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Section 1 - Chemical Product and Company Identification |
MSDS Name: N-Methyl-1,3-propanediamine, 99%
Catalog Numbers:
AC155570000, AC155570010, AC155572500
Synonyms:
3-(Methylamino)propylamine
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 6291-84-5 |
N-Methyl-1,3-propanediamine |
99 | 228-544-6 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear slightly yellow clear liquid. Flash Point: 35 deg C.
Danger! Corrosive. Causes eye and skin burns. May
cause severe respiratory tract irritation with possible burns. May
cause severe digestive tract irritation with possible burns.
Target Organs: None, none known.
Potential Health Effects
Eye:
Causes eye burns. Contact with eyes may cause severe irritation,
and possible eye burns. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin burns. May cause severe irritation and possible burns.
May cause skin rash (in milder cases), and cold and clammy skin with
cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed. Extensiv
e irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before
reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
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Section 7 - Handling and Storage
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Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Discard contaminated
shoes.
Storage:
Keep container closed when not in use. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| N-Methyl-1,3-propanediamine
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
N-Methyl-1,3-propanediamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible. Wear appropriate protective eyeglasses or
chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
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Section 9 - Physical and Chemical Properties
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Physical State: Clear liquid
Appearance: clear slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 139.0 - 141.0 deg C @ 760.00m
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:.8440g/cm3
Molecular Formula:C4H12N2
Molecular Weight:88.15
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen gas.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 6291-84-5:
TX8242500
LD50/LC50:
CAS# 6291-84-5:
Inhalation, rat:
LC50 = >189 mg/m3/6H;
Oral, mouse:
LD50 = 282 mg/kg;
Oral, rat: LD50
= 951 mg/kg;
.
Carcinogenicity:
CAS# 6291-84-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
TOXIC LIQUIDS, CORROSIVE, ORGANIC, N.O.S. |
No information available. |
| Hazard Class: |
6.1 |
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| UN Number: |
UN2927 |
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| Packing Group: |
I |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 6291-84-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 6291-84-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 6291-84-5: 1
Canada - DSL/NDSL
CAS# 6291-84-5 is listed on Canada's NDSL List.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #6 Date: 3/26/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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