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Section 1 - Chemical Product and Company Identification |
MSDS Name: N-Vinyl-2-pyrrolidinone, stabilized, 98%
Catalog Numbers:
AC140920000, AC140920010, AC140920050, AC140922500, AC140925000
Synonyms:
N-Vinylbutyrolactam; 1-Vinyl-2-pyrrolidone; 1-Vinyl-2-pyrrolidinone;
1-Ethenyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidinone;
N-Vinyl-2-pyrrolidone.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 88-12-0 |
N-vinyl-2-pyrrolidone |
98 | 201-800-4 |
| 1310-73-2 |
Sodium hydroxide |
0.1 | 215-185-5 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: yellow clear liquid.
Warning! Causes severe eye irritation and possible
eye injury. Harmful if absorbed through the skin. Causes respiratory
tract irritation. May be harmful if inhaled. May be harmful if
swallowed.
Target Organs: Liver, eyes.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause nausea and
vomiting. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled. May
cause headache. Inhalation of vapors will cause coughing or
breathing difficulty.
Chronic:
Chronic exposure may cause liver damage. Chronic exposure may cause
lung damage.
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Section 4 - First Aid Measures
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Polymerizes readily if not inhibited; heat can initiate reaction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 95 deg C ( 203.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid breathing
vapor or mist. Do not get in eyes. Avoid contact with skin and
clothing.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store at
around 20癈.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| N-vinyl-2-pyrrolidone
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0.05 ppm TWA
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none listed
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none listed
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| Sodium hydroxide
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2 mg/m3 Ceiling
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10 mg/m3 IDLH
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2 mg/m3 TWA
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OSHA Vacated PELs:
N-vinyl-2-pyrrolidone:
No OSHA Vacated PELs are listed for this chemical.
Sodium hydroxide:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Clear liquid
Appearance: colorless - yellow
Odor: characteristic odor
pH: 9-10(100g/l aq.sol.)
Vapor Pressure: 0.114 mm Hg @ 25 deg C
Vapor Density: 3.8 (air=1)
Evaporation Rate:Not available.
Viscosity: 2.4 mPa.s@ 20 deg C
Boiling Point: 90-92 deg C @ 13 mm Hg
Freezing/Melting Point:13-14 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.0430g/cm3
Molecular Formula:C6H9NO
Molecular Weight:111.14
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Section 10 - Stability and Reactivity
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Chemical Stability:
Becomes yellow over time. This material is a monomer and may
polymerize under certain conditions if the stabilizer is lost.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, polymerizing initiators.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 88-12-0:
UY6107000
CAS# 1310-73-2:
WB4900000
LD50/LC50:
CAS# 88-12-0:
Draize test, rabbit,
eye: 100 mg Severe;
Inhalation,
rat: LC50 = 3200 mg/m3/4H;
Oral,
rat: LD50 = 1470 mg/kg;
Skin,
rabbit: LD50 = 560 mg/kg;
.
CAS# 1310-73-2:
Draize test,
rabbit, eye: 400 ug Mild;
Draize
test, rabbit, eye: 1% Severe;
Draize test, rabbit, eye: 50 ug/24H
Severe;
Draize test, rabbit, eye:
1 mg/24H Severe;
Draize test,
rabbit, skin: 500 mg/24H Severe;
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Carcinogenicity:
CAS# 88-12-0:
- ACGIH:
A3 - Confirmed animal carcinogen with unknown relevance to humans
- California:
Not listed.
- NTP:
Not listed.
- IARC:
Not listed.
CAS# 1310-73-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
Log Pow 0.4
Environmental:
No information available.
Physical:
No information available.
Other:
Biodegradable.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
TOXIC LIQUIDS, ORGANIC, N.O.S. |
TOXIC LIQUID ORGANIC NOS (N-VINYL-2-PYRROLIDINONE) |
| Hazard Class: |
6.1 |
6.1 |
| UN Number: |
UN2810 |
UN2810 |
| Packing Group: |
III |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 88-12-0 is listed on the TSCA inventory.
CAS# 1310-73-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 88-12-0: immediate, reactive.
CAS # 1310-73-2: immediate, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-73-2 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 88-12-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 1310-73-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 37 Irritating to respiratory system.
R 40 Limited evidence of a carcinogenic effect.
R 41 Risk of serious damage to eyes.
R 48/20 Harmful : danger of serious damage to health by prolonged
exposure through inhalation.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
WGK (Water Danger/Protection)
CAS# 88-12-0: 3
CAS# 1310-73-2: 1
Canada - DSL/NDSL
CAS# 88-12-0 is listed on Canada's DSL List.
CAS# 1310-73-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 88-12-0 is listed on the Canadian Ingredient Disclosure List.
CAS# 1310-73-2 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 8/21/1998
Revision #5 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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