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Section 1 - Chemical Product and Company Identification |
MSDS Name: Cal-Ex Decalcifier
Catalog Numbers:
CS510-10D, CS510-1D
Synonyms:
None
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7732-18-5 |
Water |
94.38 | 231-791-2 |
| 7647-01-0 |
Hydrogen chloride |
5.5 | 231-595-7 |
| 6381-92-6 |
Disodium ethylenediaminetetraacetate dihydrate |
0.12 | unlisted |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: not available liquid.
Danger! Causes eye burns. Causes digestive tract
burns. Causes skin burns. Causes respiratory tract burns. May cause
fetal effects based upon animal studies.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract.
Inhalation:
Effects may be delayed. May cause irritation of the respiratory
tract with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure
may cause erosion of teeth.
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Section 4 - First Aid Measures
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Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Wear appropriate protective
clothing to prevent contact with skin and eyes. Wear a
self-contained breathing apparatus (SCBA) to prevent contact with
thermal decomposition products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Neutralize
spill with sodium bicarbonate.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get on skin
or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Water
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none listed
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none listed
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none listed
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| Hydrogen chloride
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2 ppm Ceiling
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50 ppm IDLH
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5 ppm Ceiling; 7 mg/m3 Ceiling
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| Disodium ethylenediaminetetraacetate dihydrate
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Hydrogen chloride:
No OSHA Vacated PELs are listed for this chemical.
Disodium ethylenediaminetetraacetate dihydrate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: not available
Odor: none reported
pH: Acidic
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 7647-01-0:
MW4025000; MW4031000
CAS# 6381-92-6:
AH4410000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 7647-01-0:
Inhalation,
mouse: LC50 = 1108 ppm/1H;
Inhalation, mouse: LC50 = 20487
mg/m3/5M;
Inhalation, mouse: LC50 =
3940 mg/m3/30M;
Inhalation, mouse:
LC50 = 8300 mg/m3/30M;
Inhalation,
rat: LC50 = 3124 ppm/1H;
Inhalation, rat: LC50 = 60938
mg/m3/5M;
Inhalation, rat: LC50 =
7004 mg/m3/30M;
Inhalation, rat:
LC50 = 45000 mg/m3/5M;
Inhalation,
rat: LC50 = 8300 mg/m3/30M;
Oral,
rabbit: LD50 = 900 mg/kg;
.
CAS# 6381-92-6:
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7647-01-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 6381-92-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
Hydrogen chloride has caused teratogenic effects in
animals.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No information reported.
Physical:
No information available.
Other:
None.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
HYDROCHLORIC ACID |
No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN1789 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 6381-92-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7647-01-0: 500 lb TPQ (gas only)
SARA Codes
CAS # 7647-01-0: immediate.
CAS # 6381-92-6: immediate.
Section 313
This material contains Hydrogen
chloride (CAS# 7647-01-0, 5.5%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 7647-01-0 is considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7647-01-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 6381-92-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7647-01-0: 1
CAS# 6381-92-6: 2
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 6381-92-6 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7647-01-0 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #5 Date: 11/07/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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