MSDS PAGE: CAS N/A MSDS AAA11416-06.asp

MSDS		Material Safety Data Sheet

CAS		N/A

File Name	:	AAA11416-06.asp

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

Material Safety Data Sheet

acc. to OSHA and ANSI

Printing date 02/03/2003 Reviewed on 10/30/2002

�? 1 Identification of substance:

�? Product details:

�? Product name: 2−Bromo�?5−nitrobenzotrifluoride

�? Stock number: A11416

�? Manufacturer/Supplier:

Alfa Aesar, A Johnson Matthey Company

Johnson Matthey Catalog Company, Inc.

30 Bond Street

Ward Hill, MA 01835�?8099

Emergency Phone: (978) 521�?6300

CHEMTREC: (800) 424�?9300

Web Site: www.alfa.com

�? Information Department: Health, Safety and Environmental

Department

�? Emergency information:

During normal hours the Health, Safety and Environmental Department.

After normal hours call Chemtrec at (800) 424�?9300.

�? 2 Composition/Data on components:

�? Chemical characterization:

Description: (CAS#)

Material Safety Data Sheet 1

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

2−Bromo�?5−nitrobenzotrifluoride (CAS# 367�?67�?9): 100%

�? 3 Hazards identification

�? Hazard description: Xi Irritant

�? Information pertaining to particular dangers for man and

environment

R 36/37/38 Irritating to eyes, respiratory system and skin.

�? Classification system

�? HMIS ratings (scale 0�?4)

(Hazardous Materials Identification System)

Health (acute effects) = 1

Flammability = 1

Reactivity = 1

�? 4 First aid measures

�? After inhalation

Supply fresh air. If required, provide artificial respiration.

Keep patient warm.

Seek immediate medical advice.

�? After skin contact

Immediately wash with water and soap and rinse thoroughly.

Seek immediate medical advice.

�? After eye contact

Rinse opened eye for several minutes under running water. Then

consult a doctor.

�? After swallowing Seek immediate medical advice.

�? 5 Fire fighting measures

�? Suitable extinguishing agents

Carbon dioxide, extinguishing powder or water spray. Fight

Material Safety Data Sheet 2

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

larger fires with water spray or alcohol resistant foam.

�? Special hazards caused by the material, its products of

combustion or

resulting gases:

In case of fire, the following can be released:

Carbon monoxide and carbon dioxide

Nitrogen oxides (NOx)

Hydrogen bromide (HBr)

Hydrogen fluoride (HF)

�? Protective equipment:

Wear self−contained respirator.

Wear fully protective impervious suit.

�? 6 Accidental release measures

�? Person−related safety precautions:

Wear protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

�? Measures for environmental protection:

Do not allow material to be released to the environment

without proper governmental permits.

�? Measures for cleaning/collecting: Ensure adequate ventilation.

�? Additional information:

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

�? 7 Handling and storage

�? Handling

�? Information for safe handling:

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Material Safety Data Sheet 3

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

Ensure good ventilation at the workplace.

�? Information about protection against explosions and fires:

Keep ignition sources away.

�? Storage

�? Requirements to be met by storerooms and receptacles:

No special requirements.

�? Information about storage in one common storage facility:

Store away from oxidizing agents.

�? Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well sealed containers.

�? 8 Exposure controls and personal protection

�? Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous

chemicals and having an average face velocity of at least 100

feet per minute.

Components with limit values that require monitoring at the

workplace:

Not required.

�? Additional information: No data

�? Personal protective equipment

�? General protective and hygienic measures

The usual precautionary measures for handling chemicals should

be followed.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Material Safety Data Sheet 4

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

Avoid contact with the eyes and skin.

�? Breathing equipment:

Use suitable respirator when high concentrations are present.

�? Protection of hands:

Impervious gloves

Check protective gloves prior to each use for their proper

condition.

�? Material of gloves

The selection of suitable gloves not only depends on the

material, but also on quality. Quality will vary from

manufacturer to manufacturer.

�? Eye protection: Safety glasses

�? Body protection: Protective work clothing.

�? 9 Physical and chemical properties:

�? General Information

�? Form:

Crystalline

Solid

�? Color: Off−white

�? Odor: Not determined

�? Value/Range Unit

Method

�? Change in condition

�? Melting point/Melting range: 46�?48 ° C

�? Boiling point/Boiling range: 87�?88 ° C 3mm

Material Safety Data Sheet 5

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

�? Sublimation temperature / start: Not determined

�? Flash point: > 110 ° C

�? Ignition temperature: Not determined

�? Decomposition temperature: Not determined

�? Danger of explosion:

Product does not present an explosion hazard.

�? Explosion limits:

�? Lower: Not determined

�? Upper: Not determined

�? Vapor pressure: Not determined

�? Density: Not determined

�? Solubility in / Miscibility with

�? Water: Not determined

�? 10 Stability and reactivity

�? Thermal decomposition / conditions to be avoided:

Material Safety Data Sheet 6

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

Decomposition will not occur if used and stored according to

specifications.

�? Materials to be avoided: Oxidizing agents

�? Dangerous reactions No dangerous reactions known

�? Dangerous products of decomposition:

Carbon monoxide and carbon dioxide

Nitrogen oxides

Hydrogen bromide

Hydrogen fluoride

�? 11 Toxicological information

�? Acute toxicity:

�? Primary irritant effect:

�? on the skin: Irritant to skin and mucous membranes.

�? on the eye: Irritating effect.

�? Sensitization: No sensitizing effects known.

�? Subacute to chronic toxicity:

Other than potential irritation (see above), no information on

illness or injury from acute or chronic exposure to this

product is available.

�? Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this

substance is not fully known.

No classification data on carcinogenic properties of this material is

available from the EPA, IARC, NTP, OSHA or ACGIH.

�? 12 Ecological information:

Material Safety Data Sheet 7

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

�? General notes:

Do not allow material to be released to the environment without proper

governmental permits.

�? 13 Disposal considerations

�? Product:

�? Recommendation

Consult state, local or national regulations to ensure proper

disposal.

�? Uncleaned packagings:

�? Recommendation:

Disposal must be made according to official regulations.

�? 14 Transport information

Not a hazardous material for transportation.

�? DOT regulations:

�? Hazard class: None

�? Land transport ADR/RID (cross−border)

�? ADR/RID class: None

�? Maritime transport IMDG:

�? IMDG Class: None

Material Safety Data Sheet 8

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

�? Air transport ICAO−TI and IATA−DGR:

�? ICAO/IATA Class: None

�? Transport/Additional information:

Not dangerous according to the above specifications.

�? 15 Regulations

�? Product related hazard informations:

�? Hazard symbols: Xi Irritant

�? Risk phrases:

36/37/38 Irritating to eyes, respiratory system and skin.

�? Safety phrases:

26 In case of contact with eyes, rinse immediately with

plenty of water and seek medical advice.

37 Wear suitable gloves.

�? National regulations

This product is not listed in the U.S. Environmental

Protection Agency Toxic Substances Control Act Chemical

Substance Inventory. Use of this product is restricted to

research and development only.

�? Information about limitation of use:

For use only by technically qualified individuals.

Material Safety Data Sheet 9

A11416 �? 2−Bromo�?5−nitrobenzotrifluoride

�? 16 Other information:

Employers should use this information only as a supplement to

other information gathered by them, and should make

independent judgement of suitability of this information to

ensure proper use and protect the health and safety of

employees. This information is furnished without warranty,

and any use of the product not in conformance with this

Material Safety Data Sheet, or in combination with any other

product or process, is the responsibility of the user.

�? Department issuing MSDS: Health, Safety and Environmental

Department.

�? Contact: Darrell R. Sanders

Material Safety Data Sheet 10

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