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Section 1 - Chemical Product and Company Identification |
MSDS Name: Dipentylamine, 99%
Catalog Numbers:
AC219360100, AC219362500
Synonyms:
Diamylamine; 1-Pentanamine, N-pentyl-; Di-n-amylamine; a secondary
amine.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 2050-92-2 |
Dipentylamine |
99 | 218-108-3 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid.
Danger! May be fatal if inhaled. Causes burns by
all exposure routes. Flammable liquid and vapor.
Harmful if swallowed or absorbed through the skin.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns. Vapor or mist may cause irritation and severe
burns. May cause blindness. Low vapor concentrations may cause a
temporary visual disturbance known as 'blue haze' or 'halo vision'.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
No skin allergy was observed in guinea pigs following repeated skin
application. (Atofina Chemicals)
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
May be fatal if inhaled. May cause severe irritation of the
respiratory tract with possible burns.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During
a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Flammable liquid and vapor. Vapors are heavier than
air and may travel to a source of ignition and flash back. Vapors
can spread along the ground and collect in low or confined areas.
This liquid floats on water and may travel to a source of ignition
and spread fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: 51-67 deg C
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 4; Flammability: 2; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Evacuate unnecessary personnel. Approach spill from upwind.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Do not breathe vapor or mist. Use only with adequate
ventilation or respiratory protection.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Dipentylamine
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Dipentylamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: amine-like
pH: Not available.
Vapor Pressure: 3 mm Hg
Vapor Density: 5.4 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 202 deg C @ 760 mm Hg
Freezing/Melting Point:-7.85 deg C
Decomposition Temperature:Not available.
Solubility: Negligible.
Specific Gravity/Density:0.7770 g/ml
Molecular Formula:C10H23N
Molecular Weight:157.30
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures. Amines absorb carbon
dioxide from the air to form carbamate salts.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 2050-92-2:
RZ9100000
LD50/LC50:
CAS# 2050-92-2:
Oral, rat: LD50 =
270 mg/kg;
Skin, rabbit: LD50 =
350 uL/kg;
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Inhalation, rat: LC50 = 66 ppm/4H (Elf Atochem). After testing,
researchers at Elf Atochem concluded that di-amylamine is corrosive
to rabbit skin at 3-minute, 1-hour and 2-hour long exposures.(See
TSCATS)
Carcinogenicity:
CAS# 2050-92-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
Substance has low to slight mobility in soil. Preferrentially adsorbs
to less saturated materials. May volatilize from moist soil surfaces.
May volatilize slowly from water. Binds strongly to particulates and
sediment. May bioconcentrate in aquatic organisms. Exists mainly in
the vapor phase in the ambient atmosphere. Will degrade by reaction
with photochemically produced hydroxyl radicals.
Physical:
Volatilization from model river: half-life = 9 hours; from model
lake: half-life = 6-7 days. Degradation in the atmosphere: half-life
= 4 hours.
Other:
No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. |
Toxic By Inhalation Liquid, Corrosive, N |
| Hazard Class: |
6.1 |
6.1(6.1) |
| UN Number: |
UN3390 |
UN3390 |
| Packing Group: |
I |
I |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 2050-92-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 2050-92-2: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 2050-92-2 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T C
Risk Phrases:
R 10 Flammable.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 24/25 Toxic in contact with skin and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 2050-92-2: No information available.
Canada - DSL/NDSL
CAS# 2050-92-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, D1A, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 2050-92-2 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #10 Date: 8/23/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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