A11407 鈭? Bromobenzene
Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/14/2003 Reviewed on 03/20/2003
鈥? 1 Identification of substance:
鈾? Product details:
鈾? Product name: Bromobenzene
鈾? Stock number: A11407
鈾? Manufacturer/Supplier:
Alfa Aesar, A Johnson Matthey Company
Johnson Matthey Catalog Company, Inc.
30 Bond Street
Ward Hill, MA 01835鈭?8099
Emergency Phone: (978) 521鈭?6300
CHEMTREC: (800) 424鈭?9300
Web Site: www.alfa.com
鈾? Information Department: Health, Safety and Environmental
Department
鈾? Emergency information:
During normal hours the Health, Safety and Environmental Department.
After normal hours call Chemtrec at (800) 424鈭?9300.
鈥? 2 Composition/Data on components:
鈾? Chemical characterization:
Description: (CAS#)
Material Safety Data Sheet 1
A11407 鈭? Bromobenzene
Bromobenzene (CAS# 108鈭?86鈭?1), 100%
鈾? Identification number(s):
鈾? EINECS Number: 203鈭?623鈭?8
鈾? EU Number: 602鈭?060鈭?00鈭?9
鈥? 3 Hazards identification
鈾? Hazard description:
Xi Irritant
N Dangerous for the environment
鈾? Information pertaining to particular dangers for man and
environment
R 10 Flammable.
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause long鈭抰erm
adverse effects in the aquatic environment
鈾? Classification system
鈾? HMIS ratings (scale 0鈭?4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 2
Reactivity = 1
鈥? 4 First aid measures
鈾? After inhalation
Supply fresh air. If required, provide artificial respiration.
Keep patient warm.
Seek immediate medical advice.
鈾? After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
Material Safety Data Sheet 2
A11407 鈭? Bromobenzene
鈾? After eye contact
Rinse opened eye for several minutes under running water. Then
consult a doctor.
鈾? After swallowing Seek immediate medical advice.
鈥? 5 Fire fighting measures
鈾? Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight
larger fires with water spray or alcohol resistant foam.
鈾? Special hazards caused by the material, its products of
combustion or
resulting gases:
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Hydrogen bromide (HBr)
鈾? Protective equipment:
Wear self鈭抍ontained respirator.
Wear fully protective impervious suit.
鈥? 6 Accidental release measures
鈾? Person鈭抮elated safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
鈾? Measures for environmental protection:
Do not allow material to be released to the environment
without proper governmental permits.
鈾? Measures for cleaning/collecting:
Absorb with liquid鈭抌inding material (sand, diatomite, acid
binders, universal binders, sawdust).
Keep away from ignition sources.
鈾? Additional information:
Material Safety Data Sheet 3
A11407 鈭? Bromobenzene
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
鈥? 7 Handling and storage
鈾? Handling
鈾? Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
鈾? Information about protection against explosions and fires:
Keep ignition sources away.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
鈾? Storage
鈾? Requirements to be met by storerooms and receptacles:
No special requirements.
鈾? Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
鈾? Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
鈥? 8 Exposure controls and personal protection
鈾? Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous
chemicals and having an average face velocity of at least 100
feet per minute.
Material Safety Data Sheet 4
A11407 鈭? Bromobenzene
Components with limit values that require monitoring at the
workplace:
Not required.
鈾? Additional information: No data
鈾? Personal protective equipment
鈾? General protective and hygienic measures
The usual precautionary measures for handling chemicals should
be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
鈾? Breathing equipment:
Use suitable respirator when high concentrations are present.
鈾? Protection of hands: Impervious gloves
鈾? Eye protection: Safety glasses
鈾? Body protection: Protective work clothing.
鈥? 9 Physical and chemical properties:
鈾? General Information
鈾? Form: Liquid
鈾? Color: Colorless
鈾? Odor: Aromatic
鈾? Value/Range Unit
Method
Material Safety Data Sheet 5
A11407 鈭? Bromobenzene
鈾? Change in condition
鈾? Melting point/Melting range: 鈭?30.7 掳 C
鈾? Boiling point/Boiling range: 156 掳 C
鈾? Sublimation temperature / start: Not determined
鈾? Flash point: 51 掳 C
鈾? Ignition temperature: 566 掳 C
鈾? Decomposition temperature: Not determined
鈾? Danger of explosion:
Product is not explosive. However, formation of explosive
air/vapor mixtures is possible.
鈾? Explosion limits:
鈾? Lower: 6 Vol %
鈾? Upper: 36.5 Vol %
鈾? Vapor pressure: at 20 掳 C 13 hPa
鈾? Density: at 20 掳 C 1.497 g/cm鲁
Material Safety Data Sheet 6
A11407 鈭? Bromobenzene
鈾? Solubility in / Miscibility with
鈾? Water: Not miscible or difficult
to mix
鈥? 10 Stability and reactivity
鈾? Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
鈾? Materials to be avoided:
Oxidizing agents
Acids
鈾? Dangerous reactions No dangerous reactions known
鈾? Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Hydrogen bromide
鈥? 11 Toxicological information
鈾? Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral: LD50: 2700 mg/kg (mam)
LD50: 2700 mg/kg (mus)
LD50: 2699 mg/kg (rat)
LD50: 3300 mg/kg (rbt)
Inhalative: LC50: 14400 mg/m3 (mam)
LC50: 20411 mg/m3 (rat)
LC50/2H: 21000 mg/m3/2H (mus)
鈾? Primary irritant effect:
鈾? on the skin: Irritant to skin and mucous membranes.
鈾? on the eye: Irritating effect.
Material Safety Data Sheet 7
A11407 鈭? Bromobenzene
鈾? Sensitization: No sensitizing effects known.
鈾? Subacute to chronic toxicity:
Bromobenzene is irritating to the skin, eyes and mucous
membranes. Exposure may cause stomach pains, vomiting and
diarrhea. Chronic exposure may cause damage to the liver and
kidneys.
鈾? Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.
鈥? 12 Ecological information:
鈾? General notes:
Also poisonous for fish and plankton in water bodies.
Do not allow material to be released to the environment without proper
governmental permits.
鈥? 13 Disposal considerations
鈾? Product:
鈾? Recommendation
Consult state, local or national regulations to ensure proper
disposal.
鈾? Uncleaned packagings:
鈾? Recommendation:
Disposal must be made according to official regulations.
鈥? 14 Transport information
Material Safety Data Sheet 8
A11407 鈭? Bromobenzene
鈾? DOT regulations:
鈾? Hazard class: 3
鈾? Identification number: UN2514
鈾? Packing group: III
鈾? Proper shipping name (technical name):
Bromobenzene
鈾? Land transport ADR/RID (cross鈭抌order)
鈾? ADR/RID class: 3 Flammable liquids
鈾? Item: 31c
鈾? Danger code (Kemler): 30
鈾? UN鈭扤umber: 2514
鈾? Description of goods: Bromobenzene
鈾? Maritime transport IMDG:
鈾? IMDG Class: 3
鈾? UN Number: 2514
鈾? Packaging group: III
鈾? Proper shipping name: Bromobenzene
Material Safety Data Sheet 9
A11407 鈭? Bromobenzene
鈾? Air transport ICAO鈭扵I and IATA鈭扗GR:
鈾? ICAO/IATA Class: 3
鈾? UN/ID Number: 2514
鈾? Packaging group: III
鈾? Proper shipping name: Bromobenzene
鈥? 15 Regulations
鈾? Product related hazard informations:
鈾? Hazard symbols:
Xi Irritant N Dangerous for the environment
鈾? Risk phrases:
10 Flammable.
38 Irritating to skin.
51/53 Toxic to aquatic organisms, may cause long鈭抰erm adverse
effects in the aquatic environment
鈾? Safety phrases:
61 Avoid release to the environment. Refer to special
instructions/Safety data sheets
鈾? National regulations
All components of this product are listed in the U.S.
Environmental Protection Agency Toxic Substances Control Act
Chemical substance Inventory.
鈾? Information about limitation of use:
Material Safety Data Sheet 10
A11407 鈭? Bromobenzene
For use only by technically qualified individuals.
鈥? 16 Other information:
Employers should use this information only as a supplement to
other information gathered by them, and should make
independent judgement of suitability of this information to
ensure proper use and protect the health and safety of
employees. This information is furnished without warranty,
and any use of the product not in conformance with this
Material Safety Data Sheet, or in combination with any other
product or process, is the responsibility of the user.
鈾? Department issuing MSDS: Health, Safety and Environmental
Department.
鈾? Contact: Darrell R. Sanders
Material Safety Data Sheet 11
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