Analysis

Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
7732-18-5	Water	97.9	231-791-2
7697-37-2	Nitric acid	2	231-714-2
7440-50-8	Copper	0.1	231-159-6

Section 3 - Hazards Identification

Appearance: Clear liquid.
Danger! May cause severe eye irritation and possible injury. Causes skin and respiratory tract irritation. Corrosive to metal.
Target Organs: Eyes.


Potential Health Effects
Eye: May cause chemical conjunctivitis and corneal damage.
Skin: Causes skin irritation.
Ingestion: May cause irritation of the digestive tract.
Inhalation: Causes respiratory tract irritation.
Chronic: Exposure to high concentrations of nitric acid vapor may cause pneuomonitis and pulmonary edema which may be fatal. Symptoms may or may not be delayed. Continued exposure to the vapor & mist of nitric acid may result in a chronic bronchitis, & more severe exposure results in a chemical pneumonitis. The vapor & mists of nitric acid may erode the teeth, particularly affecting the canines & incisors.

Section 4 - First Aid Measures

Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Administration of Sodium bicarbonate may be of value to treat acidosis.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will react with water to form toxic and corrosive fumes. Vapors may accumulate in confined spaces Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media: For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. For small fires, use carbon dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - Handling and Storage

Handling: Use only in a well-ventilated area. Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store in a cool, dry area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Water	none listed	none listed	none listed
Nitric acid	2 ppm TWA; 4 ppm STEL	2 ppm TWA; 5 mg/m3 TWA 25 ppm IDLH	2 ppm TWA; 5 mg/m3 TWA
Copper	0.2 mg/m3 TWA (fume); 1 mg/m3 TWA (dust and mist, as Cu)	1 mg/m3 TWA (dust and mist) 100 mg/m3 IDLH (dust, fume and mist)	0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dust and mist)

OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Nitric acid: 2 ppm TWA; 5 mg/m3 TWA Copper: 0.1 mg/m3 TWA (fume, dusts, mists as Cu)
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: Clear
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: miscible
Specific Gravity/Density:Not available.
Molecular Formula:Solution
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases.
Hazardous Decomposition Products: Nitrogen oxides, oxides of copper.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 7732-18-5: ZC0110000      
CAS# 7697-37-2: QU5775000; QU5900000      
CAS# 7440-50-8: GL5325000; GL7440000; GL7590000
LD50/LC50:
CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 7697-37-2:
     Inhalation, rat: LC50 = 260 mg/m3/30M;
     Inhalation, rat: LC50 = 130 mg/m3/4H;
     Inhalation, rat: LC50 = 67 ppm(NO2)/4H;
.

CAS# 7440-50-8:
.

Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7697-37-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7440-50-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.	NITRIC ACID
Hazard Class:	8	8
UN Number:	UN3264	UN2031
Packing Group:	III	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 7697-37-2 is listed on the TSCA inventory.
     CAS# 7440-50-8 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ      CAS# 7440-50-8: 5000 lb final RQ (no reporting of releases of this hazardous substance is requir
SARA Section 302 Extremely Hazardous Substances
     CAS# 7697-37-2: 1000 lb TPQ
SARA Codes
     CAS # 7697-37-2: immediate, delayed, fire.
     CAS # 7440-50-8: immediate, delayed, fire.
Section 313
     This material contains Nitric acid (CAS# 7697-37-2, 2%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
     Copper is not at a high enough concentration to be reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7697-37-2 is listed as a Hazardous Substance under the CWA.      CAS# 7440-50-8 is listed as a Priority Pollutant under the Clean      Water Act. CAS# 7440-50-8 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     CAS# 7697-37-2 is considered highly hazardous by OSHA.
STATE
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 7697-37-2 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 7440-50-8 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:
     R 37/38 Irritating to respiratory system and skin.
     R 41 Risk of serious damage to eyes.

Safety Phrases:
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)
     CAS# 7732-18-5: No information available.
     CAS# 7697-37-2: 1
     CAS# 7440-50-8: 0
Canada - DSL/NDSL
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 7697-37-2 is listed on Canada's DSL List.
     CAS# 7440-50-8 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7697-37-2 is listed on the Canadian Ingredient Disclosure List.
     CAS# 7440-50-8 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #6 Date: 3/16/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.