A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 02/03/2003 Reviewed on 10/30/2002
鈥? 1 Identification of substance:
鈾? Product details:
鈾? Product name: 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? Stock number: A11401
鈾? Manufacturer/Supplier:
Alfa Aesar, A Johnson Matthey Company
Johnson Matthey Catalog Company, Inc.
30 Bond Street
Ward Hill, MA 01835鈭?8099
Emergency Phone: (978) 521鈭?6300
CHEMTREC: (800) 424鈭?9300
Web Site: www.alfa.com
鈾? Information Department: Health, Safety and Environmental
Department
鈾? Emergency information:
During normal hours the Health, Safety and Environmental Department.
After normal hours call Chemtrec at (800) 424鈭?9300.
鈥? 2 Composition/Data on components:
鈾? Chemical characterization:
Description: (CAS#)
Material Safety Data Sheet 1
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
3,5鈭払is(trifluoromethyl)benzoyl chloride
(CAS# 785鈭?56鈭?8): 100%
鈾? Identification number(s):
鈾? EINECS Number: 212鈭?322鈭?0
鈥? 3 Hazards identification
鈾? Hazard description: C Corrosive
鈾? Information pertaining to particular dangers for man and
environment
R 14 Reacts violently with water.
R 34 Causes burns.
鈾? Classification system
鈾? HMIS ratings (scale 0鈭?4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 2
Reactivity = 2
鈥? 4 First aid measures
鈾? General information
Immediately remove any clothing soiled by the product.
鈾? After inhalation
Supply fresh air. If required, provide artificial respiration.
Keep patient warm.
Seek immediate medical advice.
鈾? After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
鈾? After eye contact
Material Safety Data Sheet 2
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
Rinse opened eye for several minutes under running water. Then
consult a doctor.
鈾? After swallowing Seek immediate medical advice.
鈥? 5 Fire fighting measures
鈾? Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
鈾? For safety reasons unsuitable extinguishing agents Water
鈾? Special hazards caused by the material, its products of
combustion or
resulting gases:
Reacts violently with water
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Hydrogen chloride (HCl)
Hydrogen fluoride (HF)
鈾? Protective equipment:
Wear self鈭抍ontained respirator.
Wear fully protective impervious suit.
鈥? 6 Accidental release measures
鈾? Person鈭抮elated safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
鈾? Measures for environmental protection:
Do not allow material to be released to the environment
without proper governmental permits.
鈾? Measures for cleaning/collecting:
Absorb with liquid鈭抌inding material (sand, diatomite, acid
binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Material Safety Data Sheet 3
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
Do not flush with water or aqueous cleansing agents
鈾? Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
鈥? 7 Handling and storage
鈾? Handling
鈾? Information for safe handling:
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
鈾? Information about protection against explosions and fires:
Keep ignition sources away.
鈾? Storage
鈾? Requirements to be met by storerooms and receptacles:
No special requirements.
鈾? Information about storage in one common storage facility:
Store away from water/moisture.
Store away from oxidizing agents.
鈾? Further information about storage conditions:
Store under dry inert gas.
Protect from humidity and water.
This product is moisture sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Store under lock and key and with access restricted to technical experts
or their assistants only.
鈥? 8 Exposure controls and personal protection
Material Safety Data Sheet 4
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous
chemicals and having an average face velocity of at least 100
feet per minute.
Components with limit values that require monitoring at the
workplace:
Not required.
鈾? Additional information: No data
鈾? Personal protective equipment
鈾? General protective and hygienic measures
The usual precautionary measures for handling chemicals should
be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
鈾? Breathing equipment:
Use suitable respirator when high concentrations are present.
鈾? Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper
condition.
鈾? Material of gloves
The selection of suitable gloves not only depends on the
material, but also on quality. Quality will vary from
manufacturer to manufacturer.
鈾? Eye protection:
Safety glasses
Tightly sealed goggles
Full face protection
鈾? Body protection: Protective work clothing.
Material Safety Data Sheet 5
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈥? 9 Physical and chemical properties:
鈾? General Information
鈾? Form: Liquid
鈾? Color: Colorless
鈾? Odor: Not determined
鈾? Value/Range Unit
Method
鈾? Change in condition
鈾? Melting point/Melting range: Not determined
鈾? Boiling point/Boiling range: Not determined
鈾? Sublimation temperature / start: Not determined
鈾? Flash point: 72 掳 C
鈾? Ignition temperature: Not determined
鈾? Decomposition temperature: Not determined
鈾? Danger of explosion:
Product does not present an explosion hazard.
鈾? Explosion limits:
Material Safety Data Sheet 6
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? Lower: Not determined
鈾? Upper: Not determined
鈾? Vapor pressure: Not determined
鈾? Density: at 20 掳 C 1.526 g/cm鲁
鈾? Solubility in / Miscibility with
鈾? Water: Reacts violently
鈥? 10 Stability and reactivity
鈾? Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
鈾? Materials to be avoided:
Water/moisture
Oxidizing agents
鈾? Dangerous reactions Reacts violently with water
鈾? Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Hydrogen chloride (HCl)
Hydrogen fluoride
鈥? 11 Toxicological information
鈾? Acute toxicity:
鈾? Primary irritant effect:
Material Safety Data Sheet 7
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? on the skin:
Corrosive effect on skin and mucous membranes.
Irritant to skin and mucous membranes.
鈾? on the eye:
Strong corrosive effect.
Irritating effect.
鈾? Sensitization: No sensitizing effects known.
鈾? Subacute to chronic toxicity:
Corrosive materials are acutely destructive to the respiratory
tract, eyes, skin and digestive tract. Eye contact may result
in permanent damage and complete vision loss. Inhalation may
result in respiratory effects such as inflammation, edema, and
chemical pneumonitis. May cause coughing, wheezing,
laryngitis, shortness of breath, headache, nausea and
vomiting. Ingestion may cause damage to the mouth, throat and
esophagus. May cause skin burns or irritation depending on
the severity of the exposure.
鈾? Additional toxicological information:
Swallowing will lead to a strong corrosive effect on mouth and throat and
to the danger of perforation of esophagus and stomach.
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.
鈥? 12 Ecological information:
鈾? General notes:
Do not allow material to be released to the environment without proper
governmental permits.
鈥? 13 Disposal considerations
鈾? Product:
Material Safety Data Sheet 8
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? Recommendation
Consult state, local or national regulations to ensure proper
disposal.
鈾? Uncleaned packagings:
鈾? Recommendation:
Disposal must be made according to official regulations.
鈥? 14 Transport information
鈾? DOT regulations:
鈾? Hazard class: 8
鈾? Identification number: UN3094
鈾? Packing group: II
鈾? Proper shipping name (technical name):
Corrosive liquid, water鈭抮eactive,
n.o.s. (3,5鈭?
Bis(trifluoromethyl)benzoyl
chloride)
鈾? Land transport ADR/RID (cross鈭抌order)
鈾? ADR/RID class: 8 Corrosive substances
鈾? Danger code (Kemler): 80
鈾? UN鈭扤umber: 3265
鈾? Description of goods: Corrosive liquid, acidic, organic,
Material Safety Data Sheet 9
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
n.o.s.
(3,5鈭払is(trifluoromethyl)benzoyl
chloride)
鈾? Maritime transport IMDG:
鈾? IMDG Class: 8
鈾? UN Number: 3265
鈾? Packaging group: II
鈾? Proper shipping name: Corrosive liquid, acidic, organic,
n.o.s.
(3,5鈭払is(trifluoromethyl)benzoyl
chloride)
鈾? Air transport ICAO鈭扵I and IATA鈭扗GR:
鈾? ICAO/IATA Class: 8
鈾? UN/ID Number: 3265
鈾? Packaging group: II
鈾? Proper shipping name: Corrosive liquid, acidic, organic,
n.o.s.
(3,5鈭払is(trifluoromethyl)benzoyl chloride)
鈥? 15 Regulations
鈾? Product related hazard informations:
Material Safety Data Sheet 10
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
鈾? Hazard symbols: C Corrosive
鈾? Risk phrases:
14 Reacts violently with water.
34 Causes burns.
鈾? Safety phrases:
8 Keep container dry.
20 When using do not eat or drink.
26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
30 Never add water to this product.
36/37/39 Wear suitable protective clothing, gloves and
eye/face protection.
45 In case of accident or if you feel unwell, seek
medical advice immediately.
60 This material and its container must be disposed of
as hazardous waste.
鈾? National regulations
This product is not listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical
Substance Inventory. Use of this product is restricted to
research and development only.
鈾? Information about limitation of use:
For use only by technically qualified individuals.
鈥? 16 Other information:
Employers should use this information only as a supplement to
other information gathered by them, and should make
independent judgement of suitability of this information to
ensure proper use and protect the health and safety of
employees. This information is furnished without warranty,
and any use of the product not in conformance with this
Material Safety Data Sheet, or in combination with any other
product or process, is the responsibility of the user.
鈾? Department issuing MSDS: Health, Safety and Environmental
Material Safety Data Sheet 11
A11401 鈭? 3,5鈭払is(trifluoromethyl)benzoyl chloride
Department.
鈾? Contact: Darrell R. Sanders
Material Safety Data Sheet 12
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