Analysis

Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
64-17-5	Ethyl alcohol	48.0	200-578-6
67-56-1	Methyl alcohol	29.0	200-659-6
107-21-1	Ethylene glycol	9.3	203-473-3
7732-18-5	Water	7.8	231-791-2
67-63-0	Isopropyl alcohol	2.9	200-661-7
64-19-7	Acetic acid, glacial	2.2	200-580-7
12067-99-1	Phosphotungstic acid anhydrous	0.5	235-087-6
17372-87-1	Eosin Y	0.5	241-409-6
5141-20-8	Light green SF Yellowish	0.04	225-906-5

Section 3 - Hazards Identification

Appearance: not available liquid. Flash Point: 16.1 deg C.
Danger! Poison! Vapor harmful. May be fatal or cause blindness if swallowed. Flammable liquid and vapor. Causes eye irritation. May cause allergic skin reaction. May be absorbed through intact skin. May cause skin irritation. May cause respiratory tract irritation. May cause central nervous system depression. May form explosive peroxides. May cause blindness. May cause liver and kidney damage. May cause reproductive and fetal effects. Cannot be made non-poisonous.
Target Organs: Kidneys, central nervous system, liver, eyes.


Potential Health Effects
Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. May cause painful sensitization to light. Vapors may cause eye irritation.
Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin.
Ingestion: May be fatal or cause blindness if swallowed. May cause irritation of the digestive tract. May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May cause visual impairment and possible permanent blindness. May cause effects similar to those described for ingestion. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air. Containers may explode when heated.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: 16.1 deg C ( 60.98 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 1

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Ethyl alcohol	1000 ppm TWA	1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm IDLH	1000 ppm TWA; 1900 mg/m3 TWA
Methyl alcohol	200 ppm TWA; 250 ppm STEL; Skin - potential significant contribution to overall exposure by the cutaneous r oute	200 ppm TWA; 260 mg/m3 TWA 6000 ppm IDLH	200 ppm TWA; 260 mg/m3 TWA
Ethylene glycol	100 mg/m3 Ceiling (aerosol only)	none listed	none listed
Water	none listed	none listed	none listed
Isopropyl alcohol	200 ppm TWA; 400 ppm STEL	400 ppm TWA; 980 mg/m3 TWA 2000 ppm IDLH	400 ppm TWA; 980 mg/m3 TWA
Acetic acid, glacial	10 ppm TWA; 15 ppm STEL	10 ppm TWA; 25 mg/m3 TWA 50 ppm IDLH	10 ppm TWA; 25 mg/m3 TWA
Phosphotungstic acid anhydrous	1 mg/m3 TWA (as W) (listed under Tungsten, soluble compounds).3 mg/m3 STEL (as W) (listed under Tungsten, soluble compounds).	1 mg/m3 TWA (as W) (listed under Tungsten, soluble compounds).	none listed
Eosin Y	none listed	none listed	none listed
Light green SF Yellowish	none listed	none listed	none listed

OSHA Vacated PELs: Ethyl alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA Ethylene glycol: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical. Isopropyl alcohol: 400 ppm TWA; 980 mg/m3 TWA Acetic acid, glacial: 10 ppm TWA; 25 mg/m3 TWA Phosphotungstic acid anhydrous: No OSHA Vacated PELs are listed for this chemical. Eosin Y: No OSHA Vacated PELs are listed for this chemical. Light green SF Yellowish: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: not available
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: > 63.9 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable. Stable under normal temperatures and pressures. This material may be sensitive to peroxide formation.
Conditions to Avoid: High temperatures, high temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials: Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), caustics (e.g. ammonia, ammonium hydrozide, calcium hydroxide, potassium hydroxide, sodium hydroxide), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), fluorides (inorganic, e.g. ammonium fluoride, calcium fluoride, cesium fluoride), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, s.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, formaldehyde.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 64-17-5: KQ6300000      
CAS# 67-56-1: PC1400000      
CAS# 107-21-1: KW2975000      
CAS# 7732-18-5: ZC0110000      
CAS# 67-63-0: NT8050000      
CAS# 64-19-7: AF1225000      
CAS# 12067-99-1: TH5650000      
CAS# 17372-87-1: LM5850000      
CAS# 5141-20-8: BQ4900000
LD50/LC50:
CAS# 64-17-5:
     Draize test, rabbit, eye: 500 mg Severe;
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Inhalation, mouse: LC50 = 39 gm/m3/4H;
     Inhalation, rat: LC50 = 20000 ppm/10H;
     Oral, mouse: LD50 = 3450 mg/kg;
     Oral, rabbit: LD50 = 6300 mg/kg;
     Oral, rat: LD50 = 7060 mg/kg;
     Oral, rat: LD50 = 9000 mg/kg;
.

CAS# 67-56-1:
     Draize test, rabbit, eye: 40 mg Moderate;
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
     Inhalation, rat: LC50 = 64000 ppm/4H;
     Oral, mouse: LD50 = 7300 mg/kg;
     Oral, rabbit: LD50 = 14200 mg/kg;
     Oral, rat: LD50 = 5600 mg/kg;
     Skin, rabbit: LD50 = 15800 mg/kg;
.

CAS# 107-21-1:
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, eye: 100 mg/1H Mild;
     Draize test, rabbit, eye: 0.012 ppm/3D;
     Draize test, rabbit, eye: 1440 mg/6H Moderate;
     Oral, mouse: LD50 = 5500 mg/kg;
     Oral, rat: LD50 = 4700 mg/kg;
     Skin, rabbit: LD50 = 9530 uL/kg;
.

CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 67-63-0:
     Draize test, rabbit, eye: 100 mg Severe;
     Draize test, rabbit, eye: 10 mg Moderate;
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 500 mg Mild;
     Inhalation, mouse: LC50 = 53000 mg/m3;
     Inhalation, rat: LC50 = 16000 ppm/8H;
     Inhalation, rat: LC50 = 72600 mg/m3;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, mouse: LD50 = 3600 mg/kg;
     Oral, rabbit: LD50 = 6410 mg/kg;
     Oral, rat: LD50 = 5045 mg/kg;
     Oral, rat: LD50 = 5000 mg/kg;
     Skin, rabbit: LD50 = 12800
CAS# 64-19-7:
     Draize test, rabbit, skin: 50 mg/24H Mild;
     Inhalation, mouse: LC50 = 5620 ppm/1H;
     Oral, rat: LD50 = 3310 mg/kg;
     Skin, rabbit: LD50 = 1060 uL/kg;
.

CAS# 12067-99-1:
     Oral, rat: LD50 = 3300 mg/kg;
.

CAS# 17372-87-1:
     Oral, mouse: LD50 = 2344 mg/kg;
.

CAS# 5141-20-8:
     Oral, rat: LD50 = >2 gm/kg;
.

Carcinogenicity:
CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 107-21-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 67-63-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 64-19-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 12067-99-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 17372-87-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 5141-20-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Ethanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals.Methanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. Specific developmental abnormalities include cardiovascular, musculoskeletal, and urogenital systems.Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have collectively been termed the "fetal alcohol syndrome".Experimental teratogenic and reproductive effects have been reported for isopropanol.Early epidemiological studies have suggested an association between the strong acid manufacture of isopropyl alcohol and paranasal sinus cancer in workers.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3癈Fish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum: EC50 = 34900 mg/L; 5-30 min; Microtox test No data available.
Environmental: No information reported.
Physical: No information available.
Other: None.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 67-56-1: waste number U154 (Ignitable waste).

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	ALCOHOLS, N.O.S.	No information available.
Hazard Class:	3
UN Number:	UN1987
Packing Group:	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 64-17-5 is listed on the TSCA inventory.
     CAS# 67-56-1 is listed on the TSCA inventory.
     CAS# 107-21-1 is listed on the TSCA inventory.
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 67-63-0 is listed on the TSCA inventory.
     CAS# 64-19-7 is listed on the TSCA inventory.
     CAS# 12067-99-1 is listed on the TSCA inventory.
     CAS# 17372-87-1 is listed on the TSCA inventory.
     CAS# 5141-20-8 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 67-63-0: Effective 12/15/86, Sunset 12/15/96
Chemical Test Rules
     CAS# 67-63-0: 40 CFR 799.2325
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ      CAS# 107-21-1: 5000 lb final RQ; 2270 kg final RQ      CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 64-17-5: immediate, delayed, fire.
     CAS # 67-56-1: immediate, fire.
     CAS # 107-21-1: immediate, delayed.
     CAS # 67-63-0: immediate, delayed, fire.
     CAS # 64-19-7: immediate, delayed, fire.
     CAS # 12067-99-1: immediate, fire.
     CAS # 17372-87-1: immediate.
Section 313
     This material contains Methyl alcohol (CAS# 67-56-1, 29.0%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
     This material contains Ethylene glycol (CAS# 107-21-1, 9.3%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
     This material contains Isopropyl alcohol (CAS# 67-63-0, 2.9%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 67-56-1 is listed as a hazardous air pollutant (HAP).
     CAS# 107-21-1 is listed as a hazardous air pollutant (HAP).






     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 64-19-7 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 107-21-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 67-63-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 64-19-7 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 12067-99-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 17372-87-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 5141-20-8 can be found on the following state right to know lists: California.

California Prop 65
WARNING: This product contains Ethyl alcohol, a chemical known to the state of California to cause developmental reproductive toxicity.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     F
Risk Phrases:
     R 11 Highly flammable.
     R 23/25 Toxic by inhalation and if swallowed.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 2 Keep out of reach of children.
     S 24 Avoid contact with skin.
     S 7 Keep container tightly closed.

WGK (Water Danger/Protection)
     CAS# 64-17-5: 0
     CAS# 67-56-1: 1
     CAS# 107-21-1: 0
     CAS# 7732-18-5: No information available.
     CAS# 67-63-0: 1
     CAS# 64-19-7: 1
     CAS# 12067-99-1: No information available.
     CAS# 17372-87-1: 1
     CAS# 5141-20-8: No information available.
Canada - DSL/NDSL
     CAS# 64-17-5 is listed on Canada's DSL List.
     CAS# 67-56-1 is listed on Canada's DSL List.
     CAS# 107-21-1 is listed on Canada's DSL List.
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 67-63-0 is listed on Canada's DSL List.
     CAS# 64-19-7 is listed on Canada's DSL List.
     CAS# 12067-99-1 is listed on Canada's DSL List.
     CAS# 17372-87-1 is listed on Canada's DSL List.
     CAS# 5141-20-8 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List.
     CAS# 67-56-1 is listed on the Canadian Ingredient Disclosure List.
     CAS# 107-21-1 is listed on the Canadian Ingredient Disclosure List.
     CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List.
     CAS# 64-19-7 is listed on the Canadian Ingredient Disclosure List.
     CAS# 12067-99-1 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 4/13/1998
Revision #5 Date: 10/29/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.