-63-0 |
Isopropyl alcohol |
99.5 | 200-661-7 |
85-83-6 |
Sudan IV |
0.5 | 201-635-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: red liquid. Flash Point: 11.7 deg C.
Warning! Flammable liquid and
vapor. Causes respiratory tract irritation. May cause
severe eye irritation and possible injury. Causes skin irritation.
May cause digestive tract irritation with nausea, vomiting, and
diarrhea. May cause central nervous system depression. May form
explosive peroxides. May cause kidney damage.
Target Organs: Kidneys, central nervous system.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Prolonged and/or repeated
contact may cause defatting of the skin and dermatitis. May cause
irritation with pain and stinging, especially if the skin is abraded.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Inhalation of vapor may cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause kidney injury.
May cause allergic skin reaction in some
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool.
Containers may explode in the heat of a fire. This chemical poses an
explosion hazard. May form explosive peroxides. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective.
Flash Point: 11.7 deg C ( 53.06 deg F)
Autoignition Temperature: 398.9 deg C ( 750.02 deg F)
Explosion Limits, Lower:2 (2-propanol)
Upper: 12.7 (2-propano
NFPA Rating:
(estimated) Health: 1; Flammability: 4; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Use spark-proof
tools and explosion proof equipment. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Isopropyl alcohol
|
200 ppm TWA; 400 ppm STEL
|
400 ppm TWA; 980 mg/m3 TWA 2000 ppm IDLH
|
400 ppm TWA; 980 mg/m3 TWA
|
Sudan IV
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Isopropyl alcohol:
400 ppm TWA; 980 mg/m3 TWA
Sudan IV:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A NIOSH/MSHA approved or European Standard EN 149 air
purifying respirator with an organic vapor cartridge
or canister may be permissible under certain
circumstances where airborne concentrations are
expected. A respiratory protection program that meets
OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or
European Standard EN 149 must be followed whenever
workplace conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: red
Odor: pleasant odor
pH: Not available.
Vapor Pressure: 33 mm Hg @20 deg C
Vapor Density: Not available.
Evaporation Rate:>1.0 (ether=1)
Viscosity: Not available.
Boiling Point: 38.3 deg C
Freezing/Melting Point:-87.8 deg C
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:0.786
Molecular Formula:Mixture
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable. This material may be sensitive to peroxide formation.
Conditions to Avoid:
This material may be sensitive to peroxide formation., incompatible
materials, ignition sources.
Incompatibilities with Other Materials:
2-Propanol is incompatible with strong oxidizers, acetaldeyde,
chlorine, ethylene oxide, acids and isocyanates, hydrogen +
palladium, nitroform, oleum, phosgene, potassium t-butoxide, oxygen,
trinitromethane, barium perchlorate, tetrafluoroborate, chromium
trioxide, sodium dichromate + sulfuric acid, aluminum, and aluminum
triisopropoxide. It also is susceptible to autoxidation and should
therefore be considered peroxidizable.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 67-63-0:
NT8050000
CAS# 85-83-6:
QL5775000
LD50/LC50:
CAS# 67-63-0: Draize test, rabbit,
eye: 100 mg Severe; Draize test,
rabbit, eye: 10 mg Moderate;
Draize test, rabbit, eye: 100 mg/24H
Moderate; Draize test, rabbit,
skin: 500 mg Mild; Inhalation,
mouse: LC50 = 53000 mg/m3;
Inhalation, rat: LC50 = 16000
ppm/8H; Inhalation, rat: LC50 =
72600 mg/m3; Oral, mouse: LD50 =
3600 mg/kg; Oral, mouse: LD50 =
3600 mg/kg; Oral, rabbit: LD50 =
6410 mg/kg; Oral, rat: LD50 = 5045
mg/kg; Oral, rat: LD50 = 5000
mg/kg; Skin, rabbit: LD50 = 12800
CAS# 85-83-6: .
Carcinogenicity:
CAS# 67-63-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 85-83-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Early epidemiological studies suggested an association
between the strong acid manufacture of isopropyl alcohol
and paranasal sinus cancer in workers. The risk of
laryngeal cancer may also be increased in these workers.
However, it has not been tested adequately in animals to
assess its carcinogenicity.
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
Cas# 67-63-0:Cytogenetic analysis
(Inhalation,rat)=1030ug/m3/16W,(Intermittent)
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
Cas# 67-63-0:LC50 (96Hr.) Fathead Minnow = 94900-10400 mg/L;
Flow-through conditionLC50 (96 Hr.) Fathead Minnow = 61200-65500
mg/L;Flow-through condition.
Environmental:
Cas# 67-63-0: TERRESTRIAL FATE: When spilled on soil, isopropanol
will both evaporate quickly and leach into the ground due to its high
vapor pressure and low adsorption to soil. Degradation in soil and
groundwater has not been determined. If soil degradation is not
rapid, it is apt to leach into the groundwater. AQUATIC FATE: When
released into water, isopropyl alcohol will volatilize (estimated
half-life approximately 5.4 days) and may biodegrade. Although it is
readily degradable in a number of laboratory tests, no data on its
degradability in natural waters.
Physical:
Cas# 67-63-0: ATMOSPHERIC FATE: When released into the atmosphere,
isopropanol will photodegrade with an estimated half-life ranging
from one to several days. Due to its solubility in water, rainout
may be significant.
Other:
None
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
ALCOHOLS, N.O.S. |
No information available. |
Hazard Class: |
3 |
|
UN Number: |
UN1987 |
|
Packing Group: |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 85-83-6 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 67-63-0: Effective 12/15/86, Sunset 12/15/96
Chemical Test Rules
CAS# 67-63-0: 40 CFR 799.2325
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 67-63-0: immediate, delayed, fire.
CAS # 85-83-6: reactive.
Section 313
This material contains Isopropyl
alcohol (CAS# 67-63-0, 99.5%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 67-63-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 85-83-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37 Wear suitable protective clothing and gloves.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 85-83-6: 2
Canada - DSL/NDSL
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 85-83-6 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 10/16/1997 Revision #7 Date: 12/04/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
|
|